RDKit 2D 21 22 0 0 0 0 0 0 0 0999 V2000 -0.7500 -9.0933 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.7500 -9.0933 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.5000 -7.7942 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7500 -6.4952 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.5000 -5.1962 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7500 -3.8971 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 -3.8971 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.5000 -2.5981 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.5000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.5000 -10.3923 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.7500 -11.6913 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 -11.6913 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5000 -12.9904 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 -14.2894 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7500 -14.2894 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.5000 -12.9904 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 2 0 2 3 1 0 3 4 1 0 4 5 1 0 5 6 1 0 6 7 2 0 6 8 1 0 8 9 1 0 9 10 2 0 10 11 1 0 11 12 2 0 12 13 1 0 13 14 2 0 2 15 1 0 15 16 1 0 16 17 2 0 17 18 1 0 18 19 2 0 19 20 1 0 20 21 2 0 14 9 1 0 21 16 1 0 M END > (1) UALIB-2342 > (1) O=C(COCC(=O)OC1=CC=CC=C1)OC1=CC=CC=C1 > (1) InChI=1S/C16H14O5/c17-15(20-13-7-3-1-4-8-13)11-19-12-16(18)21-14-9-5-2-6-10-14/h1-10H,11-12H2 > (1) Probasco, M.S. Synthetic investigations of new metal mediated methodologies and the structural study of the previously undetermined stereocenters of cyanomaclurin. Ph.D. Thesis, The University of Alabama, 2019. > (1) https://ir.ua.edu/handle/123456789/6548 $$$$ RDKit 2D 17 17 0 0 0 0 0 0 0 0999 V2000 9.5490 -3.1471 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.2500 -3.8971 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.9510 -4.6471 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.0000 -5.1962 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.5000 -2.5981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.2500 -1.2990 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 6.0000 -2.5981 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 5.2500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.0000 -2.5981 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 3.0000 0.0000 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.5000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 2 4 1 0 2 5 1 0 5 6 2 0 5 7 1 0 7 8 1 0 8 9 1 0 9 10 2 0 9 11 1 0 11 12 1 0 12 13 2 0 13 14 1 0 14 15 2 0 15 16 1 0 16 17 2 0 17 12 1 0 M END > (2) UALIB-2343 > (2) CC(C)(C)C(=O)OCC(=O)OC1=CC=CC=C1 > (2) InChI=1S/C13H16O4/c1-13(2,3)12(15)16-9-11(14)17-10-7-5-4-6-8-10/h4-8H,9H2,1-3H3 > (2) Probasco, M.S. Synthetic investigations of new metal mediated methodologies and the structural study of the previously undetermined stereocenters of cyanomaclurin. Ph.D. Thesis, The University of Alabama, 2019. > (2) https://ir.ua.edu/handle/123456789/6548 $$$$ RDKit 2D 29 28 0 0 0 0 0 0 0 0999 V2000 0.0000 3.7990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2990 4.5490 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.5981 3.7990 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 3.8971 4.5490 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.8971 6.0490 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 5.1962 3.7990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.4952 4.5490 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 7.7942 3.7990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.7942 2.2990 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 9.0933 4.5490 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.8433 3.2500 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.3433 5.8481 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.3923 5.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.5000 -5.1962 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.7500 -3.8971 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.2500 -3.8971 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 7.5000 -2.5981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.2500 -1.2990 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 6.0000 -2.5981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.2500 -1.2990 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 3.