Synthesis and applications of hierarchically porous metal and metal oxide monolithic materials

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dc.contributor Bowman, Michael K.
dc.contributor Pan, Shanlin
dc.contributor Street, Shane C.
dc.contributor Lindén, Mika
dc.contributor.advisor Bakker, Martin G.
dc.contributor.author Sayler, Franchessa Maddox
dc.date.accessioned 2017-03-01T16:46:58Z
dc.date.available 2017-03-01T16:46:58Z
dc.date.issued 2013
dc.identifier.other u0015_0000001_0001207
dc.identifier.other Sayler_alatus_0004D_11383
dc.identifier.uri https://ir.ua.edu/handle/123456789/1681
dc.description Electronic Thesis or Dissertation
dc.description.abstract A nanocasting method for synthesizing a broad range of hierarchically porous, high surface area metal and metal oxide monolithic materials was developed. The importance of a well-connected hard template was established based on conductivity measurements. A hierarchically porous, silica monolith prepared with 7% ocadecyltrimethylammonium bromide was found to be the optimum silica template. Several different factors were found to regulate how well the silica template was replicated. When the connectivity of the silica template, contents of the metal salt solution, impregnation method, temperature, atmosphere, and template removal are all controlled, a good replica of the original silica monolith can be attained in different metals or metal oxides. These metal and metal oxide monoliths were used in catalysis and liquid chromatography.
dc.format.extent 217 p.
dc.format.medium electronic
dc.format.mimetype application/pdf
dc.language English
dc.language.iso en_US
dc.publisher University of Alabama Libraries
dc.relation.ispartof The University of Alabama Electronic Theses and Dissertations
dc.relation.ispartof The University of Alabama Libraries Digital Collections
dc.relation.hasversion born digital
dc.rights All rights reserved by the author unless otherwise indicated.
dc.subject.other Materials Science
dc.subject.other Nanotechnology
dc.subject.other Nanoscience
dc.title Synthesis and applications of hierarchically porous metal and metal oxide monolithic materials
dc.type thesis
dc.type text
etdms.degree.department University of Alabama. Department of Chemistry
etdms.degree.discipline Chemistry
etdms.degree.grantor The University of Alabama
etdms.degree.level doctoral
etdms.degree.name Ph.D.


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