Mrv1927 02072015252D 9 9 0 0 1 0 999 V2000 -0.6431 1.1411 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4501 0.9696 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.5363 0.1491 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7827 -0.1864 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.2306 0.4266 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.4081 -0.9215 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.1175 1.4545 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.7009 0.8711 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.1175 2.2795 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 1 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 1 5 1 0 0 0 0 4 6 2 0 0 0 0 2 7 1 0 0 0 0 7 8 1 0 0 0 0 7 9 1 1 0 0 0 M END > UALIB-170 > (R)-5-[(R)-1-Hydroxyethyl]-butyrolactone > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > C[C@@H](O)[C@H]1CCC(=O)O1 > InChI=1S/C6H10O3/c1-4(7)5-2-3-6(8)9-5/h4-5,7H,2-3H2,1H3/t4-,5-/m1/s1 $$$$ Mrv1927 02072015252D 11 11 0 0 1 0 999 V2000 -0.6431 1.1411 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4501 0.9696 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.5363 0.1491 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7827 -0.1864 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.2306 0.4266 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.4081 -0.9215 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.1175 1.4545 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.7009 0.8711 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.1175 2.2795 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -2.1175 3.1045 0.0000 N 0 3 0 0 0 0 0 0 0 0 0 0 -2.1175 3.9295 0.0000 N 0 5 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 1 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 1 5 1 0 0 0 0 4 6 2 0 0 0 0 2 7 1 0 0 0 0 7 8 1 0 0 0 0 7 9 1 6 0 0 0 9 10 2 0 0 0 0 10 11 2 0 0 0 0 M CHG 2 10 1 11 -1 M STY 1 1 SUP M SAL 1 3 9 10 11 M SBL 1 1 9 M SMT 1 N3 M SAP 1 1 9 7 1 M END > UALIB-171 > (R)-5-[(S)-Azidoethyl]-butyrolactone > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > C[C@H](N=[N+]=[N-])[C@H]1CCC(=O)O1 > InChI=1S/C6H9N3O2/c1-4(8-9-7)5-2-3-6(10)11-5/h4-5H,2-3H2,1H3/t4-,5+/m0/s1 $$$$ Mrv1927 02072015252D 9 9 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.9403 0.2497 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 5 7 2 0 0 0 0 3 8 1 1 0 0 0 2 9 1 6 0 0 0 M END > UALIB-172 > (5R,6S)-5-Hydroxy-6-methyl-2-piperidinone > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > C[C@@H]1NC(=O)CC[C@H]1O > InChI=1S/C6H11NO2/c1-4-5(8)2-3-6(9)7-4/h4-5,8H,2-3H2,1H3,(H,7,9)/t4-,5+/m0/s1 $$$$ Mrv1927 02072015252D 19 19 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.9403 0.2497 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 5 7 2 0 0 0 0 3 8 1 1 0 0 0 2 9 1 6 0 0 0 13 10 1 0 0 0 0 10 11 1 0 0 0 0 10 12 1 0 0 0 0 12 9 1 0 0 0 0 12 14 1 0 0 0 0 14 15 1 0 0 0 0 14 16 1 0 0 0 0 12 17 1 0 0 0 0 17 18 1 0 0 0 0 17 19 1 0 0 0 0 M STY 1 1 SUP M SAL 1 11 9 10 11 12 13 14 15 16 17 18 19 M SBL 1 1 9 M SMT 1 OTIPS M SAP 1 1 9 2 1 M END > UALIB-173 > (5R,6S)-6-Methyl-5-(triisopropylsiloxy)-2-piperidinone > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CC(C)[Si](O[C@@H]1CCC(=O)N[C@H]1C)(C(C)C)C(C)C > InChI=1S/C15H31NO2Si/c1-10(2)19(11(3)4,12(5)6)18-14-8-9-15(17)16-13(14)7/h10-14H,8-9H2,1-7H3,(H,16,17)/t13-,14+/m0/s1 $$$$ Mrv1927 02072015252D 29 30 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.9403 0.2497 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2247 -0.4346 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9166 -0.8839 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.4896 -0.8091 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7977 -0.3598 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0626 -0.7344 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6293 -0.2850 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3644 -0.6596 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4075 -1.4834 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7156 -1.9328 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0194 -1.5582 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 5 7 2 0 0 0 0 3 8 1 1 0 0 0 2 9 1 6 0 0 0 4 10 1 0 0 0 0 14 11 1 0 0 0 0 11 12 1 0 0 0 0 11 13 1 0 0 0 0 13 9 1 0 0 0 0 13 15 1 0 0 0 0 15 16 1 0 0 0 0 15 17 1 0 0 0 0 13 18 1 0 0 0 0 18 19 1 0 0 0 0 18 20 1 0 0 0 0 21 10 2 0 0 0 0 10 22 1 0 0 0 0 22 23 1 0 0 0 0 23 24 1 0 0 0 0 24 25 2 0 0 0 0 25 26 1 0 0 0 0 26 27 2 0 0 0 0 27 28 1 0 0 0 0 28 29 2 0 0 0 0 24 29 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 11 9 11 12 13 14 15 16 17 18 19 20 M SBL 1 1 9 M SMT 1 OTIPS M SAP 1 1 9 2 1 M SAL 2 10 10 21 22 23 24 25 26 27 28 29 M SBL 2 1 10 M SMT 2 Cbz M SAP 2 1 10 4 1 M END > UALIB-174 > (5R,6S)-N-(Benzyloxycarbonyl)-6-methyl-5-(triisopropylsiloxy)-2-piperidinone > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CC(C)[Si](O[C@@H]1CCC(=O)N([C@H]1C)C(=O)OCC1=CC=CC=C1)(C(C)C)C(C)C > InChI=1S/C23H37NO4Si/c1-16(2)29(17(3)4,18(5)6)28-21-13-14-22(25)24(19(21)7)23(26)27-15-20-11-9-8-10-12-20/h8-12,16-19,21H,13-15H2,1-7H3/t19-,21+/m0/s1 $$$$ Mrv1927 02072015252D 36 37 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.9403 0.2497 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2247 -0.4346 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9166 -0.8839 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.4896 -0.8091 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7977 -0.3598 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0626 -0.7344 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6293 -0.2850 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3644 -0.6596 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4075 -1.4834 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7156 -1.9328 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0194 -1.5582 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3272 -0.3024 0.0000 S 0 0 0 0 0 0 0 0 0 0 0 0 -0.8793 -0.9154 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.2248 0.3107 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.2858 -0.8544 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.8989 -1.4066 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 -0.2663 -1.4675 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 0.8379 -0.2414 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 2 0 0 0 0 1 6 1 0 0 0 0 5 7 1 0 0 0 0 3 8 1 1 0 0 0 2 9 1 6 0 0 0 4 10 1 0 0 0 0 14 11 1 0 0 0 0 11 12 1 0 0 0 0 11 13 1 0 0 0 0 13 9 1 0 0 0 0 13 15 1 0 0 0 0 15 16 1 0 0 0 0 15 17 1 0 0 0 0 13 18 1 0 0 0 0 18 19 1 0 0 0 0 18 20 1 0 0 0 0 21 10 2 0 0 0 0 10 22 1 0 0 0 0 22 23 1 0 0 0 0 23 24 1 0 0 0 0 24 25 2 0 0 0 0 25 26 1 0 0 0 0 26 27 2 0 0 0 0 27 28 1 0 0 0 0 28 29 2 0 0 0 0 24 29 1 0 0 0 0 7 30 1 0 0 0 0 30 31 2 0 0 0 0 30 32 2 0 0 0 0 30 33 1 0 0 0 0 33 34 1 0 0 0 0 33 35 1 0 0 0 0 33 36 1 0 0 0 0 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 11 9 11 12 13 14 15 16 17 18 19 20 M SBL 1 1 9 M SMT 1 OTIPS M SAP 1 1 9 2 1 M SAL 2 10 10 21 22 23 24 25 26 27 28 29 M SBL 2 1 10 M SMT 2 Cbz M SAP 2 1 10 4 1 M SAL 3 8 7 30 31 32 33 34 35 36 M SBL 3 1 7 M SMT 3 OTf M SAP 3 1 7 5 1 M END > UALIB-175 > Trifluoromethanesulfonic acid (2S,3R)-N-(Benzyloxycarbonyl)-2-methyl-3-(triisopropylsiloxy)-1,2,3,4-tetrahydropyridin-6-yl ester > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CC(C)[Si](O[C@@H]1CC=C(OS(=O)(=O)C(F)(F)F)N([C@H]1C)C(=O)OCC1=CC=CC=C1)(C(C)C)C(C)C > InChI=1S/C24H36F3NO6SSi/c1-16(2)36(17(3)4,18(5)6)34-21-13-14-22(33-35(30,31)24(25,26)27)28(19(21)7)23(29)32-15-20-11-9-8-10-12-20/h8-12,14,16-19,21H,13,15H2,1-7H3/t19-,21+/m0/s1 $$$$ Mrv1927 02072015252D 33 34 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2247 -0.4346 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8860 0.3169 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3339 -0.2962 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.2181 -0.9093 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.9883 -0.6137 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.5717 -1.1970 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9166 -0.8839 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.4896 -0.8091 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7977 -0.3598 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0626 -0.7344 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6293 -0.2850 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3644 -0.6596 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4075 -1.4834 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7156 -1.9328 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0194 -1.5582 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 2 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 4 9 1 0 0 0 0 5 10 1 0 0 0 0 10 11 3 0 0 0 0 11 12 1 0 0 0 0 12 13 1 0 0 0 0 13 14 1 0 0 0 0 18 15 1 0 0 0 0 15 16 1 0 0 0 0 15 17 1 0 0 0 0 17 8 1 0 0 0 0 17 19 1 0 0 0 0 19 20 1 0 0 0 0 19 21 1 0 0 0 0 17 22 1 0 0 0 0 22 23 1 0 0 0 0 22 24 1 0 0 0 0 25 9 2 0 0 0 0 9 26 1 0 0 0 0 26 27 1 0 0 0 0 27 28 1 0 0 0 0 28 29 2 0 0 0 0 29 30 1 0 0 0 0 30 31 2 0 0 0 0 31 32 1 0 0 0 0 32 33 2 0 0 0 0 28 33 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 11 8 15 16 17 18 19 20 21 22 23 24 M SBL 1 1 8 M SMT 1 OTIPS M SAP 1 1 8 2 1 M SAL 2 10 9 25 26 27 28 29 30 31 32 33 M SBL 2 1 9 M SMT 2 Cbz M SAP 2 1 9 4 1 M END > UALIB-176 > (2S,3R)-N-(Benzyloxycarbonyl)-6-(4-hydroxy-1-butynyl)-2-methyl-3-(triisopropylsiloxy)-1,2,3,4-tetrahydropyridine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CC(C)[Si](O[C@@H]1CC=C(C#CCCO)N([C@H]1C)C(=O)OCC1=CC=CC=C1)(C(C)C)C(C)C > InChI=1S/C27H41NO4Si/c1-20(2)33(21(3)4,22(5)6)32-26-17-16-25(15-11-12-18-29)28(23(26)7)27(30)31-19-24-13-9-8-10-14-24/h8-10,13-14,16,20-23,26,29H,12,17-19H2,1-7H3/t23-,26+/m0/s1 $$$$ Mrv1927 02072015252D 36 37 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2247 -0.4346 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8860 0.3169 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3339 -0.2962 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.2181 -0.9093 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.9883 -0.6137 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.5717 -1.1970 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9166 -0.8839 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.4896 -0.8091 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7977 -0.3598 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0626 -0.7344 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6293 -0.2850 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3644 -0.6596 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4075 -1.4834 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7156 -1.9328 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0194 -1.5582 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1551 -1.7803 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.9417 -2.5772 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.9520 -1.5667 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 4 9 1 0 0 0 0 5 10 1 6 0 0 0 10 11 3 0 0 0 0 11 12 1 0 0 0 0 12 13 1 0 0 0 0 13 14 1 0 0 0 0 18 15 1 0 0 0 0 15 16 1 0 0 0 0 15 17 1 0 0 0 0 17 8 1 0 0 0 0 17 19 1 0 0 0 0 19 20 1 0 0 0 0 19 21 1 0 0 0 0 17 22 1 0 0 0 0 22 23 1 0 0 0 0 22 24 1 0 0 0 0 25 9 2 0 0 0 0 9 26 1 0 0 0 0 26 27 1 0 0 0 0 27 28 1 0 0 0 0 28 29 2 0 0 0 0 29 30 1 0 0 0 0 30 31 2 0 0 0 0 31 32 1 0 0 0 0 32 33 2 0 0 0 0 28 33 1 0 0 0 0 35 34 1 0 0 0 0 34 14 1 0 0 0 0 34 36 2 0 0 0 0 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 11 8 15 16 17 18 19 20 21 22 23 24 M SBL 1 1 8 M SMT 1 OTIPS M SAP 1 1 8 2 1 M SAL 2 10 9 25 26 27 28 29 30 31 32 33 M SBL 2 1 9 M SMT 2 Cbz M SAP 2 1 9 4 1 M SAL 3 4 14 34 35 36 M SBL 3 1 14 M SMT 3 OAc M SAP 3 1 14 13 1 M END > UALIB-177 > (2R,5R,6S)-N-(Benzyloxycarbonyl)-2-(4-acetoxy-1-butynyl)-6-methyl-5-(triisopropylsiloxy)piperidine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CC(C)[Si](O[C@@H]1CC[C@H](C#CCCOC(C)=O)N([C@H]1C)C(=O)OCC1=CC=CC=C1)(C(C)C)C(C)C > InChI=1S/C29H45NO5Si/c1-21(2)36(22(3)4,23(5)6)35-28-18-17-27(16-12-13-19-33-25(8)31)30(24(28)7)29(32)34-20-26-14-10-9-11-15-26/h9-11,14-15,21-24,27-28H,13,17-20H2,1-8H3/t24-,27-,28+/m0/s1 $$$$ Mrv1927 02072015252D 33 34 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2247 -0.4346 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8860 0.3169 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3339 -0.2962 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.2181 -0.9093 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.9883 -0.6137 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.5717 -1.1970 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9166 -0.8839 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.4896 -0.8091 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7977 -0.3598 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0626 -0.7344 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6293 -0.2850 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3644 -0.6596 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4075 -1.4834 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7156 -1.9328 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0194 -1.5582 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 4 9 1 0 0 0 0 5 10 1 6 0 0 0 10 11 3 0 0 0 0 11 12 1 0 0 0 0 12 13 1 0 0 0 0 13 14 1 0 0 0 0 18 15 1 0 0 0 0 15 16 1 0 0 0 0 15 17 1 0 0 0 0 17 8 1 0 0 0 0 17 19 1 0 0 0 0 19 20 1 0 0 0 0 19 21 1 0 0 0 0 17 22 1 0 0 0 0 22 23 1 0 0 0 0 22 24 1 0 0 0 0 25 9 2 0 0 0 0 9 26 1 0 0 0 0 26 27 1 0 0 0 0 27 28 1 0 0 0 0 28 29 2 0 0 0 0 29 30 1 0 0 0 0 30 31 2 0 0 0 0 31 32 1 0 0 0 0 32 33 2 0 0 0 0 28 33 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 11 8 15 16 17 18 19 20 21 22 23 24 M SBL 1 1 8 M SMT 1 OTIPS M SAP 1 1 8 2 1 M SAL 2 10 9 25 26 27 28 29 30 31 32 33 M SBL 2 1 9 M SMT 2 Cbz M SAP 2 1 9 4 1 M END > UALIB-178 > (2R,3R,6S)-N-(Benzyloxycarbonyl)-6-(4-hydroxy-1-butynyl)-2-methyl-3-(triisopropylsiloxy)piperidine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CC(C)[Si](O[C@@H]1CC[C@H](C#CCCO)N([C@H]1C)C(=O)OCC1=CC=CC=C1)(C(C)C)C(C)C > InChI=1S/C27H43NO4Si/c1-20(2)33(21(3)4,22(5)6)32-26-17-16-25(15-11-12-18-29)28(23(26)7)27(30)31-19-24-13-9-8-10-14-24/h8-10,13-14,20-23,25-26,29H,12,16-19H2,1-7H3/t23-,25-,26+/m0/s1 $$$$ Mrv1927 02072015252D 30 30 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2247 -0.4346 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8860 0.3169 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1157 0.6125 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.5254 0.0933 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2399 0.5058 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.9543 0.0933 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1058 0.0895 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.2470 0.3321 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3484 -1.0517 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4896 -0.8091 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7977 -0.3598 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9166 -0.8839 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 4 9 1 0 0 0 0 5 10 1 6 0 0 0 10 11 1 0 0 0 0 11 12 1 0 0 0 0 12 13 1 0 0 0 0 13 14 1 0 0 0 0 18 15 1 0 0 0 0 15 16 1 0 0 0 0 15 17 1 0 0 0 0 17 8 1 0 0 0 0 17 19 1 0 0 0 0 19 20 1 0 0 0 0 19 21 1 0 0 0 0 17 22 1 0 0 0 0 22 23 1 0 0 0 0 22 24 1 0 0 0 0 29 25 1 0 0 0 0 29 26 1 0 0 0 0 29 27 1 0 0 0 0 29 28 1 0 0 0 0 28 9 1 0 0 0 0 9 30 2 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 11 8 15 16 17 18 19 20 21 22 23 24 M SBL 1 1 8 M SMT 1 OTIPS M SAP 1 1 8 2 1 M SAL 2 7 9 25 26 27 28 29 30 M SBL 2 1 9 M SMT 2 Boc M SAP 2 1 9 4 1 M END > UALIB-179 > (2S,3R,6S)-N-(t-Butyloxycarbonyl)-6-(4-Hydroxybutyl)-2-methyl-3-(triisopropylsiloxy)piperidine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CC(C)[Si](O[C@@H]1CC[C@H](CCCCO)N([C@H]1C)C(=O)OC(C)(C)C)(C(C)C)C(C)C > InChI=1S/C24H49NO4Si/c1-17(2)30(18(3)4,19(5)6)29-22-15-14-21(13-11-12-16-26)25(20(22)7)23(27)28-24(8,9)10/h17-22,26H,11-16H2,1-10H3/t20-,21-,22+/m0/s1 $$$$ Mrv1927 02072015252D 36 36 0 0 1 0 999 V2000 -1.2857 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0002 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0002 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.2857 0.3893 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -0.5712 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 0.8577 0.8017 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.8577 1.6267 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.1432 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.7848 0.5468 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.5281 2.4507 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 0.1658 0.3524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.1658 -0.4726 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3862 -1.0857 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7665 1.0304 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.4148 -0.4256 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.6919 2.0588 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.8209 1.2438 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5628 2.8735 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.8770 1.9296 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.5814 1.1594 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.5067 2.1879 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.1006 0.5184 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.3144 -0.4928 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.8663 -1.1059 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.5694 0.2918 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -2.5074 -0.6643 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.8245 1.0764 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6314 1.2478 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.2724 1.6895 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3539 0.0368 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.9671 0.5887 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.5254 -0.7702 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6757 -2.0418 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1313 -1.8703 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.9308 -2.8265 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.1932 -0.9142 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 1 5 1 0 0 0 0 6 7 1 0 0 0 0 7 8 1 0 0 0 0 5 8 1 0 0 0 0 3 9 1 6 0 0 0 5 10 1 1 0 0 0 6 11 1 0 0 0 0 11 12 2 0 0 0 0 12 13 1 0 0 0 0 4 14 1 0 0 0 0 14 5 1 0 