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Department of Chemistry & Biochemistry

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Browsing Department of Chemistry & Biochemistry by Author "Afkhami, Farhad Akbari"

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    Solvent-Induced Formation of Novel Ni(II) Complexes Derived from Bis-Thiosemicarbazone Ligand: An Insight from Experimental and Theoretical Investigations
    (MDPI, 2021) Mahmoudi, Ghodrat; Babashkina, Maria G.; Maniukiewicz, Waldemar; Afkhami, Farhad Akbari; Nunna, Bharath Babu; Zubkov, Fedor I.; Ptaszek, Aleksandra L.; Szczepanik, Dariusz W.; Mitoraj, Mariusz P.; Safin, Damir A.; University of Maragheh; Lodz University of Technology; University of Alabama Tuscaloosa; New Jersey Institute of Technology; Harvard University; Brigham & Women's Hospital; Peoples Friendship University of Russia; Jagiellonian University; Tyumen State University; Ural Federal University; Kurgan State University
    In this work, we report solvent-induced complexation properties of a new N2S2 tetradentate bis-thiosemicarbazone ligand (H2LI), prepared by the condensation of 4-phenylthiosemicarbazide with bis-aldehyde, namely 2,2'-(ethane-1,2-diylbis(oxy)dibenzaldehyde, towards nickel(II). Using ethanol as a reaction medium allowed the isolation of a discrete mononuclear homoleptic complex [NiLI] (1), for which its crystal structure contains three independent molecules, namely 1-I, 1-II, and 1-III, in the asymmetric unit. The doubly deprotonated ligand L-I in the structure of 1 is coordinated in a cis-manner through the azomethine nitrogen atoms and the thiocarbonyl sulfur atoms. The coordination geometry around metal centers in all the three crystallographically independent molecules of 1 is best described as the seesaw structure. Interestingly, using methanol as a reaction medium in the same synthesis allowed for the isolation of a discrete mononuclear homoleptic complex [Ni(L-II)(2)] (2), where L-II is a monodeprotonated ligand 2-(2-(2-(2-(dimethoxymethyl)phenoxy)ethoxy)benzylidene)-N-phenylhydrazine-1-carbothioamide (HLII). The ligand L-II was formed in situ from the reaction of L-I with methanol upon coordination to the metal center under synthetic conditions. In the structure of 2, two ligands L-II are coordinated in a trans-manner through the azomethine nitrogen atom and the thiocarbonyl sulfur atom, also yielding a seesaw coordination geometry around the metal center. The charge and energy decomposition scheme ETS-NOCV allows for the conclusion that both structures are stabilized by a bunch of London dispersion-driven intermolecular interactions, including predominantly N-H center dot center dot center dot S and N-H center dot center dot center dot O hydrogen bonds in 1 and 2, respectively; they are further augmented by less typical C-H center dot center dot center dot X (where X = S, N, O, pi), CH center dot center dot center dot HC, pi center dot center dot center dot pi stacking and the most striking, attractive long-range intermolecular C-H center dot center dot center dot Ni preagostic interactions. The latter are found to be determined by both stabilizing Coulomb forces and an exchange-correlation contribution as revealed by the IQA energy decomposition scheme. Interestingly, the analogous long-range C-H center dot center dot center dot S interactions are characterized by a repulsive Coulomb contribution and the prevailing attractive exchange-correlation constituent. The electron density of the delocalized bonds (EDDB) method shows that the nickel(II) atom shares only similar to 0.8 vertical bar e vertical bar due to the sigma-conjugation with the adjacent in-plane atoms, demonstrating a very weak sigma-metalloaromatic character.
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    Solvent-Induced Formation of Novel Ni(II) Complexes Derived from Bis-Thiosemicarbazone Ligand: An Insight from Experimental and Theoretical Investigations (vol 22, 5337, 2021)
    (MDPI, 2022) Mahmoudi, Ghodrat; Babashkina, Maria G.; Maniukiewicz, Waldemar; Afkhami, Farhad Akbari; Nunna, Bharath Babu; Zubkov, Fedor I.; Ptaszek, Aleksandra L.; Szczepanik, Dariusz W.; Mitoraj, Mariusz P.; Safin, Damir A.; University of Maragheh; Lodz University of Technology; University of Alabama Tuscaloosa; New Jersey Institute of Technology; Harvard University; Brigham & Women's Hospital; Peoples Friendship University of Russia; Jagiellonian University; Tyumen State University; Kurgan State University