Investigation and rational design of the catalyst-support interface in redox catalysis by ceria

Show simple item record

dc.contributor Thompson, Gregory B.
dc.contributor Weaver, Mark L.
dc.contributor Uddi, Mruthunjaya
dc.contributor Ning, Haibin
dc.contributor.advisor Wang, Ruigang
dc.contributor.author Liu, Zhongqi
dc.date.accessioned 2020-09-30T17:24:50Z
dc.date.available 2020-09-30T17:24:50Z
dc.date.issued 2020
dc.identifier.other u0015_0000001_0003612
dc.identifier.other Liu_alatus_0004D_14177
dc.identifier.uri http://ir.ua.edu/handle/123456789/7011
dc.description Electronic Thesis or Dissertation
dc.description.abstract Investigating and controlling the catalyst-support interfacial interaction/structure and their effects on catalytic performance are crucial for optimizing the activity, selectivity, and durability of catalytic materials, as the heterogeneous catalytic reactions typically take place on the catalyst surface and/or at the interface between the catalyst and support. Ceria (CeO2), due to its remarkable redox activity, has been widely adopted as an active support material or promoter in a multitude of redox catalytic reactions and is the focus of this research. With the goal of bridging the predictable catalyst design-fundamental understanding of performance-practical application, we expect to develop uniform and well-defined CeO2 nanostructures as model supports to investigate the underlying mechanism of the catalyst-support interactions, and furthermore establish the correlation between interfacial structure and catalytically active sites. In Chapter 2, reducible CeO2 nanorods and nanocubes, as well as irreducible SiO2 nanospheres supported cobalt oxides (CoOx) catalysts were synthesized and comparatively studied to understand the effects of support morphology, surface defect, support reducibility, in addition to the CoOx-support interactions on their redox and catalytic properties. Chapter 3 focuses on exploring the role of “bimetallic catalysts-support interaction” over highly active CeO2 nanorods supported pure cobalt oxides and cobalt-based bimetallic oxides nanoparticles (Fe-Co, Ni-Co and Cu-Co). The interactions between cobalt with the second transition metals (Fe, Ni and Cu) are discussed as well. Nanoparticle agglomeration issue always exists when using wet-chemical methods to synthesize CeO2 nanomaterials, which is harmful for catalytic applications due to decreased surface area. Therefore, Chapter 4 presents a scalable and facile electrospinning process for designing novel fibrous structured CeO2 and one-pot synthesis of high-surface-area, thermally stable and low-temperature active Ru-CeO2 nanofiber catalysts. Besides, attracted by the great interest of three-dimensional (3D) nanoarray structures fabrication towards novel and high-performance catalyst design, as well as nanodevice applications, electrochemical deposition technique was adopted for fabricating CeO2 nanoarrays in Chapter 5. Processing factors on growing controllable CeO2 nanoarrays, including the current density, reaction temperature, stirring rate, anode and substrate types were comprehensively investigated. A scale-up synthetic strategy for CeO2 nanoarrays fabrication is developed. Besides, possible mechanisms for morphological evolution and growth of CeO2 nanoarrays are discussed.
dc.format.extent 196 p.
dc.format.medium electronic
dc.format.mimetype application/pdf
dc.language English
dc.language.iso en_US
dc.publisher University of Alabama Libraries
dc.relation.ispartof The University of Alabama Electronic Theses and Dissertations
dc.relation.ispartof The University of Alabama Libraries Digital Collections
dc.relation.hasversion born digital
dc.rights All rights reserved by the author unless otherwise indicated.
dc.subject.other Materials Science
dc.title Investigation and rational design of the catalyst-support interface in redox catalysis by ceria
dc.type thesis
dc.type text
etdms.degree.department University of Alabama. Department of Physics and Astronomy
etdms.degree.discipline Materials Science
etdms.degree.grantor The University of Alabama
etdms.degree.level doctoral
etdms.degree.name Ph.D.


Files in this item

This item appears in the following Collection(s)

Show simple item record

Search DSpace


Browse

My Account