0 0 0 4 15 1 1 0 0 0 21 16 1 0 0 0 0 16 17 1 0 0 0 0 16 18 1 0 0 0 0 16 19 1 0 0 0 0 19 20 1 0 0 0 0 20 14 1 0 0 0 0 20 22 2 0 0 0 0 26 23 1 0 0 0 0 23 24 1 0 0 0 0 23 25 1 0 0 0 0 25 9 1 0 0 0 0 25 27 1 0 0 0 0 27 28 1 0 0 0 0 27 29 1 0 0 0 0 25 30 1 0 0 0 0 30 31 1 0 0 0 0 30 32 1 0 0 0 0 35 33 1 0 0 0 0 33 34 1 0 0 0 0 34 13 1 0 0 0 0 13 36 2 0 0 0 0 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 8 14 16 17 18 19 20 21 22 M SBL 1 2 13 14 M SMT 1 NBoc M SAP 1 2 14 4 1 14 5 2 M SAL 2 11 9 23 24 25 26 27 28 29 30 31 32 M SBL 2 1 8 M SMT 2 OTIPS M SAP 2 1 9 3 1 M SAL 3 5 13 33 34 35 36 M SBL 3 1 12 M SMT 3 CO2Et M SAP 3 1 13 12 1 M END > UALIB-180 > Ethyl 6-[(2S,5R,6S)-N-(t-Butyloxycarbonyl)-6-methyl-5-(triisopropylsiloxy)piperidin-2-yl]-2(E)-hexenoate > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@]1(CCC\C=C\C(=O)OCC)CC[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N1C(=O)OC(C)(C)C > InChI=1S/C28H53NO5Si/c1-12-32-26(30)17-15-13-14-16-24-18-19-25(23(8)29(24)27(31)33-28(9,10)11)34-35(20(2)3,21(4)5)22(6)7/h15,17,20-25H,12-14,16,18-19H2,1-11H3/b17-15-/t23-,24+,25+/m0/s1 $$$$ Mrv1927 02072015252D 29 30 0 0 1 0 999 V2000 -3.2043 1.9702 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.4074 1.7567 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7876 1.3868 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -3.5741 0.5900 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.7772 0.3764 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -2.1938 0.9598 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -4.1575 0.0066 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.5845 1.6004 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.3969 0.7463 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.1834 -0.0506 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7668 -0.6340 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5637 -0.4205 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.7211 -1.2303 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0985 -1.7716 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6105 1.5432 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -5.5950 1.0171 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.3919 0.8037 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.3814 1.8140 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -5.0117 0.4337 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.1678 2.6109 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7510 3.1942 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3709 2.8243 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.1782 2.0276 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.3917 2.8245 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.7616 1.4444 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.1609 -0.6932 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.3184 -1.5031 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.3809 -0.4245 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2560 -2.5814 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 1 3 1 0 0 0 0 2 6 1 0 0 0 0 3 4 1 0 0 0 0 5 4 1 0 0 0 0 6 5 1 0 0 0 0 4 7 1 1 0 0 0 3 8 1 6 0 0 0 6 9 1 0 0 0 0 9 10 1 0 0 0 0 10 11 1 0 0 0 0 11 12 1 0 0 0 0 12 5 1 0 0 0 0 12 13 1 6 0 0 0 13 14 1 0 0 0 0 6 15 1 1 0 0 0 19 16 1 0 0 0 0 16 17 1 0 0 0 0 16 18 1 0 0 0 0 18 8 1 0 0 0 0 18 20 1 0 0 0 0 20 21 1 0 0 0 0 20 22 1 0 0 0 0 18 23 1 0 0 0 0 23 24 1 0 0 0 0 23 25 1 0 0 0 0 28 26 1 0 0 0 0 26 27 1 0 0 0 0 27 14 1 0 0 0 0 14 29 2 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 11 8 16 17 18 19 20 21 22 23 24 25 M SBL 1 1 8 M SMT 1 OTIPS M SAP 1 1 8 3 1 M SAL 2 5 14 26 27 28 29 M SBL 2 1 15 M SMT 2 CO2Et M SAP 2 1 14 13 1 M END > UALIB-181 > Ethyl (4R,6S,7R,9aS)-Octahydro-6-methyl-7-(triisopropylsiloxy)-4H-quinolizin-4-yl acetate > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@@]12CCC[C@H](CC(=O)OCC)N1[C@@H](C)[C@@H](CC2)O[Si](C(C)C)(C(C)C)C(C)C > InChI=1S/C23H45NO3Si/c1-9-26-23(25)15-21-12-10-11-20-13-14-22(19(8)24(20)21)27-28(16(2)3,17(4)5)18(6)7/h16-22H,9-15H2,1-8H3/t19-,20-,21+,22+/m0/s1 $$$$ Mrv1927 02072015252D 35 36 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2247 -0.4346 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8860 0.3169 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1157 0.6125 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.5254 0.0933 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2399 0.5058 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.9543 0.0933 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.6688 0.5058 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.3607 0.0565 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9166 -0.8839 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.4896 -0.8091 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7977 -0.3598 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0626 -0.7344 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6293 -0.2850 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3644 -0.6596 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4075 -1.4834 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7156 -1.9328 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0194 -1.5582 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 4 9 1 0 0 0 0 5 10 1 6 0 0 0 10 11 1 0 0 0 0 11 12 1 0 0 0 0 12 13 1 0 0 0 0 13 14 2 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 20 17 1 0 0 0 0 17 18 1 0 0 0 0 17 19 1 0 0 0 0 19 8 1 0 0 0 0 19 21 1 0 0 0 0 21 22 1 0 0 0 0 21 23 1 0 0 0 0 19 24 1 0 0 0 0 24 25 1 0 0 0 0 24 26 1 0 0 0 0 27 9 2 0 0 0 0 9 28 1 0 0 0 0 28 29 1 0 0 0 0 29 30 1 0 0 0 0 30 31 2 0 0 0 0 31 32 1 0 0 0 0 32 33 2 0 0 0 0 33 34 1 0 0 0 0 34 35 2 0 0 0 0 30 35 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 11 8 17 18 19 20 21 22 23 24 25 26 M SBL 1 1 8 M SMT 1 OTIPS M SAP 1 1 8 2 1 M SAL 2 10 9 27 28 29 30 31 32 33 34 35 M SBL 2 1 9 M SMT 2 Cbz M SAP 2 1 9 4 1 M END > UALIB-182 > (2S,5R,6S)-N-(Benzyloxycarbonyl)-2-[6-hydroxy-4-(E)-hexenyl]-6-methyl-5-(triisopropylsiloxy)piperidine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CC(C)[Si](O[C@@H]1CC[C@H](CCC\C=C\CO)N([C@H]1C)C(=O)OCC1=CC=CC=C1)(C(C)C)C(C)C > InChI=1S/C29H49NO4Si/c1-22(2)35(23(3)4,24(5)6)34-28-19-18-27(17-13-8-9-14-20-31)30(25(28)7)29(32)33-21-26-15-11-10-12-16-26/h9-12,14-16,22-25,27-28,31H,8,13,17-21H2,1-7H3/b14-9+/t25-,27-,28+/m0/s1 $$$$ Mrv1927 02072015252D 36 38 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2247 -0.4346 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8860 0.3169 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1157 0.6125 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.5254 0.0933 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2399 0.5058 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 1.9543 0.0933 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 2.6688 0.5058 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.3607 0.0565 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.8232 1.0892 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9166 -0.8839 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.4896 -0.8091 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7977 -0.3598 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0626 -0.7344 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6293 -0.2850 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3644 -0.6596 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4075 -1.4834 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7156 -1.9328 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0194 -1.5582 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 4 9 1 0 0 0 0 5 10 1 6 0 0 0 10 11 1 0 0 0 0 11 12 1 0 0 0 0 12 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 13 17 1 6 0 0 0 14 17 1 6 0 0 0 21 18 1 0 0 0 0 18 19 1 0 0 0 0 18 20 1 0 0 0 0 20 8 1 0 0 0 0 20 22 1 0 0 0 0 22 23 1 0 0 0 0 22 24 1 0 0 0 0 20 25 1 0 0 0 0 25 26 1 0 0 0 0 25 27 1 0 0 0 0 28 9 2 0 0 0 0 9 29 1 0 0 0 0 29 30 1 0 0 0 0 30 31 1 0 0 0 0 31 32 2 0 0 0 0 32 33 1 0 0 0 0 33 34 2 0 0 0 0 34 35 1 0 0 0 0 35 36 2 0 0 0 0 31 36 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 11 8 18 19 20 21 22 23 24 25 26 27 M SBL 1 1 8 M SMT 1 OTIPS M SAP 1 1 8 2 1 M SAL 2 10 9 28 29 30 31 32 33 34 35 36 M SBL 2 1 9 M SMT 2 Cbz M SAP 2 1 9 4 1 M END > UALIB-183 > (2S,5R,6S)-N-(Benzyloxycarbonyl)-2-[(4S,5S)-4,5-epoxy-6-hydroxyhexyl]-6-methyl-5-(triisopropylsiloxy)piperidine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CC(C)[Si](O[C@@H]1CC[C@H](CCC[C@@H]2O[C@H]2CO)N([C@H]1C)C(=O)OCC1=CC=CC=C1)(C(C)C)C(C)C > InChI=1S/C29H49NO5Si/c1-20(2)36(21(3)4,22(5)6)35-26-17-16-25(14-11-15-27-28(18-31)34-27)30(23(26)7)29(32)33-19-24-12-9-8-10-13-24/h8-10,12-13,20-23,25-28,31H,11,14-19H2,1-7H3/t23-,25-,26+,27-,28-/m0/s1 $$$$ Mrv1927 02072015252D 27 28 0 0 1 0 999 V2000 -0.7644 3.1812 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7212 4.0050 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4131 4.4544 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.1482 4.0798 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.1914 3.2560 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.4995 2.8066 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9265 2.8814 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -3.6184 3.3307 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -3.5752 4.1546 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.8401 4.5291 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5427 1.9828 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.2344 4.9003 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -4.3328 2.9182 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.0127 2.0609 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.9920 1.2909 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.8282 1.5703 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1870 2.0894 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.6346 1.7913 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0471 1.0768 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0473 2.5057 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -3.8096 1.7913 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.4598 3.2200 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.2848 3.2200 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0475 3.9347 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7616 2.0930 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.4762 2.5055 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7616 1.2680 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 6 1 1 0 0 0 0 5 7 1 0 0 0 0 7 8 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 10 4 1 0 0 0 0 6 11 1 1 0 0 0 4 12 1 1 0 0 0 8 13 1 6 0 0 0 7 14 1 1 0 0 0 11 15 1 1 0 0 0 11 16 1 0 0 0 0 16 17 1 0 0 0 0 21 18 1 0 0 0 0 18 19 1 0 0 0 0 18 20 1 0 0 0 0 20 13 1 0 0 0 0 20 22 1 0 0 0 0 22 23 1 0 0 0 0 22 24 1 0 0 0 0 20 25 1 0 0 0 0 25 26 1 0 0 0 0 25 27 1 0 0 0 0 M STY 1 1 SUP M SAL 1 11 13 18 19 20 21 22 23 24 25 26 27 M SBL 1 1 14 M SMT 1 OTIPS M SAP 1 1 13 8 1 M END > UALIB-184 > (4S,6S,7R,9aS)-Octahydro-4-[(1S)-1,2-dihydroxyethyl]-6-methyl-7-(triisopropylsiloxy)-4H-quinolizine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@@]12CCC[C@@H]([C@H](O)CO)N1[C@@H](C)[C@@H](CC2)O[Si](C(C)C)(C(C)C)C(C)C > InChI=1S/C21H43NO3Si/c1-14(2)26(15(3)4,16(5)6)25-21-12-11-18-9-8-10-19(20(24)13-23)22(18)17(21)7/h14-21,23-24H,8-13H2,1-7H3/t17-,18-,19-,20+,21+/m0/s1 $$$$ Mrv1927 02072015252D 24 24 0 0 1 0 999 V2000 -1.6071 0.7366 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6071 -0.0884 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8721 -0.4629 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -0.1576 -0.0504 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.2887 -1.0463 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3319 -1.8702 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.4258 -0.6338 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.0932 -1.1187 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.7851 -0.6694 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.3371 -1.2825 0.0000 Cl 0 0 0 0 0 0 0 0 0 0 0 0 2.5921 -0.4979 0.0000 Cl 0 0 0 0 0 0 0 0 0 0 0 0 2.0808 0.1008 0.0000 Cl 0 0 0 0 0 0 0 0 0 0 0 0 -0.8535 1.0722 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1390 0.6597 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.5529 1.1090 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2880 0.7344 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1119 0.7776 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.7530 1.2968 0.0000 Br 0 0 0 0 0 0 0 0 0 0 0 0 1.2714 1.5996 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.9858 1.1871 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.9858 0.3621 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2714 -0.0504 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.5569 0.3621 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.5569 1.1871 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 3 5 1 0 0 0 0 5 6 2 0 0 0 0 5 7 1 0 0 0 0 7 8 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 9 11 1 0 0 0 0 9 12 1 0 0 0 0 1 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 2 0 0 0 0 16 17 2 0 0 0 0 17 18 1 0 0 0 0 24 19 2 0 0 0 0 19 20 1 0 0 0 0 20 21 2 0 0 0 0 21 22 1 0 0 0 0 22 23 2 0 0 0 0 24 23 1 0 0 0 0 23 4 1 0 0 0 0 M STY 1 1 SUP M SAL 1 7 4 19 20 21 22 23 24 M SBL 1 1 3 M SMT 1 Bn M SAP 1 1 4 3 1 M END > UALIB-185 > N-(7-Bromohepta-5,6-dienyl)-N-benzyl(2,2,2-trochloroethoxy)formamide > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > ClC(Cl)(Cl)COC(=O)N(CCCCC=C=CBr)CC1=CC=CC=C1 > InChI=1S/C17H19BrCl3NO2/c18-11-7-2-1-3-8-12-22(13-15-9-5-4-6-10-15)16(23)24-14-17(19,20)21/h2,4-6,9-11H,1,3,8,12-14H2 $$$$ Mrv1927 02072015252D 31 31 0 0 1 0 999 V2000 -1.6071 0.7366 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6071 -0.0884 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8721 -0.4629 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -0.1576 -0.0504 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.2887 -1.0463 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3319 -1.8702 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.4258 -0.6338 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.0932 -1.1187 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.7851 -0.6694 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.3371 -1.2825 0.0000 Cl 0 0 0 0 0 0 0 0 0 0 0 0 2.5921 -0.4979 0.0000 Cl 0 0 0 0 0 0 0 0 0 0 0 0 2.0808 0.1008 0.0000 Cl 0 0 0 0 0 0 0 0 0 0 0 0 -0.8535 1.0722 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1390 0.6597 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.5529 1.1090 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2880 0.7344 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1119 0.7776 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.7530 1.2968 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.3661 1.8488 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.0580 2.2982 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.7931 1.9236 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.8363 1.0998 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.5713 0.7252 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.6145 -0.0986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.3496 -0.4732 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2714 1.5996 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.9858 1.1871 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.9858 0.3621 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2714 -0.0504 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.5569 0.3621 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.5569 1.1871 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 3 5 1 0 0 0 0 5 6 2 0 0 0 0 5 7 1 0 0 0 0 7 8 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 9 11 1 0 0 0 0 9 12 1 0 0 0 0 1 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 2 0 0 0 0 16 17 2 0 0 0 0 17 18 1 0 0 0 0 18 19 3 0 0 0 0 19 20 1 0 0 0 0 20 21 1 0 0 0 0 21 22 1 0 0 0 0 22 23 1 0 0 0 0 23 24 1 0 0 0 0 24 25 1 0 0 0 0 31 26 2 0 0 0 0 26 27 1 0 0 0 0 27 28 2 0 0 0 0 28 29 1 0 0 0 0 29 30 2 0 0 0 0 31 30 1 0 0 0 0 30 4 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 7 4 26 27 28 29 30 31 M SBL 1 1 3 M SMT 1 Bn M SAP 1 1 4 3 1 M SAL 2 6 20 21 22 23 24 25 M SBL 2 1 19 M SMT 2 Hex M SAP 2 1 20 19 1 M SDS EXP 1 2 M END > UALIB-186 > N-(Pentadeca-5,6-dien-8-ynyl)-N-benzyl(2,2,2-trichloroethoxy)formamide > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CCCCCCC#CC=C=CCCCCN(CC1=CC=CC=C1)C(=O)OCC(Cl)(Cl)Cl > InChI=1S/C25H32Cl3NO2/c1-2-3-4-5-6-7-8-9-10-11-12-13-17-20-29(21-23-18-15-14-16-19-23)24(30)31-22-25(26,27)28/h9,11,14-16,18-19H,2-6,12-13,17,20-22H2,1H3 $$$$ Mrv1927 02072015252D 23 24 0 0 1 0 999 V2000 -1.9643 1.4277 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.6788 1.0152 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.6788 0.1902 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.9643 -0.2223 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.2498 0.1902 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.2498 1.0152 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0075 -1.0462 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.6749 -1.5311 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6367 -0.3619 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.1169 -0.0263 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7844 -0.5112 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4518 -0.9962 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0649 -1.5482 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5887 -2.3516 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.2561 -2.8365 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.0098 -2.5010 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.0960 -1.6805 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.4286 -1.1956 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.6780 -2.1002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.5065 -2.9072 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.1196 -3.4592 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.9481 -4.2662 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5612 -4.8182 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 4 7 1 0 0 0 0 7 8 1 0 0 0 0 5 9 1 0 0 0 0 9 10 2 0 0 0 0 10 11 1 4 0 0 0 11 12 3 0 0 0 0 12 13 1 0 0 0 0 8 14 2 0 0 0 0 14 15 1 0 0 0 0 15 16 2 0 0 0 0 16 17 1 0 0 0 0 17 18 2 0 0 0 0 8 18 1 0 0 0 0 13 19 1 0 0 0 0 19 20 1 0 0 0 0 20 21 1 0 0 0 0 21 22 1 0 0 0 0 22 23 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 6 8 14 