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.0000 -2.5981 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 3.0000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.5000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 1 0 4 5 2 0 4 6 1 0 6 7 1 0 7 8 1 0 8 9 2 0 8 10 1 0 10 11 1 0 10 12 1 0 10 13 1 0 14 15 1 0 15 16 1 0 16 17 1 0 17 18 2 0 17 19 1 0 19 20 1 0 20 21 1 0 21 22 2 0 21 23 1 0 23 24 1 0 24 25 2 0 25 26 1 0 26 27 2 0 27 28 1 0 28 29 2 0 29 24 1 0 M END > (3) UALIB-2344 > (3) CCOC(=O)COC(=O)C(C)(C)C.CCOC(=O)COC(=O)CC1=CC=CC=C1 > (3) InChI=1S/C12H14O4.C9H16O4/c1-2-15-12(14)9-16-11(13)8-10-6-4-3-5-7-10;1-5-12-7(10)6-13-8(11)9(2,3)4/h3-7H,2,8-9H2,1H3;5-6H2,1-4H3 > (3) Probasco, M.S. Synthetic investigations of new metal mediated methodologies and the structural study of the previously undetermined stereocenters of cyanomaclurin. Ph.D. Thesis, The University of Alabama, 2019. > (3) https://ir.ua.edu/handle/123456789/6548 $$$$ RDKit 2D 13 12 0 0 0 0 0 0 0 0999 V2000 0.0000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2990 0.7500 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.5981 -0.0000 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 3.8971 0.7500 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.8971 2.2500 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 5.1962 -0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.4952 0.7500 0.0000 N 0 0 0 0 0 4 0 0 0 0 0 0 7.2452 -0.5490 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.7452 -0.5490 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.7452 2.0490 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.4952 3.3481 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.7942 1.5000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.7942 3.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 1 0 4 5 2 0 4 6 1 0 6 7 1 0 7 8 1 0 8 9 1 0 7 10 1 0 10 11 1 0 7 12 1 0 12 13 1 0 M CHG 1 7 1 M END > (4) UALIB-2345 > (4) CCOC(=O)C[N+](CC)(CC)CC > (4) InChI=1S/C10H22NO2/c1-5-11(6-2,7-3)9-10(12)13-8-4/h5-9H2,1-4H3/q+1 > (4) Probasco, M.S. Synthetic investigations of new metal mediated methodologies and the structural study of the previously undetermined stereocenters of cyanomaclurin. Ph.D. Thesis, The University of Alabama, 2019. > (4) https://ir.ua.edu/handle/123456789/6548 $$$$ RDKit 2D 20 20 0 0 0 0 0 0 0 0999 V2000 6.0000 -2.5981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.2500 -1.2990 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 3.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.0000 0.0000 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.5000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7500 1.2990 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5000 2.5981 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 3.8971 0.0000 Si 0 0 0 0 0 4 0 0 0 0 0 0 -2.0490 4.6471 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.5490 3.1471 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0000 5.1962 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2990 4.4462 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.2990 5.9462 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7500 6.4952 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 1 0 4 5 1 0 5 6 2 0 6 7 1 0 7 8 2 0 8 9 1 0 9 10 2 0 8 11 1 0 11 12 1 0 12 13 1 0 13 14 1 0 13 15 1 0 13 16 1 0 16 17 1 0 16 18 1 0 16 19 1 0 11 20 2 0 20 5 1 0 M END > (5) UALIB-2346 > (5) COCOC1=CC=C(C=O)C(O[Si](C)(C)C(C)(C)C)=C1 > (5) InChI=1S/C15H24O4Si/c1-15(2,3)20(5,6)19-14-9-13(18-11-17-4)8-7-12(14)10-16/h7-10H,11H2,1-6H3 > (5) Probasco, M.S. Synthetic investigations of new metal mediated methodologies and the structural study of the previously undetermined stereocenters of cyanomaclurin. Ph.D. Thesis, The University of Alabama, 2019. > (5) https://ir.ua.edu/handle/123456789/6548 $$$$ RDKit 2D 9 8 0 0 0 0 0 0 0 0999 V2000 0.0000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2990 0.7500 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 2.5981 -0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.8971 0.7500 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.1962 -0.0000 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 6.4952 0.7500 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.7942 -0.0000 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 9.0933 0.7500 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.3923 -0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 1 0 4 5 1 0 5 6 1 0 6 7 1 0 7 8 1 0 8 9 2 0 M END > (6) UALIB-2347 > (6) C=COCOCCOC > (6) InChI=1S/C6H12O3/c1-3-8-6-9-5-4-7-2/h3H,1,4-6H2,2H3 > (6) Probasco, M.S. Synthetic investigations of new metal mediated methodologies and the structural study of the previously undetermined stereocenters of cyanomaclurin. Ph.D. Thesis, The University of Alabama, 2019. > (6) https://ir.ua.edu/handle/123456789/6548 $$$$ RDKit 2D 30 30 0 0 0 0 0 0 0 0999 V2000 3.0000 -10.3923 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.7500 -9.0933 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 3.0000 -7.7942 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.7500 -6.4952 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.0000 -5.1962 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 3.7500 -3.8971 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.0000 -2.5981 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 3.