Fluoroalkoxy-functionalized carbenes for main group and transition metal complexes

Show simple item record

dc.contributor Shaughnessy, Kevin H.
dc.contributor Snowden, Timothy S.
dc.contributor Thrasher, Joseph S.
dc.contributor Streubel, Rainer
dc.contributor Simmons, Howard E.
dc.contributor.advisor Arduengo III, Anthony J.
dc.contributor.author Runyon, Jason W.
dc.date.accessioned 2017-03-01T14:38:47Z
dc.date.available 2017-03-01T14:38:47Z
dc.date.issued 2011
dc.identifier.other u0015_0000001_0000540
dc.identifier.other Runyon_alatus_0004D_10689
dc.identifier.uri https://ir.ua.edu/handle/123456789/1045
dc.description Electronic Thesis or Dissertation
dc.description.abstract This dissertation recounts the synthesis and use of imidazol-2-ylidenes for their applications as ligands for main group elements and transition metals and as sterically hindered Lewis bases for hydrogen activation. Chapter 1 reviews the background of carbenes as ligands for main group compounds and transition metal complexes. The history and development of chelating Martin-type fluoroalkoxy ligands to form unique bonding architectures is covered. The synthetic strategies employed to functionalize carbene ligands with fluoroalkoxy substituents is reviewed leading to the development of stable fluoroalkoxy imidazolium zwitterions. A series of new ionic fluoroalkoxy imidazol-2ylidenes is described along with a comparison of the electronic properties to neutral imidazol-2-ylidenes. These fluoroalkoxy imidazol-2-ylidenes were used to prepare chelated hypervalent main group compounds. The structural characterization of the hypervalent adducts is described along with effects due to chelation. Additionally, the characterization of unique fused heterocyclic byproducts formed from unstable main group chelates is reviewed. The synthesis and characterization of transition metal complexes utilizing these ligands are described. Special emphasis is focused on catalytically active transition metals complexes and the influence of the tridentate ligand on catalyst activity. This ligand was also used to allow for the stabilization of iron benzylidene complexes which may have applications towards olefin metathesis. Chapter 2 describes work on hydrogen activation as a project with the U.S. Dept. of Energy's Alabama Chemical Hydrogen Storage Initiative. This project takes advantage of sterically hindered Lewis acid-base pairs to activate small molecules. A wide range of main group element Lewis acids were explored with a variety of mixed results. "Abnormal" coordination of Lewis acids to the carbene backbone results in structures with unique properties and reactivity. These systems were utilized with the goal of reversible heterolytic hydrogen cleavage followed by hydrogen elimination under another set of circumstances.
dc.format.extent 344 p.
dc.format.medium electronic
dc.format.mimetype application/pdf
dc.language English
dc.language.iso en_US
dc.publisher University of Alabama Libraries
dc.relation.ispartof The University of Alabama Electronic Theses and Dissertations
dc.relation.ispartof The University of Alabama Libraries Digital Collections
dc.relation.hasversion born digital
dc.rights All rights reserved by the author unless otherwise indicated.
dc.subject.other Chemistry
dc.title Fluoroalkoxy-functionalized carbenes for main group and transition metal complexes
dc.type thesis
dc.type text
etdms.degree.department University of Alabama. Dept. of Chemistry
etdms.degree.discipline Chemistry
etdms.degree.grantor The University of Alabama
etdms.degree.level doctoral
etdms.degree.name Ph.D.


Files in this item

This item appears in the following Collection(s)

Show simple item record

Search DSpace


Browse

My Account