15 16 17 18 M SBL 1 1 8 M SMT 1 Ph M SAP 1 1 8 7 1 M SAL 2 6 13 19 20 21 22 23 M SBL 2 1 13 M SMT 2 Hex M SAP 2 1 13 12 1 M END > UALIB-187 > 2-(Dec)-1-en-3-ynyl)-N-benzylpiperidine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CCCCCCC#CC=CC1CCCCN1CC1=CC=CC=C1 > InChI=1S/C22H31N/c1-2-3-4-5-6-7-8-12-17-22-18-13-14-19-23(22)20-21-15-10-9-11-16-21/h9-12,15-17,22H,2-6,13-14,18-20H2,1H3 $$$$ Mrv1927 02072015252D 32 32 0 0 1 0 999 V2000 -1.6071 0.7366 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6071 -0.0884 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8721 -0.4629 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -0.1576 -0.0504 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.2887 -1.0463 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3319 -1.8702 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.4258 -0.6338 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.0932 -1.1187 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.7851 -0.6694 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.3371 -1.2825 0.0000 Cl 0 0 0 0 0 0 0 0 0 0 0 0 2.5921 -0.4979 0.0000 Cl 0 0 0 0 0 0 0 0 0 0 0 0 2.0808 0.1008 0.0000 Cl 0 0 0 0 0 0 0 0 0 0 0 0 -0.8535 1.0722 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1390 0.6597 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.5529 1.1090 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2880 0.7344 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1119 0.7776 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.7530 1.2968 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5543 1.9366 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.2301 1.4634 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.1582 0.6415 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 3.3364 0.7135 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 4.0863 -0.1803 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.7621 -0.6535 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.9801 0.5696 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.3287 -0.1781 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2714 1.5996 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.9858 1.1871 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.9858 0.3621 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2714 -0.0504 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.5569 0.3621 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.5569 1.1871 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 3 5 1 0 0 0 0 5 6 2 0 0 0 0 5 7 1 0 0 0 0 7 8 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 9 11 1 0 0 0 0 9 12 1 0 0 0 0 1 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 2 0 0 0 0 16 17 2 0 0 0 0 17 18 1 0 0 0 0 18 22 1 0 0 0 0 19 20 1 0 0 0 0 20 21 1 0 0 0 0 21 22 1 0 0 0 0 21 23 1 0 0 0 0 23 24 1 0 0 0 0 21 25 1 0 0 0 0 25 26 1 0 0 0 0 32 27 2 0 0 0 0 27 28 1 0 0 0 0 28 29 2 0 0 0 0 29 30 1 0 0 0 0 30 31 2 0 0 0 0 32 31 1 0 0 0 0 31 4 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 7 4 27 28 29 30 31 32 M SBL 1 1 3 M SMT 1 Bn M SAP 1 1 4 3 1 M SAL 2 8 19 20 21 22 23 24 25 26 M SBL 2 1 18 M SMT 2 OTES M SAP 2 1 22 18 1 M SDS EXP 1 2 M END > UALIB-188 > N-[(8-Triethylsiloxy)octa-5,6-dienyl)-N-benzyl(2,2,2-trichloroethoxy)formamide > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CC[Si](CC)(CC)OCC=C=CCCCCN(CC1=CC=CC=C1)C(=O)OCC(Cl)(Cl)Cl > InChI=1S/C24H36Cl3NO3Si/c1-4-32(5-2,6-3)31-19-15-10-8-7-9-14-18-28(20-22-16-12-11-13-17-22)23(29)30-21-24(25,26)27/h8,11-13,15-17H,4-7,9,14,18-21H2,1-3H3 $$$$ Mrv1927 02072015252D 17 16 0 0 1 0 999 V2000 -4.0402 0.0223 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -3.3051 0.3969 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5700 0.7714 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.8555 1.1839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.2425 0.6319 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.1993 -0.1920 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.5505 1.0812 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.1845 0.7067 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.7575 2.2200 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3829 1.4849 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6479 1.8595 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1180 1.1104 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.0084 0.7498 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4577 0.0579 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.7753 -0.3523 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9971 0.8462 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.3483 -0.4270 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 3 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 6 0 0 0 5 7 1 0 0 0 0 7 8 1 0 0 0 0 8 13 1 0 0 0 0 9 10 1 0 0 0 0 10 11 1 0 0 0 0 10 12 1 0 0 0 0 10 13 1 0 0 0 0 13 14 2 0 0 0 0 15 1 1 0 0 0 0 1 16 1 0 0 0 0 1 17 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 4 1 15 16 17 M SBL 1 1 1 M SMT 1 TMS M SAP 1 1 1 2 1 M SAL 2 6 9 10 11 12 13 14 M SBL 2 1 8 M SMT 2 Piv M SAP 2 1 13 8 1 M SDS EXP 1 2 M END > UALIB-189 > (R)-2-Hydroxy-5-trimethylsilyl-4-pentyn-1-yl 2,2,-dimethylpropionate > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CC(C)(C)C(=O)OC[C@H](O)CC#C[Si](C)(C)C > InChI=1S/C13H24O3Si/c1-13(2,3)12(15)16-10-11(14)8-7-9-17(4,5)6/h11,14H,8,10H2,1-6H3/t11-/m1/s1 $$$$ Mrv1927 02072015252D 13 12 0 0 1 0 999 V2000 -3.3051 0.3969 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5700 0.7714 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.8555 1.1839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.2425 0.6319 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.1993 -0.1920 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.5505 1.0812 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.1845 0.7067 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.7575 2.2200 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3829 1.4849 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6479 1.8595 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1180 1.1104 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.0084 0.7498 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4577 0.0579 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 3 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 6 0 0 0 4 6 1 0 0 0 0 6 7 1 0 0 0 0 7 12 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 9 11 1 0 0 0 0 9 12 1 0 0 0 0 12 13 2 0 0 0 0 M STY 1 1 SUP M SAL 1 6 8 9 10 11 12 13 M SBL 1 1 7 M SMT 1 Piv M SAP 1 1 12 7 1 M SDS EXP 1 1 M END > UALIB-190 > (R)-2-Hydroxy-4-pentyn-1-yl 2,2,-dimethylpropionate > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CC(C)(C)C(=O)OC[C@H](O)CC#C > InChI=1S/C10H16O3/c1-5-6-8(11)7-13-9(12)10(2,3)4/h1,8,11H,6-7H2,2-4H3/t8-/m1/s1 $$$$ Mrv1927 02072015252D 41 42 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2247 -0.4346 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8860 0.3169 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3339 -0.2962 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.2181 -0.9093 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.9883 -0.6137 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 1.5717 -1.1970 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.9883 0.2113 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.5717 -2.0220 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 3.3620 -3.2707 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8771 -2.6032 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.2096 -3.0882 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5445 -2.1183 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.3922 -1.9358 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.7277 -1.1821 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9166 -0.8839 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.4896 -0.8091 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7977 -0.3598 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0626 -0.7344 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6293 -0.2850 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3644 -0.6596 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4075 -1.4834 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7156 -1.9328 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0194 -1.5582 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 2 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 4 9 1 0 0 0 0 5 10 1 0 0 0 0 10 11 3 0 0 0 0 11 12 1 0 0 0 0 12 13 1 0 0 0 0 13 14 1 0 0 0 0 13 15 1 1 0 0 0 14 16 1 0 0 0 0 16 21 1 0 0 0 0 17 18 1 0 0 0 0 18 19 1 0 0 0 0 18 20 1 0 0 0 0 18 21 1 0 0 0 0 21 22 2 0 0 0 0 26 23 1 0 0 0 0 23 24 1 0 0 0 0 23 25 1 0 0 0 0 25 8 1 0 0 0 0 25 27 1 0 0 0 0 27 28 1 0 0 0 0 27 29 1 0 0 0 0 25 30 1 0 0 0 0 30 31 1 0 0 0 0 30 32 1 0 0 0 0 33 9 2 0 0 0 0 9 34 1 0 0 0 0 34 35 1 0 0 0 0 35 36 1 0 0 0 0 36 37 2 0 0 0 0 37 38 1 0 0 0 0 38 39 2 0 0 0 0 39 40 1 0 0 0 0 40 41 2 0 0 0 0 36 41 1 0 0 0 0 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 11 8 23 24 25 26 27 28 29 30 31 32 M SBL 1 1 8 M SMT 1 OTIPS M SAP 1 1 8 2 1 M SAL 2 10 9 33 34 35 36 37 38 39 40 41 M SBL 2 1 9 M SMT 2 Cbz M SAP 2 1 9 4 1 M SAL 3 6 17 18 19 20 21 22 M SBL 3 1 17 M SMT 3 Piv M SAP 3 1 21 16 1 M SDS EXP 1 3 M END > UALIB-191 > (2R)-5-[(2S,3R)-N-(Benzyloxycarbonyl)-2-methyl-3-(triisopropylsiloxy)-1,2,3,4-tetrahydropyridin-6-yl]-2-hydroxy-5-pentyn-1-yl 2,2-dimethylpropionate > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CC(C)[Si](O[C@@H]1CC=C(C#CC[C@@H](O)COC(=O)C(C)(C)C)N([C@H]1C)C(=O)OCC1=CC=CC=C1)(C(C)C)C(C)C > InChI=1S/C33H51NO6Si/c1-23(2)41(24(3)4,25(5)6)40-30-20-19-28(17-14-18-29(35)22-38-31(36)33(8,9)10)34(26(30)7)32(37)39-21-27-15-12-11-13-16-27/h11-13,15-16,19,23-26,29-30,35H,18,20-22H2,1-10H3/t26-,29+,30+/m0/s1 $$$$ Mrv1927 02072015252D 42 43 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2247 -0.4346 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8860 0.3169 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3339 -0.2962 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.2181 -0.9093 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.9883 -0.6137 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 1.5717 -1.1970 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.9883 0.2113 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.5717 -2.0220 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 3.3620 -3.2707 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8771 -2.6032 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.2096 -3.0882 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5445 -2.1183 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.3922 -1.9358 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.7277 -1.1821 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.8615 1.2511 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9166 -0.8839 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.4896 -0.8091 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7977 -0.3598 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0626 -0.7344 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6293 -0.2850 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3644 -0.6596 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4075 -1.4834 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7156 -1.9328 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0194 -1.5582 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 4 9 1 0 0 0 0 5 10 1 0 0 0 0 10 11 3 0 0 0 0 11 12 1 0 0 0 0 12 13 1 0 0 0 0 13 14 1 0 0 0 0 13 15 1 1 0 0 0 14 16 1 0 0 0 0 16 21 1 0 0 0 0 17 18 1 0 0 0 0 18 19 1 0 0 0 0 18 20 1 0 0 0 0 18 21 1 0 0 0 0 21 22 2 0 0 0 0 5 23 1 1 0 0 0 27 24 1 0 0 0 0 24 25 1 0 0 0 0 24 26 1 0 0 0 0 26 8 1 0 0 0 0 26 28 1 0 0 0 0 28 29 1 0 0 0 0 28 30 1 0 0 0 0 26 31 1 0 0 0 0 31 32 1 0 0 0 0 31 33 1 0 0 0 0 34 9 2 0 0 0 0 9 35 1 0 0 0 0 35 36 1 0 0 0 0 36 37 1 0 0 0 0 37 38 2 0 0 0 0 38 39 1 0 0 0 0 39 40 2 0 0 0 0 40 41 1 0 0 0 0 41 42 2 0 0 0 0 37 42 1 0 0 0 0 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 11 8 24 25 26 27 28 29 30 31 32 33 M SBL 1 1 8 M SMT 1 OTIPS M SAP 1 1 8 2 1 M SAL 2 10 9 34 35 36 37 38 39 40 41 42 M SBL 2 1 9 M SMT 2 Cbz M SAP 2 1 9 4 1 M SAL 3 6 17 18 19 20 21 22 M SBL 3 1 17 M SMT 3 Piv M SAP 3 1 21 16 1 M SDS EXP 1 3 M END > UALIB-192 > (2R)-5-[(2R,5R,6S)-N-(Benzyloxycarbonyl)-6-methyl-5-(triisopropylsiloxy)piperidin-2-yl]-2-hydroxy-4-pentyn-1-yl 2,2-dimethylpropionate > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@@]1(CC[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N1C(=O)OCC1=CC=CC=C1)C#CC[C@@H](O)COC(=O)C(C)(C)C > InChI=1S/C33H53NO6Si/c1-23(2)41(24(3)4,25(5)6)40-30-20-19-28(17-14-18-29(35)22-38-31(36)33(8,9)10)34(26(30)7)32(37)39-21-27-15-12-11-13-16-27/h11-13,15-16,23-26,28-30,35H,18-22H2,1-10H3/t26-,28-,29+,30+/m0/s1 $$$$ Mrv1927 02072015252D 38 38 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.8860 0.3169 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8615 1.2511 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.3110 -0.4346 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0647 -0.7702 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.6699 -0.9538 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.8997 -0.6581 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1852 -1.0706 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6117 -0.8571 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1940 0.7662 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4190 0.2141 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1541 0.5887 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 1.1541 1.4137 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.8460 0.1394 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.8460 -0.6856 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 2.6710 -0.6856 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.0835 0.0288 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.3691 0.4413 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.7980 -0.3837 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.4960 0.7433 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.0835 -1.4001 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 5 9 1 0 0 0 0 5 10 1 1 0 0 0 4 11 1 0 0 0 0 11 12 2 0 0 0 0 11 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 2 0 0 0 0 9 17 1 0 0 0 0 17 18 1 0 0 0 0 18 19 1 0 0 0 0 19 20 1 1 0 0 0 19 21 1 0 0 0 0 21 22 1 0 0 0 0 22 23 1 0 0 0 0 27 24 1 0 0 0 0 24 25 1 0 0 0 0 24 26 1 0 0 0 0 26 8 1 0 0 0 0 26 28 1 0 0 0 0 28 29 1 0 0 0 0 28 30 1 0 0 0 0 26 31 1 0 0 0 0 31 32 1 0 0 0 0 31 33 1 0 0 0 0 37 34 1 0 0 0 0 34 35 1 0 0 0 0 34 36 1 0 0 0 0 34 23 1 0 0 0 0 23 38 2 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 11 8 24 25 26 27 28 29 30 31 32 33 M SBL 1 1 8 M SMT 1 OTIPS M SAP 1 1 8 2 1 M SAL 2 6 23 34 35 36 37 38 M SBL 2 1 23 M SMT 2 Piv M SAP 2 1 23 22 1 M END > UALIB-193 > (2R)-5-[(2S,5R,6S)-N-(Allyloxycarbonyl)-6-methyl-5-(triisopropylsiloxy)piperidin-2-yl]-2-hydroxypent-1-yl 2,2-dimethylpropionate > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@]1(CCC[C@@H](O)COC(=O)C(C)(C)C)CC[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N1C(=O)OCC=C > InChI=1S/C29H55NO6Si/c1-12-18-34-28(33)30-23(8)26(36-37(20(2)3,21(4)5)22(6)7)17-16-24(30)14-13-15-25(31)19-35-27(32)29(9,10)11/h12,20-26,31H,1,13-19H2,2-11H3/t23-,24-,25+,26+/m0/s1 $$$$ Mrv1927 02072015252D 38 39 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.8860 0.3169 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8615 1.2511 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 0.5429 -0.5842 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1940 0.7662 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4190 0.2141 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1541 0.5887 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 1.8686 2.6512 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.8460 0.1394 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.8460 -0.6856 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 2.5831 3.0637 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.2975 2.6512 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.2975 1.8262 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.5831 1.4137 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.8686 1.8262 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1541 1.4137 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.1921 -0.9587 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8841 -0.5094 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6191 -0.8839 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.3110 -0.4346 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0461 -0.8091 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 5 9 1 0 0 0 0 5 10 1 1 0 0 0 4 27 1 0 0 0 0 9 12 1 0 0 0 0 12 13 1 0 0 0 0 13 14 1 0 0 0 0 14 23 1 1 0 0 0 14 16 1 0 0 0 0 16 17 1 0 0 0 0 15 18 1 0 0 0 0 18 19 1 0 0 0 0 19 20 1 0 0 0 0 20 21 1 0 0 0 0 21 22 1 0 0 0 0 15 22 1 0 0 0 0 22 23 1 0 0 0 0 11 24 2 0 0 0 0 24 25 1 0 0 0 0 25 26 1 0 0 0 0 26 27 1 0 0 0 0 27 28 2 0 0 0 0 32 29 1 0 0 0 0 29 30 1 0 0 0 0 29 31 1 0 0 0 0 31 8 1 0 0 0 0 31 33 1 0 0 0 0 33 34 1 0 0 0 0 33 35 1 0 0 0 0 31 36 1 0 0 0 0 36 37 1 0 0 0 0 36 38 1 0 0 0 0 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 11 8 29 30 31 32 33 34 35 36 37 38 M SBL 1 1 8 M SMT 1 OTIPS M SAP 1 1 8 2 1 M SAL 2 6 11 24 25 26 27 28 M SBL 2 1 11 M SMT 2 Alloc M SAP 2 1 27 4 1 M SDS EXP 1 2 M SAL 3 7 15 18 19 20 21 22 23 M SBL 3 1 15 M SMT 3 OTHP M SAP 3 1 23 14 1 M SDS EXP 1 3 M END > UALIB-194 > (2S,5R,6S)-N-(Allyloxycarbonyl)-2-[(4R)-5-hydroxy-4-(tetrahydro-2H-pyran-2-yloxy)pentyl]-6-methyl-5-(triisopropylsiloxy)piperidine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@]1(CCC[C@H](CO)OC2CCCCO2)CC[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N1C(=O)OCC=C > InChI=1S/C29H55NO6Si/c1-9-18-34-29(32)30-24(8)27(36-37(21(2)3,22(4)5)23(6)7)17-16-25(30)13-12-14-26(20-31)35-28-15-10-11-19-33-28/h9,21-28,31H,1,10-20H2,2-8H3/t24-,25-,26+,27+,28?