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.2500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.0000 -2.5981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.0000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.7500 1.2990 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.5000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0000 0.0000 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.7500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.2500 1.2990 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -6.0000 2.5981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.5000 2.5981 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.7500 3.8971 0.0000 Si 0 0 0 0 0 4 0 0 0 0 0 0 2.0490 4.6471 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.5490 3.1471 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0000 5.1962 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.2990 4.4462 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2990 5.9462 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 6.4952 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 1 0 4 5 1 0 5 6 1 0 6 7 1 0 7 8 1 0 8 9 1 6 9 10 2 0 8 11 1 0 11 12 1 6 11 13 1 0 13 14 2 0 14 15 1 0 15 16 2 0 16 17 1 0 17 18 1 0 18 19 1 0 19 20 1 0 16 21 1 0 21 22 2 0 22 23 1 0 23 24 1 0 24 25 1 0 24 26 1 0 24 27 1 0 27 28 1 0 27 29 1 0 27 30 1 0 22 13 1 0 M END > (7) UALIB-2348 > (7) C=C[C@H](OCOCCOC)[C@@H](O)C1=CC=C(OCOC)C=C1O[Si](C)(C)C(C)(C)C > (7) InChI=1S/C22H38O7Si/c1-9-19(28-16-26-13-12-24-5)21(23)18-11-10-17(27-15-25-6)14-20(18)29-30(7,8)22(2,3)4/h9-11,14,19,21,23H,1,12-13,15-16H2,2-8H3/t19-,21-/m0/s1 > (7) Probasco, M.S. Synthetic investigations of new metal mediated methodologies and the structural study of the previously undetermined stereocenters of cyanomaclurin. Ph.D. Thesis, The University of Alabama, 2019. > (7) https://ir.ua.edu/handle/123456789/6548 $$$$ RDKit 2D 16 16 0 0 0 0 0 0 0 0999 V2000 3.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.0000 0.0000 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.5000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5000 -2.5981 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 -3.8971 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.2500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.0000 2.5981 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5000 2.5981 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 3.8971 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 2 0 4 5 1 0 5 6 1 0 6 7 1 0 5 8 2 0 8 9 1 0 9 10 2 0 10 11 1 0 11 12 2 0 8 13 1 0 13 14 1 0 14 15 1 0 13 16 2 0 16 3 1 0 M END > (8) UALIB-2349 > (8) COC1=CC(OC)=C(/C=C/C=O)C(OC)=C1 > (8) InChI=1S/C12H14O4/c1-14-9-7-11(15-2)10(5-4-6-13)12(8-9)16-3/h4-8H,1-3H3/b5-4+ > (8) Probasco, M.S. Synthetic investigations of new metal mediated methodologies and the structural study of the previously undetermined stereocenters of cyanomaclurin. Ph.D. Thesis, The University of Alabama, 2019. > (8) https://ir.ua.edu/handle/123456789/6548 $$$$ RDKit 2D 19 19 0 0 0 0 0 0 0 0999 V2000 3.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.0000 0.0000 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.5000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5000 -2.5981 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 -3.8971 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.2500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.0000 2.5981 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -7.5000 2.5981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -8.2500 3.8971 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -8.2500 1.2990 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5000 2.5981 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 3.8971 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 2 0 4 5 1 0 5 6 1 0 6 7 1 0 5 8 2 0 8 9 1 0 9 10 2 0 10 11 1 0 11 12 1 0 12 13 1 0 13 14 1 0 13 15 2 0 8 16 1 0 16 17 1 0 17 18 1 0 16 19 2 0 19 3 1 0 M END > (9) UALIB-2350 > (9) COC1=CC(OC)=C(/C=C/COC(C)=O)C(OC)=C1 > (9) InChI=1S/C14H18O5/c1-10(15)19-7-5-6-12-13(17-3)8-11(16-2)9-14(12)18-4/h5-6,8-9H,7H2,1-4H3/b6-5+ > (9) Probasco, M.S. Synthetic investigations of new metal mediated methodologies and the structural study of the previously undetermined stereocenters of cyanomaclurin. Ph.D. Thesis, The University of Alabama, 2019. > (9) https://ir.ua.edu/handle/123456789/6548 $$$$ RDKit 2D 25 25 0 0 0 0 0 0 0 0999 V2000 9.7500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.2500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.5000 0.0000 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 6.0000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.2500 1.2990 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 5.2500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.0000 -2.5981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.5000 -2.5981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.2500 -3.8971 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.7500 -3.8971 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 10.5000 -5.1962 0.0000 Si 0 0 0 0 0 4 0 0 0 0 0 0 11.7990 -4.4462 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.2010 -5.9462 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 11.2500 -6.4952 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.9510 -7.2452 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 12.5490 -5.7452 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 12.0000 -7.7942 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.0000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.5000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 1 0 4 5 2 0 4 6 1 0 6 7 2 0 7 8 1 0 8 9 1 0 9 10 1 0 10 11 1 0 11 12 1 0 11 13 1 0 11 14 1 0 14 15 1 0 14 16 1 0 14 17 1 0 6 18 1 0 18 19 2 0 19 20 1 0 20 21 2 0 21 22 1 0 22 23 2 0 23 24 1 0 24 25 2 0 25 20 1 0 M END > (10) UALIB-2351 > (10) CCOC(=O)C(=C\CCO[Si](C)(C)C(C)(C)C)/C=C/C1=CC=CC=C1 > (10) InChI=1S/C21H32O3Si/c1-7-23-20(22)19(16-15-18-12-9-8-10-13-18)14-11-17-24-25(5,6)21(2,3)4/h8-10,12-16H,7,11,17H2,1-6H3/b16-15+,19-14- > (10) Probasco, M.S. Synthetic investigations of new metal mediated methodologies and the structural study of the previously undetermined stereocenters of cyanomaclurin. Ph.D. Thesis, The University of Alabama, 2019. > (10) https://ir.ua.edu/handle/123456789/6548 $$$$ RDKit 2D 15 14 0 0 0 0 0 0 0 0999 V2000 -4.5000 -2.5981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0000 -2.5981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2500 -1.2990 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0000 -2.5981 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.0000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.5000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.2500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0000 2.5981 0.0000 Si 0 0 0 0 0 4 0 0 0 0 0 0 -4.2990 1.8481 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7010 3.3481 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7500 3.8971 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 1 0 4 5 2 0 4 6 1 0 6 7 2 0 7 8 1 0 8 9 1 0 6 10 1 0 10 11 2 0 11 12 1 0 12 13 1 0 12 14 1 0 12 15 1 0 M END > (11) UALIB-2352 > (11) CC/C=C(/C=C/[Si](C)(C)C)C(=O)OCC > (11) InChI=1S/C12H22O2Si/c1-6-8-11(12(13)14-7-2)9-10-15(3,4)5/h8-10H,6-7H2,1-5H3/b10-9+,11-8- > (11) Probasco, M.S. Synthetic investigations of new metal mediated methodologies and the structural study of the previously undetermined stereocenters of cyanomaclurin. Ph.D. Thesis, The University of Alabama, 2019. > (11) https://ir.ua.edu/handle/123456789/6548 $$$$ RDKit 2D 23 22 0 0 0 0 0 0 0 0999 V2000 -4.5000 -2.5981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0000 -2.5981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2500 -1.2990 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0000 -2.5981 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.0000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.5000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.2500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.5000 -2.5981 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 6.0000 -2.5981 0.0000 Si 0 0 0 0 0 4 0 0 0 0 0 0 6.0000 -4.0981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.0000 -1.0981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.5000 -2.5981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.5000 -1.0981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.5000 -4.0981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.0000 -2.5981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0000 2.5981 0.0000 Si 0 0 0 0 0 4 0 0 0 0 0 0 -4.2990 1.8481 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7010 3.3481 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7500 3.8971 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 1 0 4 5 2 0 4 6 1 0 6 7 2 0 7 8 1 0 8 9 1 0 9 10 1 0 10 11 1 0 11 12 1 0 11 13 1 0 11 14 1 0 14 15 1 0 14 16 1 0 14 17 1 0 6 18 1 0 18 19 2 0 19 20 1 0 20 21 1 0 20 22 1 0 20 23 1 0 M END > (12) UALIB-2353 > (12) CCOC(=O)C(=C\CCO[Si](C)(C)C(C)(C)C)/C=C/[Si](C)(C)C > (12) InChI=1S/C18H36O3Si2/c1-10-20-17(19)16(13-15-22(5,6)7)12-11-14-21-23(8,9)18(2,3)4/h12-13,15H,10-11,14H2,1-9H3/b15-13+,16-12- > (12) Probasco, M.S. Synthetic investigations of new metal mediated methodologies and the structural study of the previously undetermined stereocenters of cyanomaclurin. Ph.D. Thesis, The University of Alabama, 2019. > (12) https://ir.ua.edu/handle/123456789/6548 $$$$ RDKit 2D 21 21 0 0 0 0 0 0 0 0999 V2000 1.5000 -5.1962 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.0000 -5.1962 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.7500 -3.8971 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 5.2500 -3.8971 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.0000 -5.1962 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 6.0000 -2.5981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.2500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.0000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.5000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.5000 -2.5981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.2500 -3.8971 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.7500 -3.8971 0.0000 Si 0 0 0 0 0 4 0 0 0 0 0 0 9.7500 -5.3971 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.7500 -2.3971 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 11.2500 -3.8971 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 1 0 4 5 2 0 4 6 1 0 6 7 2 0 7 8 1 0 8 9 1 0 9 10 1 0 10 11 2 0 11 12 1 0 12 13 2 0 13 14 1 0 14 15 2 0 6 16 1 0 16 17 2 0 17 18 1 0 18 19 1 0 18 20 1 0 18 21 1 0 15 10 1 0 M END > (13) UALIB-2354 > (13) CCOC(=O)C(=C\CCC1=CC=CC=C1)/C=C/[Si](C)(C)C > (13) InChI=1S/C18H26O2Si/c1-5-20-18(19)17(14-15-21(2,3)4)13-9-12-16-10-7-6-8-11-16/h6-8,10-11,13-15H,5,9,12H2,1-4H3/b15-14+,17-13- > (13) Probasco, M.S. Synthetic investigations of new metal mediated methodologies and the structural study of the previously undetermined stereocenters of cyanomaclurin. Ph.D. Thesis, The University of Alabama, 2019. > (13) https://ir.ua.edu/handle/123456789/6548 $$$$ RDKit 2D 13 12 0 0 0 0 0 0 0 0999 V2000 -0.7500 -6.4952 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0000 -5.1962 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 -3.8971 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.0000 -2.5981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.5000 -2.5981 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.5000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.2500 1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0000 -2.5981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.5000 -2.5981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2500 -3.8971 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 1 0 4 5 2 0 4 6 1 0 6 7 1 0 7 8 2 0 8 9 1 0 6 10 2 0 10 11 1 0 11 12 1 0 11 13 1 0 M END > (14) UALIB-2355 > (14) C/C=C/C(=C/C(C)C)C(=O)OCC > (14) InChI=1S/C11H18O2/c1-5-7-10(8-9(3)4)11(12)13-6-2/h5,7-9H,6H2,1-4H3/b7-5+,10-8- > (14) Probasco, M.S. Synthetic investigations of new metal mediated methodologies and the structural study of the previously undetermined stereocenters of cyanomaclurin. Ph.D. Thesis, The University of Alabama, 2019. > (14) https://ir.ua.edu/handle/123456789/6548 $$$$ RDKit 2D 16 15 0 0 0 0 0 0 0 0999 V2000 -0.7500 -6.4952 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0000 -5.1962 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 -3.8971 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.0000 -2.5981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.5000 -2.5981 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.5000 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.2500 1.2990 0.0000 Si 0 0 0 0 0 4 0 0 0 0 0 0 3.5490 0.5490 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.9510 2.0490 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.0000 2.5981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2500 -1.2990 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0000 -2.5981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.5000 -2.5981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2500 -3.8971 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 1 0 4 5 2 0 4 6 1 0 6 7 1 0 7 8 2 0 8 9 1 0 9 10 1 0 9 11 1 0 9 12 1 0 6 13 2 0 13 14 1 0 14 15 1 0 14 16 1 0 M END > (15) UALIB-2356 > (15) CCOC(=O)C(=C\C(C)C)/C=C/[Si](C)(C)C > (15) InChI=1S/C13H24O2Si/c1-7-15-13(14)12(10-11(2)3)8-9-16(4,5)6/h8-11H,7H2,1-6H3/b9-8+,12-10- > (15) Probasco, M.S. Synthetic investigations of new metal mediated methodologies and the structural study of the previously undetermined stereocenters of cyanomaclurin. Ph.D. Thesis, The University of Alabama, 2019. > (15) https://ir.ua.edu/handle/123456789/6548 $$$$