/m0/s1 $$$$ Mrv1927 02072015252D 36 37 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.8860 0.3169 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8615 1.2511 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.1940 0.7662 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4190 0.2141 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1541 0.5887 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 1.8460 0.1394 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3110 -0.4346 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1109 1.4126 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 2.5135 -0.3456 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0461 -0.8092 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.6191 -0.8838 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.8841 -0.5092 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1920 -0.9585 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.5429 -0.5839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2349 -1.0331 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1919 -1.8570 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4568 -2.2316 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.2352 -1.7824 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 5 9 1 0 0 0 0 5 10 1 1 0 0 0 4 15 1 0 0 0 0 9 11 1 0 0 0 0 11 12 1 0 0 0 0 12 13 1 0 0 0 0 13 14 1 0 0 0 0 13 16 1 1 0 0 0 14 17 3 0 0 0 0 21 18 1 0 0 0 0 18 19 1 0 0 0 0 18 20 1 0 0 0 0 20 8 1 0 0 0 0 20 22 1 0 0 0 0 22 23 1 0 0 0 0 22 24 1 0 0 0 0 20 25 1 0 0 0 0 25 26 1 0 0 0 0 25 27 1 0 0 0 0 28 15 2 0 0 0 0 15 29 1 0 0 0 0 29 30 1 0 0 0 0 30 31 1 0 0 0 0 31 32 2 0 0 0 0 32 33 1 0 0 0 0 33 34 2 0 0 0 0 34 35 1 0 0 0 0 35 36 2 0 0 0 0 31 36 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 11 8 18 19 20 21 22 23 24 25 26 27 M SBL 1 1 8 M SMT 1 OTIPS M SAP 1 1 8 2 1 M SAL 2 10 15 28 29 30 31 32 33 34 35 36 M SBL 2 1 11 M SMT 2 Cbz M SAP 2 1 15 4 1 M END > UALIB-195 > (2S,5R,6S)-N-(Allyloxycarbonyl)-2-[(4R)-4-hydroxy-5-hexynyl]-6-methyl-5-(triisopropylsiloxy)piperidine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@]1(CCC[C@@H](O)C#C)CC[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N1C(=O)OCC1=CC=CC=C1 > InChI=1S/C29H47NO4Si/c1-9-27(31)17-13-16-26-18-19-28(34-35(21(2)3,22(4)5)23(6)7)24(8)30(26)29(32)33-20-25-14-11-10-12-15-25/h1,10-12,14-15,21-24,26-28,31H,13,16-20H2,2-8H3/t24-,26-,27-,28+/m0/s1 $$$$ Mrv1927 02072015252D 39 39 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.8860 0.3169 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8615 1.2511 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.1940 0.7662 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4190 0.2141 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1541 0.5887 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3110 -0.4346 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1973 1.4126 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 1.8686 0.1762 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 2.5831 -0.2363 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.7546 -1.0433 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 3.3677 0.0186 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.0596 -0.4307 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.0164 -1.2546 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 4.8442 -0.1758 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 5.6144 -0.4714 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.3289 -0.0589 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1920 -0.9585 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8841 -0.5092 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6191 -0.8838 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.5429 -0.5839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0461 -0.8092 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 5 9 1 0 0 0 0 5 10 1 1 0 0 0 9 11 1 0 0 0 0 11 12 1 0 0 0 0 12 13 1 1 0 0 0 4 14 1 0 0 0 0 13 15 1 6 0 0 0 13 16 2 0 0 0 0 16 17 2 0 0 0 0 17 18 1 0 0 0 0 17 19 1 0 0 0 0 19 20 1 0 0 0 0 20 21 2 0 0 0 0 20 22 1 0 0 0 0 22 23 1 0 0 0 0 23 24 1 0 0 0 0 28 25 1 0 0 0 0 25 26 1 0 0 0 0 25 27 1 0 0 0 0 27 8 1 0 0 0 0 27 29 1 0 0 0 0 29 30 1 0 0 0 0 29 31 1 0 0 0 0 27 32 1 0 0 0 0 32 33 1 0 0 0 0 32 34 1 0 0 0 0 38 35 2 0 0 0 0 35 36 1 0 0 0 0 36 37 1 0 0 0 0 37 14 1 0 0 0 0 14 39 2 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 11 8 25 26 27 28 29 30 31 32 33 34 M SBL 1 1 8 M SMT 1 OTIPS M SAP 1 1 8 2 1 M SAL 2 6 14 35 36 37 38 39 M SBL 2 1 14 M SMT 2 Alloc M SAP 2 1 14 4 1 M END > UALIB-196 > Ethyl (3R)-8-[(2S,5R,6S)-N-(Allyloxycarbonyl)-6-methyl-5-(triisopropylsiloxy)piperidin-2-yl]-3,4-octadienoate > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H]C(CCC[C@@]1([H])CC[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N1C(=O)OCC=C)=[C@@]=C([H])CC(=O)OCC > InChI=1S/C29H51NO5Si/c1-10-21-34-29(32)30-25(9)27(35-36(22(3)4,23(5)6)24(7)8)20-19-26(30)17-15-13-12-14-16-18-28(31)33-11-2/h10,12,16,22-27H,1,11,13,15,17-21H2,2-9H3/t14?,25-,26-,27+/m0/s1 $$$$ Mrv1927 02072015252D 42 42 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.8860 0.3169 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8615 1.2511 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.1940 0.7662 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4190 0.2141 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1541 0.5887 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3110 -0.4346 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1973 1.4126 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 1.8686 0.1762 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 2.5831 -0.2363 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.7546 -1.0433 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 3.3677 0.0186 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.0596 -0.4307 0.0000 C 0 0 3 0 0 0 0 0 0 0 0 0 4.0164 -1.2546 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 4.8442 -0.1758 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1920 -0.9585 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8841 -0.5092 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6191 -0.8838 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.5429 -0.5839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0461 -0.8092 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 5.6288 0.0791 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.2419 -0.4731 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.0266 -0.2182 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.6395 -0.7702 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.4243 -0.5154 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 5 9 1 0 0 0 0 5 10 1 1 0 0 0 9 11 1 0 0 0 0 11 12 1 0 0 0 0 12 13 1 1 0 0 0 4 14 1 0 0 0 0 13 15 1 6 0 0 0 13 16 2 0 0 0 0 16 17 2 0 0 0 0 17 18 1 0 0 0 0 17 19 1 0 0 0 0 19 20 1 0 0 0 0 20 21 1 4 0 0 0 20 22 1 0 0 0 0 26 23 1 0 0 0 0 23 24 1 0 0 0 0 23 25 1 0 0 0 0 25 8 1 0 0 0 0 25 27 1 0 0 0 0 27 28 1 0 0 0 0 27 29 1 0 0 0 0 25 30 1 0 0 0 0 30 31 1 0 0 0 0 30 32 1 0 0 0 0 36 33 2 0 0 0 0 33 34 1 0 0 0 0 34 35 1 0 0 0 0 35 14 1 0 0 0 0 14 37 2 0 0 0 0 22 38 1 0 0 0 0 38 39 1 0 0 0 0 39 40 1 0 0 0 0 40 41 1 0 0 0 0 41 42 1 0 0 0 0 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 11 8 23 24 25 26 27 28 29 30 31 32 M SBL 1 1 8 M SMT 1 OTIPS M SAP 1 1 8 2 1 M SAL 2 6 14 33 34 35 36 37 M SBL 2 1 14 M SMT 2 Alloc M SAP 2 1 14 4 1 M SAL 3 6 22 38 39 40 41 42 M SBL 3 1 22 M SMT 3 Hex M SAP 3 1 22 20 1 M END > UALIB-197 > (2S,5R,6S)-N-(Allyloxycarbonyl)-2-[(4R,8RS)-8-hydroxy-4,5-tetradecadienyl]-6-methyl-5-(triisopropylsiloxy)piperidine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H]C(CCC[C@@]1([H])CC[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N1C(=O)OCC=C)=[C@@]=C([H])CC(O)CCCCCC > InChI=1S/C33H61NO4Si/c1-10-12-13-18-21-31(35)22-19-16-14-15-17-20-30-23-24-32(29(9)34(30)33(36)37-25-11-2)38-39(26(3)4,27(5)6)28(7)8/h11,14,19,26-32,35H,2,10,12-13,15,17-18,20-25H2,1,3-9H3/t16?,29-,30-,31?,32+/m0/s1 $$$$ Mrv1927 02072015252D 49 49 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.8860 0.3169 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8615 1.2511 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.1940 0.7662 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4190 0.2141 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1541 0.5887 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3110 -0.4346 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1973 1.4126 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 1.8686 0.1762 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 2.5831 -0.2363 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.7546 -1.0433 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 3.3677 0.0186 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.0596 -0.4307 0.0000 C 0 0 3 0 0 0 0 0 0 0 0 0 4.0164 -1.2546 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 4.8442 -0.1758 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1920 -0.9585 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8841 -0.5092 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6191 -0.8838 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.5429 -0.5839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0461 -0.8092 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 5.6288 0.0791 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.2419 -0.4731 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.0266 -0.2182 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.6395 -0.7702 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.4243 -0.5154 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.7971 -2.1216 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.9732 -2.0784 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 5.2464 -1.4297 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.1494 -2.0353 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.7000 -2.7272 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.9301 -2.9023 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.1950 -3.2768 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 5 9 1 0 0 0 0 5 10 1 1 0 0 0 9 11 1 0 0 0 0 11 12 1 0 0 0 0 12 13 1 1 0 0 0 4 14 1 0 0 0 0 13 15 1 6 0 0 0 13 16 2 0 0 0 0 16 17 2 0 0 0 0 17 18 1 0 0 0 0 17 19 1 0 0 0 0 19 20 1 0 0 0 0 20 21 1 4 0 0 0 20 22 1 0 0 0 0 26 23 1 0 0 0 0 23 24 1 0 0 0 0 23 25 1 0 0 0 0 25 8 1 0 0 0 0 25 27 1 0 0 0 0 27 28 1 0 0 0 0 27 29 1 0 0 0 0 25 30 1 0 0 0 0 30 31 1 0 0 0 0 30 32 1 0 0 0 0 36 33 2 0 0 0 0 33 34 1 0 0 0 0 34 35 1 0 0 0 0 35 14 1 0 0 0 0 14 37 2 0 0 0 0 22 38 1 0 0 0 0 38 39 1 0 0 0 0 39 40 1 0 0 0 0 40 41 1 0 0 0 0 41 42 1 0 0 0 0 45 43 1 0 0 0 0 43 44 1 0 0 0 0 44 21 1 0 0 0 0 44 46 1 0 0 0 0 46 47 1 0 0 0 0 44 48 1 0 0 0 0 48 49 1 0 0 0 0 M STY 4 1 SUP 2 SUP 3 SUP 4 SUP M SAL 1 11 8 23 24 25 26 27 28 29 30 31 32 M SBL 1 1 8 M SMT 1 OTIPS M SAP 1 1 8 2 1 M SAL 2 6 14 33 34 35 36 37 M SBL 2 1 14 M SMT 2 Alloc M SAP 2 1 14 4 1 M SAL 3 6 22 38 39 40 41 42 M SBL 3 1 22 M SMT 3 Hex M SAP 3 1 22 20 1 M SAL 4 8 21 43 44 45 46 47 48 49 M SBL 4 1 21 M SMT 4 OTES M SAP 4 1 21 20 1 M END > UALIB-198 > (2S,5R,6S)-N-(Allyloxycarbonyl)-6-Mehtyl-2-[(4R,8RS)-8-(triethylsiloxy)-4,5-tetradecadienyl]-5-(triisopropylsiloxy)piperidine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H]C(CCC[C@@]1([H])CC[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N1C(=O)OCC=C)=[C@@]=C([H])CC(CCCCCC)O[Si](CC)(CC)CC > InChI=1S/C39H75NO4Si2/c1-13-18-19-24-27-37(43-45(15-3,16-4)17-5)28-25-22-20-21-23-26-36-29-30-38(35(12)40(36)39(41)42-31-14-2)44-46(32(6)7,33(8)9)34(10)11/h14,20,25,32-38H,2,13,15-19,21,23-24,26-31H2,1,3-12H3/t22?,35-,36-,37?,38+/m0/s1 $$$$ Mrv1927 02072015252D 42 42 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.8860 0.3169 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1940 0.7662 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4190 0.2141 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1541 0.5887 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1973 1.4126 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 1.8686 0.1762 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 2.5831 -0.2363 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.7546 -1.0433 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 3.3677 0.0186 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.0596 -0.4307 0.0000 C 0 0 3 0 0 0 0 0 0 0 0 0 4.0164 -1.2546 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 4.8442 -0.1758 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.6288 0.0791 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.2419 -0.4731 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.0266 -0.2182 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.6395 -0.7702 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.4243 -0.5154 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.7971 -2.1216 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.9732 -2.0784 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 5.2464 -1.4297 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.1494 -2.0353 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.7000 -2.7272 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.9301 -2.9023 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.1950 -3.2768 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 5 9 1 6 0 0 0 9 10 1 0 0 0 0 10 11 1 0 0 0 0 11 12 1 1 0 0 0 12 13 1 6 0 0 0 12 14 2 0 0 0 0 14 15 2 0 0 0 0 15 16 1 0 0 0 0 15 17 1 0 0 0 0 17 18 1 0 0 0 0 18 19 1 4 0 0 0 18 20 1 0 0 0 0 24 21 1 0 0 0 0 21 22 1 0 0 0 0 21 23 1 0 0 0 0 23 8 1 0 0 0 0 23 25 1 0 0 0 0 25 26 1 0 0 0 0 25 27 1 0 0 0 0 23 28 1 0 0 0 0 28 29 1 0 0 0 0 28 30 1 0 0 0 0 20 31 1 0 0 0 0 31 32 1 0 0 0 0 32 33 1 0 0 0 0 33 34 1 0 0 0 0 34 35 1 0 0 0 0 38 36 1 0 0 0 0 36 37 1 0 0 0 0 37 19 1 0 0 0 0 37 39 1 0 0 0 0 39 40 1 0 0 0 0 37 41 1 0 0 0 0 41 42 1 0 0 0 0 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 11 8 21 22 23 24 25 26 27 28 29 30 M SBL 1 1 8 M SMT 1 OTIPS M SAP 1 1 8 2 1 M SAL 2 6 20 31 32 33 34 35 M SBL 2 1 20 M SMT 2 Hex M SAP 2 1 20 18 1 M SAL 3 8 19 36 37 38 39 40 41 42 M SBL 3 1 19 M SMT 3 OTES M SAP 3 1 19 18 1 M END > UALIB-199 > (2S,5R,6S)-6-Methyl-2-[(4R,8RS)-8-(triethylsiloxy)-4,5-tetradecadienyl]-5-(triisopropylsiloxy)piperidine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H]C(CCC[C@H]1CC[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N1)=[C@@]=C([H])CC(CCCCCC)O[Si](CC)(CC)CC > InChI=1S/C35H71NO2Si2/c1-12-16-17-22-25-34(37-39(13-2,14-3)15-4)26-23-20-18-19-21-24-33-27-28-35(32(11)36-33)38-40(29(5)6,30(7)8)31(9)10/h18,23,29-36H,12-17,19,21-22,24-28H2,1-11H3/t20?,32-,33-,34?,35+/m0/s1 $$$$ Mrv1927 02072015252D 82 84 0 0 1 0 999 V2000 -3.6090 2.7777 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -3.6090 3.6027 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.8945 4.0152 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.1801 3.6027 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.1801 2.7777 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -2.8945 2.3652 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.4656 4.0152 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7511 3.6027 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7511 2.7777 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4656 2.3652 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.8945 1.5402 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4656 1.5402 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7511 1.1277 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7511 0.3027 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0367 -0.1098 0.0000 C 0 0 3 0 0 0 0 0 0 0 0 0 -0.0367 -0.9348 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6778 0.3027 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.3235 2.3652 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -11.6154 2.4503 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -11.6154 3.2753 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -10.9009 3.6878 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -10.1865 3.2753 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -10.1865 2.4503 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -9.4720 3.6878 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -10.9009 2.0378 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -8.7575 3.2753 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -8.7575 2.4503 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -9.4720 2.0378 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -10.9009 1.2128 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -12.3299 2.0378 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -9.4720 1.2128 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -8.7575 0.8003 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -8.7575 -0.0247 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -8.0430 -0.4372 0.0000 C 0 0 3 0 0 0 0 0 0 0 0 0 -8.0430 -1.2622 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -7.3286 -0.0247 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -10.2727 4.0958 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.2663 4.4232 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -5.4505 2.6672 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.2755 2.6672 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0380 1.9527 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -5.0380 3.3817 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6255 1.2382 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0380 0.5238 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.8005 1.2382 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7524 1.5402 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7524 0.7152 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.4669 1.9527 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.8048 0.0007 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3923 0.7152 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 1.3923 -0.7137 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.9798 1.4297 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3923 2.1442 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1067 1.1277 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1067 1.9527 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0367 -1.7598 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6778 -2.1723 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6778 -2.9973 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3923 -3.4098 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3923 -4.2348 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -13.4568 2.3400 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -14.2818 2.3400 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -13.0443 1.6253 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -13.0441 3.0542 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -12.6320 0.9108 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -13.0445 0.1963 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -11.8070 0.9108 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -13.7588 1.2130 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -13.7590 0.3880 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -14.4733 1.6255 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.2016 -0.3265 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.6141 0.3878 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -6.6139 -1.0412 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -7.0268 1.1023 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.6143 1.8167 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.8998 0.8005 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.8998 1.6255 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -8.0430 -2.0872 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -7.3286 -2.4997 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -7.3286 -3.3247 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.6141 -3.7372 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.6141 -4.5622 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 1 6 1 0 0 0 0 6 5 1 0 0 0 0 4 7 1 0 0 0 0 7 8 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 10 5 1 0 0 0 0 6 11 1 1 0 0 0 10 12 1 6 0 0 0 12 13 2 0 0 0 0 13 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 15 17 1 4 0 0 0 1 18 1 6 0 0 0 19 20 1 0 0 0 0 20 21 1 0 0 0 0 21 22 1 0 0 0 0 22 23 1 0 0 0 0 22 24 1 0 0 0 0 23 25 1 0 0 0 0 25 19 1 0 0 0 0 24 26 1 0 0 0 0 26 27 1 0 0 0 0 27 28 1 0 0 0 0 28 23 1 0 0 0 0 25 29 1 1 0 0 0 19 30 1 6 0 0 0 28 31 1 1 0 0 0 31 32 2 0 0 0 0 32 33 1 0 0 0 0 33 34 1 0 0 0 0 34 35 1 0 0 0 0 34 36 1 4 0 0 0 22 37 1 1 0 0 0 4 38 1 1 0 0 0 42 39 1 0 0 0 0 39 40 1 0 0 0 0 39 41 1 0 0 0 0 41 18 1 0 0 0 0 41 43 1 0 0 0 0 43 44 1 0 0 0 0 43 45 1 0 0 0 0 41 46 1 0 0 0 0 46 47 1 0 0 0 0 46 48 1 0 0 0 0 51 49 1 0 0 0 0 49 50 1 0 0 0 0 50 17 1 0 0 0 0 50 52 1 0 0 0 0 52 53 1 0 0 0 0 50 54 1 0 0 0 0 54 55 1 0 0 0 0 16 56 1 0 0 0 0 56 57 1 0 0 0 0 57 58 1 0 0 0 0 58 59 1 0 0 0 0 59 60 1 0 0 0 0 64 61 1 0 0 0 0 61 62 1 0 0 0 0 61 63 1 0 0 0 0 63 30 1 0 0 0 0 63 65 1 0 0 0 0 65 66 1 0 0 0 0 65 67 1 0 0 0 0 63 68 1 0 0 0 0 68 69 1 0 0 0 0 68 70 1 0 0 0 0 73 71 1 0 0 0 0 71 72 1 0 0 0 0 72 36 1 0 0 0 0 72 74 1 0 0 0 0 74 75 1 0 0 0 0 72 76 1 0 0 0 0 76 77 1 0 0 0 0 35 78 1 0 0 0 0 78 79 1 0 0 0 0 79 80 1 0 0 0 0 80 81 1 0 0 0 0 81 82 1 0 0 0 0 M STY 6 1 SUP 2 SUP 3 SUP 4 SUP 5 SUP 6 SUP M SAL 1 11 18 39 40 41 42 43 44 45 46 47 48 M SBL 1 1 19 M SMT 1 OTIPS M SAP 1 1 18 1 1 M SAL 2 8 17 49 50 51 52 53 54 55 M SBL 2 1 18 M SMT 2 OTES M SAP 2 1 17 15 1 M SAL 3 6 16 56 57 58 59 60 M SBL 3 1 17 M SMT 3 Hex M SAP 3 1 16 15 1 M SAL 4 11 30 61 62 63 64 65 66 67 68 69 70 M SBL 4 1 32 M SMT 4 OTIPS M SAP 4 1 30 19 1 M SAL 5 8 36 71 72 73 74 75 76 77 M SBL 5 1 38 M SMT 5 OTES M SAP 5 1 36 34 1 M SAL 6 6 35 78 79 80 81 82 M SBL 6 1 37 M SMT 6 Hex M SAP 6 1 35 34 1 M END > UALIB-200 > (4S,6S,7R,9aS)-Octahydro-6-methyl-4-[(1E,4RS)-4-(triethylsiloxy)-1-decenyl]-7-(triisopropylsiloxy)-4H-quinolizine and (4R,6S,7R,9aS)-Octahydro-6-methyl-4-[1E,4RS)-4-(triethylsiloxy)-1-decenyl]-7-(triisopropylsiloxy)-4H-quinolizine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@@]12CCC[C@@H](\C=C\CC(CCCCCC)O[Si](CC)(CC)CC)N1[C@@H](C)[C@@H](CC2)O[Si](C(C)C)(C(C)C)C(C)C.[H][C@@]12CCC[C@H](\C=C\CC(CCCCCC)O[Si](CC)(CC)CC)N1[C@@H](C)[C@@H](CC2)O[Si](C(C)C)(C(C)C)C(C)C > InChI=1S/2C35H71NO2Si2/c2*1-12-16-17-18-24-34(37-39(13-2,14-3)15-4)25-20-23-32-21-19-22-33-26-27-35(31(11)36(32)33)38-40(28(5)6,29(7)8)30(9)10/h2*20,23,28-35H,12-19,21-22,24-27H2,1-11H3/b2*23-20+/t31-,32+,33-,34?,35+;31-,32-,33-,34?,35+/m00/s1 $$$$ Mrv1927 02072015252D 34 35 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2679 -0.4357 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.6004 -0.9207 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8859 -0.5082 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8428 0.3157 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -0.8851 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -1.7101 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6272 -2.1950 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6272 -3.0200 0.0000 C 0 0 3 0 0 0 0 0 0 0 0 0 -2.9598 -3.5049 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2453 -3.0924 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6619 -3.6758 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0488 -3.1237 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3814 -3.6087 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.3537 -3.2341 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8615 1.2511 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -4.2403 -3.5720 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 4 9 1 0 0 0 0 9 10 1 0 0 0 0 10 11 1 0 0 0 0 11 12 1 0 0 0 0 12 5 1 0 0 0 0 9 13 1 1 0 0 0 13 14 2 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 17 18 1 0 0 0 0 18 19 1 0 0 0 0 19 20 1 0 0 0 0 20 21 1 0 0 0 0 21 22 1 0 0 0 0 5 23 1 1 0 0 0 16 24 1 4 0 0 0 28 25 1 0 0 0 0 25 26 1 0 0 0 0 25 27 1 0 0 0 0 27 8 1 0 0 0 0 27 29 1 0 0 0 0 29 30 1 0 0 0 0 29 31 1 0 0 0 0 27 32 1 0 0 0 0 32 33 1 0 0 0 0 32 34 1 0 0 0 0 M STY 1 1 SUP M SAL 1 11 8 25 26 27 28 29 30 31 32 33 34 M SBL 1 1 8 M SMT 1 OTIPS M SAP 1 1 8 2 1 M END > UALIB-201 > (1E,4RS)-1-[(4S,6S,7R,9aS)-Octahydro-6-methyl-5-(triisopropylsiloxy)-4H-quinolizin-4-yl]-1-decen-4-ol > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@@]12CCC[C@@H](\C=C\CC(O)CCCCCC)N1[C@@H](C)[C@@H](CC2)O[Si](C(C)C)(C(C)C)C(C)C > InChI=1S/C29H57NO2Si/c1-9-10-11-12-18-28(31)19-14-17-26-15-13-16-27-20-21-29(25(8)30(26)27)32-33(22(2)3,23(4)5)24(6)7/h14,17,22-29,31H,9-13,15-16,18-21H2,1-8H3/b17-14+/t25-,26-,27-,28?,29+/m0/s1 $$$$ Mrv1927 02072015252D 33 34 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2679 -0.4357 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.6004 -0.9207 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8859 -0.5082 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8428 0.3157 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -0.8851 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -1.7101 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6272 -2.1950 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6272 -3.0200 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8615 1.2511 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -4.2683 -3.5392 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3546 -4.3597 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7134 -4.8788 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9432 -4.5832 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3021 -5.1024 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6102 -4.6531 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 4 9 1 0 0 0 0 9 10 1 0 0 0 0 10 11 1 0 0 0 0 11 12 1 0 0 0 0 12 5 1 0 0 0 0 9 13 1 1 0 0 0 13 14 2 0 0 0 0 14 15 1 0 0 0 0 15 16 2 0 0 0 0 5 17 1 1 0 0 0 16 18 1 0 0 0 0 18 19 1 0 0 0 0 19 20 1 0 0 0 0 20 21 1 0 0 0 0 21 22 1 0 0 0 0 22 23 1 0 0 0 0 27 24 1 0 0 0 0 24 25 1 0 0 0 0 24 26 1 0 0 0 0 26 8 1 0 0 0 0 26 28 1 0 0 0 0 28 29 1 0 0 0 0 28 30 1 0 0 0 0 26 31 1 0 0 0 0 31 32 1 0 0 0 0 31 33 1 0 0 0 0 M STY 1 1 SUP M SAL 1 11 8 24 25 26 27 28 29 30 31 32 33 M SBL 1 1 8 M SMT 1 OTIPS M SAP 1 1 8 2 1 M END > UALIB-202 > (4S,6S,7R,9aS)-Octahydro-6-methyl-4-[(1E,3E)-1,3-decadienyl]-7-(triisopropylsiloxy)-4H-quinolizine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@@]12CCC[C@@H](\C=C\C=C\CCCCCC)N1[C@@H](C)[C@@H](CC2)O[Si](C(C)C)(C(C)C)C(C)C > InChI=1S/C29H55NOSi/c1-9-10-11-12-13-14-15-16-18-27-19-17-20-28-21-22-29(26(8)30(27)28)31-32(23(2)3,24(4)5)25(6)7/h14-16,18,23-29H,9-13,17,19-22H2,1-8H3/b15-14+,18-16+/t26-,27+,28-,29+/m0/s1 $$$$ Mrv1927 02072015252D 23 24 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2679 -0.4357 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.6004 -0.9207 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8859 -0.5082 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8428 0.3157 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -0.8851 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -1.7101 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6272 -2.1950 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6272 -3.0200 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8615 1.2511 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -4.2683 -3.5392 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3546 -4.3597 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7134 -4.8788 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9432 -4.5832 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3021 -5.1024 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6102 -4.6531 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 4 9 1 0 0 0 0 9 10 1 0 0 0 0 10 11 1 0 0 0 0 11 12 1 0 0 0 0 12 5 1 0 0 0 0 9 13 1 1 0 0 0 13 14 2 0 0 0 0 14 15 1 0 0 0 0 15 16 2 0 0 0 0 5 17 1 1 0 0 0 16 18 1 0 0 0 0 18 19 1 0 0 0 0 19 20 1 0 0 0 0 20 21 1 0 0 0 0 21 22 1 0 0 0 0 22 23 1 0 0 0 0 M END > UALIB-203 > Clavepictine B > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@@]12CCC[C@@H](\C=C\C=C\CCCCCC)N1[C@@H](C)[C@H](O)CC2 > InChI=1S/C20H35NO/c1-3-4-5-6-7-8-9-10-12-18-13-11-14-19-15-16-20(22)17(2)21(18)19/h8-10,12,17-20,22H,3-7,11,13-16H2,1-2H3/b9-8+,12-10+/t17-,18+,19-,20+/m0/s1 $$$$ Mrv1927 02072015252D 26 27 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2679 -0.4357 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.6004 -0.9207 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8859 -0.5082 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8428 0.3157 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -0.8851 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -1.7101 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6272 -2.1950 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6272 -3.0200 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8615 1.2511 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -4.2683 -3.5392 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3546 -4.3597 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7134 -4.8788 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9432 -4.5832 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3021 -5.1024 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6102 -4.6531 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3230 3.3493 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.1012 2.1509 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 4 9 1 0 0 0 0 9 10 1 0 0 0 0 10 11 1 0 0 0 0 11 12 1 0 0 0 0 12 5 1 0 0 0 0 9 13 1 1 0 0 0 13 14 2 0 0 0 0 14 15 1 0 0 0 0 15 16 2 0 0 0 0 5 17 1 1 0 0 0 16 18 1 0 0 0 0 18 19 1 0 0 0 0 19 20 1 0 0 0 0 20 21 1 0 0 0 0 21 22 1 0 0 0 0 22 23 1 0 0 0 0 25 24 1 0 0 0 0 24 8 1 0 0 0 0 24 26 2 0 0 0 0 M STY 1 1 SUP M SAL 1 4 8 24 25 26 M SBL 1 1 8 M SMT 1 OAc M SAP 1 1 8 2 1 M END > UALIB-204 > Clavepictine A > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@@]12CCC[C@@H](\C=C\C=C\CCCCCC)N1[C@@H](C)[C@@H](CC2)OC(C)=O > InChI=1S/C22H37NO2/c1-4-5-6-7-8-9-10-11-13-20-14-12-15-21-16-17-22(25-19(3)24)18(2)23(20)21/h9-11,13,18,20-22H,4-8,12,14-17H2,1-3H3/b10-9+,13-11+/t18-,20+,21-,22+/m0/s1 $$$$ Mrv1927 02072015252D 28 29 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2247 -0.4346 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9166 -0.8839 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.4896 -0.8091 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7977 -0.3598 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0626 -0.7344 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6293 -0.2850 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3644 -0.6596 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4075 -1.4834 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7156 -1.9328 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0194 -1.5582 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 2 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 4 9 1 0 0 0 0 13 10 1 0 0 0 0 10 11 1 0 0 0 0 10 12 1 0 0 0 0 12 8 1 0 0 0 0 12 14 1 0 0 0 0 14 15 1 0 0 0 0 14 16 1 0 0 0 0 12 17 1 0 0 0 0 17 18 1 0 0 0 0 17 19 1 0 0 0 0 20 9 2 0 0 0 0 9 21 1 0 0 0 0 21 22 1 0 0 0 0 22 23 1 0 0 0 0 23 24 2 0 0 0 0 24 25 1 0 0 0 0 25 26 2 0 0 0 0 26 27 1 0 0 0 0 27 28 2 0 0 0 0 23 28 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 11 8 10 11 12 13 14 15 16 17 18 19 M SBL 1 1 8 M SMT 1 OTIPS M SAP 1 1 8 2 1 M SAL 2 10 9 20 21 22 23 24 25 26 27 28 M SBL 2 1 9 M SMT 2 Cbz M SAP 2 1 9 4 1 M END > UALIB-205 > (2S,3R)-N-(Benzyloxycarbonyl)-2-methyl-3-(triisopropylsiloxy)-1,2,3,4-tetrahydropyridine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CC(C)[Si](O[C@@H]1CC=CN([C@H]1C)C(=O)OCC1=CC=CC=C1)(C(C)C)C(C)C > InChI=1S/C23H37NO3Si/c1-17(2)28(18(3)4,19(5)6)27-22-14-11-15-24(20(22)7)23(25)26-16-21-12-9-8-10-13-21/h8-13,15,17-20,22H,14,16H2,1-7H3/t20-,22+/m0/s1 $$$$ Mrv1927 02072015252D 35 36 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2247 -0.4346 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.9403 0.2497 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.2258 0.6622 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4153 0.1431 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.0828 0.6280 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.7972 0.2155 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.4647 0.7004 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.1321 0.2155 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9166 -0.8839 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.4896 -0.8091 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7977 -0.3598 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0626 -0.7344 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6293 -0.2850 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3644 -0.6596 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4075 -1.4834 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7156 -1.9328 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0194 -1.5582 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 4 9 1 0 0 0 0 6 5 2 0 0 0 0 5 10 1 0 0 0 0 10 11 1 0 0 0 0 11 12 1 0 0 0 0 12 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 20 17 1 0 0 0 0 17 18 1 0 0 0 0 17 19 1 0 0 0 0 19 8 1 0 0 0 0 19 21 1 0 0 0 0 21 22 1 0 0 0 0 21 23 1 0 0 0 0 19 24 1 0 0 0 0 24 25 1 0 0 0 0 24 26 1 0 0 0 0 27 9 2 0 0 0 0 9 28 1 0 0 0 0 28 29 1 0 0 0 0 29 30 1 0 0 0 0 30 31 2 0 0 0 0 31 32 1 0 0 0 0 32 33 2 0 0 0 0 33 34 1 0 0 0 0 34 35 2 0 0 0 0 30 35 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 11 8 17 18 19 20 21 22 23 24 25 26 M SBL 1 1 7 M SMT 1 OTIPS M SAP 1 1 8 2 1 M SAL 2 10 9 27 28 29 30 31 32 33 34 35 M SBL 2 1 8 M SMT 2 Cbz M SAP 2 1 9 4 1 M END > UALIB-206 > (2S,3R)-N-(Benzyloxycarbonyl)-6-heptyl-2-methyl-3-(triisopropylsiloxy)-1,2,3,4-tetrahydropyridine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CCCCCCCC1=CC[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N1C(=O)OCC1=CC=CC=C1 > InChI=1S/C30H51NO3Si/c1-9-10-11-12-16-19-28-20-21-29(34-35(23(2)3,24(4)5)25(6)7)26(8)31(28)30(32)33-22-27-17-14-13-15-18-27/h13-15,17-18,20,23-26,29H,9-12,16,19,21-22H2,1-8H3/t26-,29+/m0/s1 $$$$ Mrv1927 02072015252D 25 25 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2247 -0.4346 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1058 0.0895 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.2470 0.3321 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3484 -1.0517 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4896 -0.8091 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7977 -0.3598 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9166 -0.8839 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 4 9 1 0 0 0 0 13 10 1 0 0 0 0 10 11 1 0 0 0 0 10 12 1 0 0 0 0 12 8 1 0 0 0 0 12 14 1 0 0 0 0 14 15 1 0 0 0 0 14 16 1 0 0 0 0 12 17 1 0 0 0 0 17 18 1 0 0 0 0 17 19 1 0 0 0 0 24 20 1 0 0 0 0 24 21 1 0 0 0 0 24 22 1 0 0 0 0 24 23 1 0 0 0 0 23 9 1 0 0 0 0 9 25 2 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 11 8 10 11 12 13 14 15 16 17 18 19 M SBL 1 1 8 M SMT 1 OTIPS M SAP 1 1 8 2 1 M SAL 2 7 9 20 21 22 23 24 25 M SBL 2 1 9 M SMT 2 Boc M SAP 2 1 9 4 1 M END > UALIB-207 > (2S,3R)-N-(t-Butyloxycarbonyl)-2-methyl-3-(triisopropyl)piperidine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CC(C)[Si](O[C@@H]1CCCN([C@H]1C)C(=O)OC(C)(C)C)(C(C)C)C(C)C > InChI=1S/C20H41NO3Si/c1-14(2)25(15(3)4,16(5)6)24-18-12-11-13-21(17(18)7)19(22)23-20(8,9)10/h14-18H,11-13H2,1-10H3/t17-,18+/m0/s1 $$$$ Mrv1927 02072015252D 28 28 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2247 -0.4346 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8389 0.3893 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7957 1.2132 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.4264 -0.3252 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1058 0.0895 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.2470 0.3321 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3484 -1.0517 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4896 -0.8091 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.7977 -0.3598 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9166 -0.8839 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 4 9 1 0 0 0 0 5 10 1 6 0 0 0 10 11 2 0 0 0 0 10 12 1 0 0 0 0 16 13 1 0 0 0 0 13 14 1 0 0 0 0 13 15 1 0 0 0 0 15 8 1 0 0 0 0 15 17 1 0 0 0 0 17 18 1 0 0 0 0 17 19 1 0 0 0 0 15 20 1 0 0 0 0 20 21 1 0 0 0 0 20 22 1 0 0 0 0 27 23 1 0 0 0 0 27 24 1 0 0 0 0 27 25 1 0 0 0 0 27 26 1 0 0 0 0 26 9 1 0 0 0 0 9 28 2 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 11 8 13 14 15 16 17 18 19 20 21 22 M SBL 1 1 8 M SMT 1 OTIPS M SAP 1 1 8 2 1 M SAL 2 7 9 23 24 25 26 27 28 M SBL 2 1 9 M SMT 2 Boc M SAP 2 1 9 4 1 M END > UALIB-208 > (2R,5R,6S)-N-(t-Butyloxycarbonyl)-6-methyl-5-(triisopropylsiloxy)piperidine-2-carboxaldehyde > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H]C(=O)[C@H]1CC[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N1C(=O)OC(C)(C)C > InChI=1S/C21H41NO4Si/c1-14(2)27(15(3)4,16(5)6)26-19-12-11-18(13-23)22(17(19)7)20(24)25-21(8,9)10/h13-19H,11-12H2,1-10H3/t17-,18+,19+/m0/s1 $$$$ Mrv1927 02072015252D 16 15 0 0 1 0 999 V2000 -3.0134 0.7589 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2783 1.1335 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.6109 0.6485 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -0.8758 1.0231 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.2346 0.5039 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3215 1.9573 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.5246 -0.1719 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.3646 -0.5142 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0565 -0.0649 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.4076 -1.3380 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7053 1.2082 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.4065 -0.0153 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.2776 -0.8301 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.9188 -1.3491 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7899 -2.1640 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4311 -2.6832 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 2 6 1 6 0 0 0 3 7 1 6 0 0 0 10 8 1 0 0 0 0 8 9 1 0 0 0 0 9 1 1 0 0 0 0 1 11 2 0 0 0 0 5 12 1 0 0 0 0 12 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 5 1 8 9 10 11 M SBL 1 1 1 M SMT 1 CO2Et M SAP 1 1 1 2 1 M SAL 2 6 5 12 13 14 15 16 M SBL 2 1 4 M SMT 2 Hex M SAP 2 1 5 4 1 M END > UALIB-209 > Ethyl (2R,3S)-2,3-dihydroxydecanoate > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CCCCCCC[C@H](O)[C@@H](O)C(=O)OCC > InChI=1S/C12H24O4/c1-3-5-6-7-8-9-10(13)11(14)12(15)16-4-2/h10-11,13-14H,3-9H2,1-2H3/t10-,11-/m0/s1 $$$$ Mrv1927 02072015252D 26 25 0 0 1 0 999 V2000 -3.0134 0.7589 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2783 1.1335 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.6109 0.6485 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -0.8758 1.0231 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.2346 0.5039 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3215 1.9573 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.5246 -0.1719 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.3646 -0.5142 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0565 -0.0649 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.4076 -1.3380 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7053 1.2082 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.4065 -0.0153 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.2776 -0.8301 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.9188 -1.3491 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7899 -2.1640 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4311 -2.6832 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6178 -0.9061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1328 -1.5734 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4383 -0.9924 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -0.2824 -0.1523 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2588 -1.0787 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5942 -1.8324 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.7438 -0.4114 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.3520 -1.8129 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0193 -2.2979 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.5982 -2.1484 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 2 6 1 6 0 0 0 3 7 1 6 0 0 0 10 8 1 0 0 0 0 8 9 1 0 0 0 0 9 1 1 0 0 0 0 1 11 2 0 0 0 0 5 12 1 0 0 0 0 12 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 20 17 1 0 0 0 0 17 18 1 0 0 0 0 17 19 1 0 0 0 0 19 7 1 0 0 0 0 19 21 1 0 0 0 0 21 22 1 0 0 0 0 21 23 1 0 0 0 0 19 24 1 0 0 0 0 24 25 1 0 0 0 0 24 26 1 0 0 0 0 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 5 1 8 9 10 11 M SBL 1 1 1 M SMT 1 CO2Et M SAP 1 1 1 2 1 M SAL 2 6 5 12 13 14 15 16 M SBL 2 1 4 M SMT 2 Hex M SAP 2 1 5 4 1 M SAL 3 11 7 17 18 19 20 21 22 23 24 25 26 M SBL 3 1 6 M SMT 3 OTIPS M SAP 3 1 7 3 1 M END > UALIB-210 > Ethyl (2R,3S)-2-Hydroxy-3-(triisopropylsiloxy)decanoate > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CCCCCCC[C@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@@H](O)C(=O)OCC > InChI=1S/C21H44O4Si/c1-9-11-12-13-14-15-19(20(22)21(23)24-10-2)25-26(16(3)4,17(5)6)18(7)8/h16-20,22H,9-15H2,1-8H3/t19-,20-/m0/s1 $$$$ Mrv1927 02072015252D 32 32 0 0 1 0 999 V2000 -3.0134 0.7589 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2783 1.1335 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.6109 0.6485 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -0.8758 1.0231 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.2346 0.5039 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3215 1.9573 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.5246 -0.1719 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.3646 -0.5142 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0565 -0.0649 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.4076 -1.3380 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7053 1.2082 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.4065 -0.0153 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.2776 -0.8301 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.9188 -1.3491 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7899 -2.1640 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4311 -2.6832 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6178 -0.9061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1328 -1.5734 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4383 -0.9924 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -0.2824 -0.1523 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2588 -1.0787 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5942 -1.8324 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.7438 -0.4114 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.3520 -1.8129 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0193 -2.2979 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.5982 -2.1484 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.1429 3.9796 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.4510 4.4289 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7159 4.0544 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6728 3.2305 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.3647 2.7812 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0997 3.1558 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 2 6 1 6 0 0 0 3 7 1 6 0 0 0 10 8 1 0 0 0 0 8 9 1 0 0 0 0 9 1 1 0 0 0 0 1 11 2 0 0 0 0 5 12 1 0 0 0 0 12 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 20 17 1 0 0 0 0 17 18 1 0 0 0 0 17 19 1 0 0 0 0 19 7 1 0 0 0 0 19 21 1 0 0 0 0 21 22 1 0 0 0 0 21 23 1 0 0 0 0 19 24 1 0 0 0 0 24 25 1 0 0 0 0 24 26 1 0 0 0 0 32 27 1 0 0 0 0 27 28 1 0 0 0 0 28 29 1 0 0 0 0 29 30 1 0 0 0 0 30 31 1 0 0 0 0 32 31 1 0 0 0 0 31 6 1 0 0 0 0 M STY 4 1 SUP 2 SUP 3 SUP 4 SUP M SAL 1 5 1 8 9 10 11 M SBL 1 1 1 M SMT 1 CO2Et M SAP 1 1 1 2 1 M SAL 2 6 5 12 13 14 15 16 M SBL 2 1 4 M SMT 2 Hex M SAP 2 1 5 4 1 M SAL 3 11 7 17 18 19 20 21 22 23 24 25 26 M SBL 3 1 6 M SMT 3 OTIPS M SAP 3 1 7 3 1 M SAL 4 7 6 27 28 29 30 31 32 M SBL 4 1 5 M SMT 4 OTHP M SAP 4 1 6 2 1 M END > UALIB-211 > Ethyl (2R,3S)-2-(tetrahydro-2H-pyran-2-yloxy)-3-(triisopropylsiloxy)decanoate > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CCCCCCC[C@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@@H](OC1CCCCO1)C(=O)OCC > InChI=1S/C26H52O5Si/c1-9-11-12-13-14-17-23(31-32(20(3)4,21(5)6)22(7)8)25(26(27)28-10-2)30-24-18-15-16-19-29-24/h20-25H,9-19H2,1-8H3/t23-,24?,25-/m0/s1 $$$$ Mrv1927 02072015252D 28 28 0 0 1 0 999 V2000 -3.0134 0.7589 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2783 1.1335 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.6109 0.6485 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -0.8758 1.0231 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.2346 0.5039 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3215 1.9573 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.5246 -0.1719 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.4065 -0.0153 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.2776 -0.8301 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.9188 -1.3491 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7899 -2.1640 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4311 -2.6832 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6178 -0.9061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1328 -1.5734 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4383 -0.9924 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -0.2824 -0.1523 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2588 -1.0787 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5942 -1.8324 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.7438 -0.4114 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.3520 -1.8129 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0193 -2.2979 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.5982 -2.1484 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.1429 3.9796 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.4510 4.4289 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7159 4.0544 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6728 3.2305 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.3647 2.7812 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0997 3.1558 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 2 6 1 6 0 0 0 3 7 1 6 0 0 0 5 8 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 10 11 1 0 0 0 0 11 12 1 0 0 0 0 16 13 1 0 0 0 0 13 14 1 0 0 0 0 13 15 1 0 0 0 0 15 7 1 0 0 0 0 15 17 1 0 0 0 0 17 18 1 0 0 0 0 17 19 1 0 0 0 0 15 20 1 0 0 0 0 20 21 1 0 0 0 0 20 22 1 0 0 0 0 28 23 1 0 0 0 0 23 24 1 0 0 0 0 24 25 1 0 0 0 0 25 26 1 0 0 0 0 26 27 1 0 0 0 0 28 27 1 0 0 0 0 27 6 1 0 0 0 0 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 6 5 8 9 10 11 12 M SBL 1 1 4 M SMT 1 Hex M SAP 1 1 5 4 1 M SAL 2 11 7 13 14 15 16 17 18 19 20 21 22 M SBL 2 1 6 M SMT 2 OTIPS M SAP 2 1 7 3 1 M SAL 3 7 6 23 24 25 26 27 28 M SBL 3 1 5 M SMT 3 OTHP M SAP 3 1 6 2 1 M END > UALIB-212 > (2S,3S)-2-(tetrahydro-2H-pyran-2-yloxy)-3-(triisopropylsiloxy)decanol > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CCCCCCC[C@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](O)OC1CCCCO1 > InChI=1S/C23H48O4Si/c1-8-9-10-11-12-15-21(23(24)26-22-16-13-14-17-25-22)27-28(18(2)3,19(4)5)20(6)7/h18-24H,8-17H2,1-7H3/t21-,22?,23+/m0/s1 $$$$ Mrv1927 02072015252D 31 31 0 0 1 0 999 V2000 -3.0134 0.7589 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2783 1.1335 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.6109 0.6485 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -0.8758 1.0231 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.2346 0.5039 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3215 1.9573 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.5246 -0.1719 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.7053 1.2083 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.0009 1.9785 0.0000 Br 0 0 0 0 0 0 0 0 0 0 0 0 -4.1546 0.5164 0.0000 Br 0 0 0 0 0 0 0 0 0 0 0 0 0.4065 -0.0153 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.2776 -0.8301 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.9188 -1.3491 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7899 -2.1640 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4311 -2.6832 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6178 -0.9061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1328 -1.5734 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4383 -0.9924 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -0.2824 -0.1523 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2588 -1.0787 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5942 -1.8324 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.7438 -0.4114 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.3520 -1.8129 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0193 -2.2979 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.5982 -2.1484 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.1429 3.9796 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.4510 4.4289 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7159 4.0544 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6728 3.2305 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.3647 2.7812 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0997 3.1558 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 2 6 1 6 0 0 0 3 7 1 6 0 0 0 1 8 2 0 0 0 0 8 9 1 0 0 0 0 8 10 1 0 0 0 0 5 11 1 0 0 0 0 11 12 1 0 0 0 0 12 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 1 0 0 0 0 19 16 1 0 0 0 0 16 17 1 0 0 0 0 16 18 1 0 0 0 0 18 7 1 0 0 0 0 18 20 1 0 0 0 0 20 21 1 0 0 0 0 20 22 1 0 0 0 0 18 23 1 0 0 0 0 23 24 1 0 0 0 0 23 25 1 0 0 0 0 31 26 1 0 0 0 0 26 27 1 0 0 0 0 27 28 1 0 0 0 0 28 29 1 0 0 0 0 29 30 1 0 0 0 0 31 30 1 0 0 0 0 30 6 1 0 0 0 0 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 6 5 11 12 13 14 15 M SBL 1 1 4 M SMT 1 Hex M SAP 1 1 5 4 1 M SAL 2 11 7 16 17 18 19 20 21 22 23 24 25 M SBL 2 1 6 M SMT 2 OTIPS M SAP 2 1 7 3 1 M SAL 3 7 6 26 27 28 29 30 31 M SBL 3 1 5 M SMT 3 OTHP M SAP 3 1 6 2 1 M END > UALIB-213 > (3S,4S)-1,1,Dibromo-3-(tetrahydro-2H-pyran-2-yloxy)-4-(triisopropylsiloxy)-1-undecene > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CCCCCCC[C@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@@H](OC1CCCCO1)C=C(Br)Br > InChI=1S/C25H48Br2O3Si/c1-8-9-10-11-12-15-22(30-31(19(2)3,20(4)5)21(6)7)23(18-24(26)27)29-25-16-13-14-17-28-25/h18-23,25H,8-17H2,1-7H3/t22-,23-,25?/m0/s1 $$$$ Mrv1927 02072015252D 23 22 0 0 1 0 999 V2000 -3.0134 0.7589 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2783 1.1335 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.6109 0.6485 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -0.8758 1.0231 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.2346 0.5039 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3215 1.9573 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.5246 -0.1719 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.7671 0.4234 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4065 -0.0153 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.2776 -0.8301 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.9188 -1.3491 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7899 -2.1640 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4311 -2.6832 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6178 -0.9061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1328 -1.5734 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4383 -0.9924 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -0.2824 -0.1523 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2588 -1.0787 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5942 -1.8324 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.7438 -0.4114 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.3520 -1.8129 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0193 -2.2979 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.5982 -2.1484 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 2 6 1 6 0 0 0 3 7 1 6 0 0 0 1 8 3 0 0 0 0 5 9 1 0 0 0 0 9 10 1 0 0 0 0 10 11 1 0 0 0 0 11 12 1 0 0 0 0 12 13 1 0 0 0 0 17 14 1 0 0 0 0 14 15 1 0 0 0 0 14 16 1 0 0 0 0 16 7 1 0 0 0 0 16 18 1 0 0 0 0 18 19 1 0 0 0 0 18 20 1 0 0 0 0 16 21 1 0 0 0 0 21 22 1 0 0 0 0 21 23 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 6 5 9 10 11 12 13 M SBL 1 1 4 M SMT 1 Hex M SAP 1 1 5 4 1 M SAL 2 11 7 14 15 16 17 18 19 20 21 22 23 M SBL 2 1 6 M SMT 2 OTIPS M SAP 2 1 7 3 1 M END > UALIB-214 > (3S,4S)-4-(Triisopropylsiloxy)-1-undecyn-3-ol > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CCCCCCC[C@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@@H](O)C#C > InChI=1S/C20H40O2Si/c1-9-11-12-13-14-15-20(19(21)10-2)22-23(16(3)4,17(5)6)18(7)8/h2,16-21H,9,11-15H2,1,3-8H3/t19-,20-/m0/s1 $$$$ Mrv1927 02072015252D 30 29 0 0 1 0 999 V2000 -2.5446 -0.1339 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.9315 0.4181 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.2904 0.9373 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.4665 0.9805 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -0.0172 1.6724 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.8067 1.6292 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.1168 0.3971 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2897 -0.9186 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.3685 -0.0908 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.8877 -0.7319 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7753 1.6047 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 1.6305 1.5860 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0051 0.8509 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8289 0.8078 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.2035 0.0727 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.0274 0.0295 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2836 0.3971 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0804 0.1836 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7002 -0.1864 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 1.0700 1.1940 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.1168 -0.7696 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.3304 -1.5665 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6801 -0.5561 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2836 -0.7696 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.0700 -1.5665 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0804 -0.5561 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.7772 -1.6312 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.5920 -1.5021 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.4818 -2.4016 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.7025 -0.6028 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 2 0 0 0 0 2 3 2 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 4 7 1 6 0 0 0 1 8 1 1 0 0 0 1 9 1 6 0 0 0 9 10 1 0 0 0 0 3 11 1 0 0 0 0 6 12 1 0 0 0 0 12 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 20 17 1 0 0 0 0 17 18 1 0 0 0 0 17 19 1 0 0 0 0 19 7 1 0 0 0 0 19 21 1 0 0 0 0 21 22 1 0 0 0 0 21 23 1 0 0 0 0 19 24 1 0 0 0 0 24 25 1 0 0 0 0 24 26 1 0 0 0 0 29 27 1 0 0 0 0 27 28 1 0 0 0 0 28 10 1 0 0 0 0 10 30 2 0 0 0 0 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 6 6 12 13 14 15 16 M SBL 1 1 5 M SMT 1 Hex M SAP 1 1 6 5 1 M SAL 2 11 7 17 18 19 20 21 22 23 24 25 26 M SBL 2 1 6 M SMT 2 OTIPS M SAP 2 1 7 4 1 M SAL 3 5 10 27 28 29 30 M SBL 3 1 9 M SMT 3 CO2Et M SAP 3 1 10 9 1 M END > UALIB-215 > Ethyl (3R,6S)-6-(triisopropylsiloxy)-3,4-tridecadienoate > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H]C(CC(=O)OCC)=[C@@]=C([H])[C@H](CCCCCCC)O[Si](C(C)C)(C(C)C)C(C)C > InChI=1S/C24H46O3Si/c1-9-11-12-13-14-17-23(18-15-16-19-24(25)26-10-2)27-28(20(3)4,21(5)6)22(7)8/h16,18,20-23H,9-14,17,19H2,1-8H3/t15-,23-/m0/s1 $$$$ Mrv1927 02072015252D 27 26 0 0 1 0 999 V2000 -2.5446 -0.1339 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.9315 0.4181 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.2904 0.9373 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.4665 0.9805 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -0.0172 1.6724 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.8067 1.6292 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.1168 0.3971 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2897 -0.9186 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.3685 -0.0908 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7753 1.6047 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.8877 -0.7319 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6947 -0.5604 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.6305 1.5860 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0051 0.8509 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8289 0.8078 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.2035 0.0727 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.0274 0.0295 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2836 0.3971 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0804 0.1836 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7002 -0.1864 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 1.0700 1.1940 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.1168 -0.7696 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.3304 -1.5665 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6801 -0.5561 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2836 -0.7696 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.0700 -1.5665 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0804 -0.5561 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 2 0 0 0 0 2 3 2 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 4 7 1 6 0 0 0 1 8 1 1 0 0 0 1 9 1 6 0 0 0 3 10 1 0 0 0 0 9 11 1 0 0 0 0 11 12 1 0 0 0 0 6 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 21 18 1 0 0 0 0 18 19 1 0 0 0 0 18 20 1 0 0 0 0 20 7 1 0 0 0 0 20 22 1 0 0 0 0 22 23 1 0 0 0 0 22 24 1 0 0 0 0 20 25 1 0 0 0 0 25 26 1 0 0 0 0 25 27 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 6 6 13 14 15 16 17 M SBL 1 1 5 M SMT 1 Hex M SAP 1 1 6 5 1 M SAL 2 11 7 18 19 20 21 22 23 24 25 26 27 M SBL 2 1 6 M SMT 2 OTIPS M SAP 2 1 7 4 1 M END > UALIB-216 > (3R,6S)-6-(Triisopropylsiloxy)-3,4-tridecadien-1-ol > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H]C(CCO)=[C@@]=C([H])[C@H](CCCCCCC)O[Si](C(C)C)(C(C)C)C(C)C > InChI=1S/C22H44O2Si/c1-8-9-10-11-13-16-22(17-14-12-15-18-23)24-25(19(2)3,20(4)5)21(6)7/h12,17,19-23H,8-11,13,15-16,18H2,1-7H3/t14-,22-/m0/s1 $$$$ Mrv1927 02072015252D 27 26 0 0 1 0 999 V2000 -2.5446 -0.1339 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.9315 0.4181 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.2904 0.9373 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.4665 0.9805 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -0.0172 1.6724 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.8067 1.6292 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.1168 0.3971 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2897 -0.9186 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.3685 -0.0908 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7753 1.6047 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.8877 -0.7319 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6947 -0.5604 0.0000 Br 0 0 0 0 0 0 0 0 0 0 0 0 1.6305 1.5860 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0051 0.8509 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8289 0.8078 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.2035 0.0727 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.0274 0.0295 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2836 0.3971 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0804 0.1836 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7002 -0.1864 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 1.0700 1.1940 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.1168 -0.7696 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.3304 -1.5665 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6801 -0.5561 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2836 -0.7696 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.0700 -1.5665 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0804 -0.5561 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 2 0 0 0 0 2 3 2 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 4 7 1 6 0 0 0 1 8 1 1 0 0 0 1 9 1 6 0 0 0 3 10 1 0 0 0 0 9 11 1 0 0 0 0 11 12 1 0 0 0 0 6 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 21 18 1 0 0 0 0 18 19 1 0 0 0 0 18 20 1 0 0 0 0 20 7 1 0 0 0 0 20 22 1 0 0 0 0 22 23 1 0 0 0 0 22 24 1 0 0 0 0 20 25 1 0 0 0 0 25 26 1 0 0 0 0 25 27 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 6 6 13 14 15 16 17 M SBL 1 1 5 M SMT 1 Hex M SAP 1 1 6 5 1 M SAL 2 11 7 18 19 20 21 22 23 24 25 26 27 M SBL 2 1 6 M SMT 2 OTIPS M SAP 2 1 7 4 1 M END > UALIB-217 > (3R,6S)-1-Bromo-6-(triisopropylsiloxy)-3,4-tridecadiene > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H]C(CCBr)=[C@@]=C([H])[C@H](CCCCCCC)O[Si](C(C)C)(C(C)C)C(C)C > InChI=1S/C22H43BrOSi/c1-8-9-10-11-13-16-22(17-14-12-15-18-23)24-25(19(2)3,20(4)5)21(6)7/h12,17,19-22H,8-11,13,15-16,18H2,1-7H3/t14-,22-/m0/s1 $$$$ Mrv1927 02072015252D 28 27 0 0 1 0 999 V2000 -2.5446 -0.1339 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.9315 0.4181 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.2904 0.9373 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.4665 0.9805 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -0.0172 1.6724 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.8067 1.6292 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.1168 0.3971 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2897 -0.9186 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.3685 -0.0908 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7753 1.6047 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.8877 -0.7319 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6947 -0.5604 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.6305 1.5860 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0051 0.8509 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8289 0.8078 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.2035 0.0727 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.0274 0.0295 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2836 0.3971 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0804 0.1836 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7002 -0.1864 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 1.0700 1.1940 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.1168 -0.7696 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.3304 -1.5665 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6801 -0.5561 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2836 -0.7696 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.0700 -1.5665 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0804 -0.5561 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.5016 -0.3889 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 1 2 2 0 0 0 0 2 3 2 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 4 7 1 6 0 0 0 1 8 1 1 0 0 0 1 9 1 6 0 0 0 3 10 1 0 0 0 0 9 11 1 0 0 0 0 11 12 1 0 0 0 0 6 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 21 18 1 0 0 0 0 18 19 1 0 0 0 0 18 20 1 0 0 0 0 20 7 1 0 0 0 0 20 22 1 0 0 0 0 22 23 1 0 0 0 0 22 24 1 0 0 0 0 20 25 1 0 0 0 0 25 26 1 0 0 0 0 25 27 1 0 0 0 0 12 28 3 0 0 0 0 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 6 6 13 14 15 16 17 M SBL 1 1 5 M SMT 1 Hex M SAP 1 1 6 5 1 M SAL 2 11 7 18 19 20 21 22 23 24 25 26 27 M SBL 2 1 6 M SMT 2 OTIPS M SAP 2 1 7 4 1 M SAL 3 2 12 28 M SBL 3 1 11 M SMT 3 CN M SAP 3 1 12 11 1 M END > UALIB-218 > (3R,6S)-1-Cyano-6-(triisopropylsiloxy)-3,4-tridecadiene > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H]C(CCC#N)=[C@@]=C([H])[C@H](CCCCCCC)O[Si](C(C)C)(C(C)C)C(C)C > InChI=1S/C23H43NOSi/c1-8-9-10-11-14-17-23(18-15-12-13-16-19-24)25-26(20(2)3,21(4)5)22(6)7/h12,18,20-23H,8-11,13-14,16-17H2,1-7H3/t15-,23-/m0/s1 $$$$ Mrv1927 02072015252D 28 27 0 0 1 0 999 V2000 -2.5446 -0.1339 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.9315 0.4181 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.2904 0.9373 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.4665 0.9805 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -0.0172 1.6724 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.8067 1.6292 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.1168 0.3971 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2897 -0.9186 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.3685 -0.0908 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7753 1.6047 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.8877 -0.7319 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6947 -0.5604 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6947 0.2646 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.6305 1.5860 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0051 0.8509 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8289 0.8078 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.2035 0.0727 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.0274 0.0295 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2836 0.3971 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0804 0.1836 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7002 -0.1864 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 1.0700 1.1940 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.1168 -0.7696 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.3304 -1.5665 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6801 -0.5561 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2836 -0.7696 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.0700 -1.5665 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0804 -0.5561 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 2 0 0 0 0 2 3 2 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 4 7 1 6 0 0 0 1 8 1 1 0 0 0 1 9 1 6 0 0 0 3 10 1 0 0 0 0 9 11 1 0 0 0 0 11 12 1 0 0 0 0 12 13 2 0 0 0 0 6 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 17 18 1 0 0 0 0 22 19 1 0 0 0 0 19 20 1 0 0 0 0 19 21 1 0 0 0 0 21 7 1 0 0 0 0 21 23 1 0 0 0 0 23 24 1 0 0 0 0 23 25 1 0 0 0 0 21 26 1 0 0 0 0 26 27 1 0 0 0 0 26 28 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 6 6 14 15 16 17 18 M SBL 1 1 5 M SMT 1 Hex M SAP 1 1 6 5 1 M SAL 2 11 7 19 20 21 22 23 24 25 26 27 28 M SBL 2 1 6 M SMT 2 OTIPS M SAP 2 1 7 4 1 M END > UALIB-219 > (4R,7S)-7-(Triisopropylsiloxy)-4,5-tetradecadien-1-al > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H]C(CCC=O)=[C@@]=C([H])[C@H](CCCCCCC)O[Si](C(C)C)(C(C)C)C(C)C > InChI=1S/C23H44O2Si/c1-8-9-10-11-14-17-23(18-15-12-13-16-19-24)25-26(20(2)3,21(4)5)22(6)7/h12,18-23H,8-11,13-14,16-17H2,1-7H3/t15-,23-/m0/s1 $$$$ Mrv1927 02072015252D 161162 0 0 1 0 999 V2000 -6.8527 0.6018 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -7.5671 0.1893 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -7.5671 -0.6357 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -6.8527 -1.0482 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -6.1382 -0.6357 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -6.1382 0.1893 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -8.2083 -1.1549 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.4237 -0.2232 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -5.4463 -1.0851 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -4.6761 -0.7894 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.0350 -1.3086 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.2999 -0.9340 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.7165 -1.5174 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.1332 -2.1008 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5201 -1.5487 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -0.7850 -1.9233 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0313 -1.5877 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5201 -0.7237 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -5.6178 -1.8920 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -4.7789 -1.5700 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -8.1802 0.7413 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -6.8527 -1.8732 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.2136 -0.1136 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.1332 -2.9258 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 2.6347 3.9547 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.9202 3.5422 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 1.9202 2.7172 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 2.6347 2.3047 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 3.3492 2.7172 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 3.3492 3.5422 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2791 2.1980 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.0636 3.1297 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 4.0411 2.2679 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 4.8113 2.5635 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.4524 2.0443 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.1875 2.4189 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.7709 1.8355 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 7.3542 1.2522 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.9673 1.8042 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 8.7024 1.4296 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.4561 1.7652 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.9673 2.6292 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 3.8696 1.4609 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 4.7085 1.7830 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 1.3071 4.0943 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 2.6347 1.4797 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.2737 3.2394 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.3542 0.4272 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 5.5365 -2.3846 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.8220 -2.7971 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 4.8220 -3.6221 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 5.5365 -4.0346 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 6.2510 -3.6221 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 6.2510 -2.7971 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 4.1809 -4.1413 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.9654 -3.2096 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.9429 -4.0714 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 7.7131 -3.7758 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.3542 -4.2949 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.0893 -3.9204 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.6727 -4.5038 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 10.2560 -5.0871 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.8691 -4.5351 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 11.6042 -4.9096 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 12.3579 -4.5741 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.8691 -3.7101 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 4.2089 -2.2450 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 9.1755 -3.0999 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.2560 -5.9121 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 5.5797 -4.8585 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.3333 -5.1940 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 4.8878 -5.3078 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 6.8030 -2.1840 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.2385 -4.8416 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -4.7093 -1.4609 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.8362 -1.1588 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0112 -2.5879 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.1382 -2.2857 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -5.4237 -1.8732 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -7.5671 -2.2857 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -9.3454 0.6802 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -10.1523 0.8516 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -8.7933 1.2933 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -9.0903 -0.1045 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -8.2414 1.9065 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -8.4964 2.6911 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -7.4344 1.7350 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -9.4065 1.8453 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -9.2351 2.6523 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -10.1911 1.5903 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3451 0.1013 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.7576 0.8157 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5201 0.1013 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -2.7576 -0.6132 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6951 0.1013 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.2826 0.8157 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.2826 -0.6132 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5201 0.9263 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8056 1.3388 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2345 1.3388 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7224 -1.2521 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3898 -1.7369 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1435 -1.4013 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8109 -1.8862 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5646 -1.5505 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.2098 2.1008 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.8772 1.6158 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 11.6309 1.9514 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 12.2983 1.4665 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 13.0520 1.8020 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.1423 3.4542 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.7298 4.1687 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.9673 3.4542 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 6.7298 2.7397 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.7923 3.4542 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.2048 4.1687 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.2048 2.7397 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.9673 4.2792 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.6818 4.6917 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.2529 4.6917 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.1420 4.0332 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6650 4.2047 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6941 4.6463 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 0.3970 3.2486 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2461 5.2594 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.9911 6.0440 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0531 5.0879 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0810 5.1983 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.2525 6.0053 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7037 4.9434 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.7781 1.8922 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.6512 2.1942 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.4762 0.7652 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.3492 1.0672 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 4.0637 1.4797 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.9202 1.0672 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 13.1116 -4.2386 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 13.7790 -4.7236 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 14.5327 -4.3882 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 15.2001 -4.8733 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 15.9538 -4.5379 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.0441 -2.8851 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.6316 -2.1706 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.8691 -2.8851 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 9.6316 -3.5996 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 11.6941 -2.8851 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 12.1066 -2.1706 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 12.1066 -3.5996 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.8691 -2.0601 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 11.5836 -1.6476 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.1546 -1.6476 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.0438 -2.3060 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.2368 -2.1344 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5958 -1.6929 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 3.2986 -3.0906 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.1480 -1.0799 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.8931 -0.2953 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.9549 -1.2515 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.9828 -1.1409 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.1545 -0.3339 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1982 -1.3957 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 5 8 1 1 0 0 0 5 9 1 0 0 0 0 9 10 1 0 0 0 0 10 11 1 0 0 0 0 11 12 1 1 0 0 0 12 13 2 0 0 0 0 13 14 2 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 15 18 1 1 0 0 0 9 19 1 1 0 0 0 9 20 1 6 0 0 0 2 21 1 6 0 0 0 4 22 1 0 0 0 0 12 23 1 6 0 0 0 14 24 1 0 0 0 0 25 26 1 0 0 0 0 26 27 1 0 0 0 0 27 28 1 0 0 0 0 28 29 1 0 0 0 0 29 30 1 0 0 0 0 25 30 1 0 0 0 0 27 31 1 1 0 0 0 29 32 1 1 0 0 0 29 33 1 0 0 0 0 33 34 1 0 0 0 0 34 35 1 0 0 0 0 35 36 1 1 0 0 0 36 37 2 0 0 0 0 37 38 2 0 0 0 0 38 39 1 0 0 0 0 39 40 1 0 0 0 0 40 41 1 0 0 0 0 39 42 1 1 0 0 0 33 43 1 1 0 0 0 33 44 1 6 0 0 0 26 45 1 6 0 0 0 28 46 1 0 0 0 0 36 47 1 6 0 0 0 38 48 1 0 0 0 0 49 50 1 0 0 0 0 50 51 1 0 0 0 0 51 52 1 0 0 0 0 52 53 1 0 0 0 0 53 54 1 0 0 0 0 49 54 1 0 0 0 0 51 55 1 1 0 0 0 53 56 1 1 0 0 0 53 57 1 0 0 0 0 57 58 1 1 0 0 0 58 59 1 0 0 0 0 59 60 1 1 0 0 0 60 61 2 0 0 0 0 61 62 2 0 0 0 0 62 63 1 0 0 0 0 63 64 1 0 0 0 0 64 65 1 0 0 0 0 63 66 1 1 0 0 0 50 67 1 6 0 0 0 60 68 1 6 0 0 0 62 69 1 0 0 0 0 52 70 1 0 0 0 0 70 71 1 0 0 0 0 71 57 1 0 0 0 0 70 72 2 0 0 0 0 54 73 1 6 0 0 0 57 74 1 6 0 0 0 79 75 1 0 0 0 0 79 76 1 0 0 0 0 79 77 1 0 0 0 0 79 78 1 0 0 0 0 78 22 1 0 0 0 0 22 80 2 0 0 0 0 84 81 1 0 0 0 0 81 82 1 0 0 0 0 81 83 1 0 0 0 0 83 21 1 0 0 0 0 83 85 1 0 0 0 0 85 86 1 0 0 0 0 85 87 1 0 0 0 0 83 88 1 0 0 0 0 88 89 1 0 0 0 0 88 90 1 0 0 0 0 94 91 1 0 0 0 0 91 92 1 0 0 0 0 91 93 1 0 0 0 0 93 18 1 0 0 0 0 93 95 1 0 0 0 0 95 96 1 0 0 0 0 95 97 1 0 0 0 0 93 98 1 0 0 0 0 98 99 1 0 0 0 0 98100 1 0 0 0 0 17101 1 0 0 0 0 101102 1 0 0 0 0 102103 1 0 0 0 0 103104 1 0 0 0 0 104105 1 0 0 0 0 41106 1 0 0 0 0 106107 1 0 0 0 0 107108 1 0 0 0 0 108109 1 0 0 0 0 109110 1 0 0 0 0 114111 1 0 0 0 0 111112 1 0 0 0 0 111113 1 0 0 0 0 113 42 1 0 0 0 0 113115 1 0 0 0 0 115116 1 0 0 0 0 115117 1 0 0 0 0 113118 1 0 0 0 0 118119 1 0 0 0 0 118120 1 0 0 0 0 124121 1 0 0 0 0 121122 1 0 0 0 0 121123 1 0 0 0 0 123 45 1 0 0 0 0 123125 1 0 0 0 0 125126 1 0 0 0 0 125127 1 0 0 0 0 123128 1 0 0 0 0 128129 1 0 0 0 0 128130 1 0 0 0 0 135131 1 0 0 0 0 135132 1 0 0 0 0 135133 1 0 0 0 0 135134 1 0 0 0 0 134 46 1 0 0 0 0 46136 2 0 0 0 0 65137 1 0 0 0 0 137138 1 0 0 0 0 138139 1 0 0 0 0 139140 1 0 0 0 0 140141 1 0 0 0 0 145142 1 0 0 0 0 142143 1 0 0 0 0 142144 1 0 0 0 0 144 66 1 0 0 0 0 144146 1 0 0 0 0 146147 1 0 0 0 0 146148 1 0 0 0 0 144149 1 0 0 0 0 149150 1 0 0 0 0 149151 1 0 0 0 0 155152 1 0 0 0 0 152153 1 0 0 0 0 152154 1 0 0 0 0 154 67 1 0 0 0 0 154156 1 0 0 0 0 156157 1 0 0 0 0 156158 1 0 0 0 0 154159 1 0 0 0 0 159160 1 0 0 0 0 159161 1 0 0 0 0 M STY 8 1 SUP 2 SUP 3 SUP 4 SUP 5 SUP 6 SUP 7 SUP 8 SUP M STY 3 9 SUP 10 SUP 11 SUP M SAL 1 7 22 75 76 77 78 79 80 M SBL 1 1 22 M SMT 1 Boc M SAP 1 1 22 4 1 M SAL 2 11 21 81 82 83 84 85 86 87 88 89 90 M SBL 2 1 21 M SMT 2 OTIPS M SAP 2 1 21 2 1 M SAL 3 11 18 91 92 93 94 95 96 97 98 99 100 M SBL 3 1 18 M SMT 3 OTIPS M SAP 3 1 18 15 1 M SAL 4 6 17 101 102 103 104 105 M SBL 4 1 17 M SMT 4 Hex M SAP 4 1 17 16 1 M SAL 5 6 41 106 107 108 109 110 M SBL 5 1 41 M SMT 5 Hex M SAP 5 1 41 40 1 M SAL 6 11 42 111 112 113 114 115 116 117 118 119 120 M SBL 6 1 42 M SMT 6 OTIPS M SAP 6 1 42 39 1 M SAL 7 11 45 121 122 123 124 125 126 127 128 129 130 M SBL 7 1 45 M SMT 7 OTIPS M SAP 7 1 45 26 1 M SAL 8 7 46 131 132 133 134 135 136 M SBL 8 1 46 M SMT 8 Boc M SAP 8 1 46 28 1 M SAL 9 6 65 137 138 139 140 141 M SBL 9 1 65 M SMT 9 Hex M SAP 9 1 65 64 1 M SAL 10 11 66 142 143 144 145 146 147 148 149 150 151 M SBL 10 1 66 M SMT 10 OTIPS M SAP 10 1 66 63 1 M SAL 11 11 67 152 153 154 155 156 157 158 159 160 161 M SBL 11 1 67 M SMT 11 OTIPS M SAP 11 1 67 50 1 M END > UALIB-220 > (2R,5R,6S)-1-(t-Butyloxycarbonyl)-2-[(1S,4R,7S)-1-hydroxy-7-(triisopropylsiloxy)-4,5-tetradecadienyl]-6-methyl-5-(triisopropylsiloxy)piperidine and (2R,5R,6S)-1-(t-Butyloxycarbonyl)-2-[(1R,4R,7S)-1-hydroxy-7-(triisopropylsiloxy)-4,5-tetradecadienyl]-6-methyl-5-(triisopropylsiloxy)piperidine and (2S,3R,6R,7R)-2-Methyl-9-oxa-3-(triisopropylsiloxy)-7-[(3R,6S)-7-(triisopropylsiloxy)-3,4-tridecadienyl]-1-azabicyclo[4.3.0]nonan-9-one > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H]C1C[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N2C(=O)O[C@]([H])(CCC([H])=[C@]=C([H])[C@H](CCCCCCC)O[Si](C(C)C)(C(C)C)C(C)C)[C@@]12[H].[H]C(CC[C@]([H])(O)[C@@]1([H])CC[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N1C(=O)OC(C)(C)C)=[C@@]=C([H])[C@H](CCCCCCC)O[Si](C(C)C)(C(C)C)C(C)C.[H]C(CC[C@@]([H])(O)[C@@]1([H])CC[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N1C(=O)OC(C)(C)C)=[C@@]=C([H])[C@H](CCCCCCC)O[Si](C(C)C)(C(C)C)C(C)C > InChI=1S/2C43H85NO5Si2.C39H75NO4Si2/c2*1-18-19-20-21-23-26-38(48-50(31(2)3,32(4)5)33(6)7)27-24-22-25-28-40(45)39-29-30-41(37(14)44(39)42(46)47-43(15,16)17)49-51(34(8)9,35(10)11)36(12)13;1-15-16-17-18-20-23-35(43-45(28(2)3,29(4)5)30(6)7)24-21-19-22-25-38-36-26-27-37(34(14)40(36)39(41)42-38)44-46(31(8)9,32(10)11)33(12)13/h2*22,27,31-41,45H,18-21,23,25-26,28-30H2,1-17H3;19,24,28-38H,15-18,20,22-23,25-27H2,1-14H3/t24?,37-,38-,39+,40+,41+;24?,37-,38-,39+,40-,41+;21?,34-,35-,36+,37+,38+/m000/s1 $$$$ Mrv1927 02072015252D 49 50 0 0 1 0 999 V2000 5.5365 -2.3846 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.8220 -2.7971 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 4.8220 -3.6221 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 5.5365 -4.0346 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 6.2510 -3.6221 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 6.2510 -2.7971 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.1809 -4.1413 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.9654 -3.2096 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.9429 -4.0714 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.7131 -3.7758 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.3542 -4.2949 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.0893 -3.9204 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.6727 -4.5038 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 10.2560 -5.0871 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.8691 -4.5351 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 11.6042 -4.9096 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 12.3579 -4.5741 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.8691 -3.7101 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 4.2089 -2.2450 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 9.1755 -3.0999 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.2560 -5.9121 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 5.5797 -4.8585 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.3333 -5.1940 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 4.8878 -5.3078 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 13.1116 -4.2386 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 13.7790 -4.7236 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 14.5327 -4.3882 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 15.2001 -4.8733 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 15.9538 -4.5379 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.0441 -2.8851 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.6316 -2.1706 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.8691 -2.8851 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 9.6316 -3.5996 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 11.6941 -2.8851 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 12.1066 -2.1706 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 12.1066 -3.5996 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.8691 -2.0601 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 11.5836 -1.6476 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.1546 -1.6476 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.0438 -2.3060 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.2368 -2.1344 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5958 -1.6929 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 3.2986 -3.0906 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.1480 -1.0799 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.8931 -0.2953 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.9549 -1.2515 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.9828 -1.1409 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.1545 -0.3339 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1982 -1.3957 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 5 8 1 1 0 0 0 5 9 1 0 0 0 0 9 10 1 1 0 0 0 10 11 1 0 0 0 0 11 12 1 1 0 0 0 12 13 2 0 0 0 0 13 14 2 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 15 18 1 1 0 0 0 2 19 1 6 0 0 0 12 20 1 6 0 0 0 14 21 1 0 0 0 0 4 22 1 0 0 0 0 22 23 1 0 0 0 0 9 23 1 6 0 0 0 22 24 2 0 0 0 0 17 25 1 0 0 0 0 25 26 1 0 0 0 0 26 27 1 0 0 0 0 27 28 1 0 0 0 0 28 29 1 0 0 0 0 33 30 1 0 0 0 0 30 31 1 0 0 0 0 30 32 1 0 0 0 0 32 18 1 0 0 0 0 32 34 1 0 0 0 0 34 35 1 0 0 0 0 34 36 1 0 0 0 0 32 37 1 0 0 0 0 37 38 1 0 0 0 0 37 39 1 0 0 0 0 43 40 1 0 0 0 0 40 41 1 0 0 0 0 40 42 1 0 0 0 0 42 19 1 0 0 0 0 42 44 1 0 0 0 0 44 45 1 0 0 0 0 44 46 1 0 0 0 0 42 47 1 0 0 0 0 47 48 1 0 0 0 0 47 49 1 0 0 0 0 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 6 17 25 26 27 28 29 M SBL 1 1 17 M SMT 1 Hex M SAP 1 1 17 16 1 M SAL 2 11 18 30 31 32 33 34 35 36 37 38 39 M SBL 2 1 18 M SMT 2 OTIPS M SAP 2 1 18 15 1 M SAL 3 11 19 40 41 42 43 44 45 46 47 48 49 M SBL 3 1 19 M SMT 3 OTIPS M SAP 3 1 19 2 1 M END > UALIB-221 > (2S,3R,6R,7S)-2-Methyl-9-oxa-3-(triisopropylsiloxy)-7-[(3R,6S)-7-(triisopropylsiloxy)-3,4-tridecadien-1-yl]-1-azabicyclo[4.3.0]nonan-9-one > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H]C(CCC1OC(=O)N2[C@@H](C)[C@@H](CC[C@]12[H])O[Si](C(C)C)(C(C)C)C(C)C)=[C@@]=C([H])[C@H](CCCCCCC)O[Si](C(C)C)(C(C)C)C(C)C > InChI=1S/C39H75NO4Si2/c1-15-16-17-18-20-23-35(43-45(28(2)3,29(4)5)30(6)7)24-21-19-22-25-38-36-26-27-37(34(14)40(36)39(41)42-38)44-46(31(8)9,32(10)11)33(12)13/h19,24,28-38H,15-18,20,22-23,25-27H2,1-14H3/t21?,34-,35-,36+,37+,38?/m0/s1 $$$$ Mrv1927 02072015252D 132134 0 0 1 0 999 V2000 -12.3016 -1.9730 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -12.3016 -1.1480 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -11.5871 -0.7355 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -10.8727 -1.1480 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -10.8727 -1.9730 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -11.5871 -2.3855 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -11.5871 -3.2105 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -13.0161 -0.7355 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -13.0161 -2.3855 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -10.1376 -2.3475 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -10.1808 -1.5236 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -10.1376 -3.1725 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -9.3839 -2.0119 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -8.8006 -2.5953 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -8.2172 -2.0119 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -7.5760 -2.5311 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -6.9349 -3.0503 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.2430 -2.6010 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -6.2430 -1.7760 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -5.5511 -3.0503 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -9.5856 -3.7856 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -10.1376 -4.3987 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -8.7651 -3.8718 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -10.9446 -4.2272 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -11.4966 -4.8403 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -11.2417 -5.6249 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -10.4347 -5.7964 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -9.8827 -5.1833 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -9.6378 -6.0099 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.8917 -3.8742 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -4.7272 -3.0071 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -8.5128 -1.2417 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -8.1514 3.8466 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -8.1514 4.6716 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -7.4370 5.0841 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.7225 4.6716 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.7225 3.8466 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -7.4370 3.4341 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -7.4370 2.6091 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -8.8659 5.0841 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -8.8659 3.4341 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.9874 3.4721 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -6.0306 4.2960 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -5.9874 2.6471 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -5.2337 3.8076 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6504 3.2243 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.0670 3.8076 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.4259 3.2885 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.7847 2.7693 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0928 3.2186 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.0928 4.0436 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.4009 2.7693 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.4354 2.0340 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.9874 1.4209 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6149 1.9478 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -6.7944 1.5924 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -7.3464 0.9793 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -7.0915 0.1947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.2845 0.0232 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7325 0.6363 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.4876 -0.1904 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.7415 1.9454 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.5770 2.8124 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3627 4.5779 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -14.1431 -1.0374 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -14.9681 -1.0374 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -13.7306 -0.3230 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -13.7306 -1.7519 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -13.3181 0.3915 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -13.7306 1.1060 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -12.4931 0.3915 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -14.4450 0.0895 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -14.4450 0.9145 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -15.1595 -0.3230 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -9.4437 -2.7978 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -10.5707 -2.4960 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -9.7457 -3.9247 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -10.8727 -3.6230 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -10.1582 -3.2105 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -12.3016 -3.6230 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -8.8409 -6.2235 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 -10.2212 -6.5934 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 -9.8513 -5.2131 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 -7.0680 -0.9510 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -7.4805 -0.2365 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.2430 -0.9510 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -7.4805 -1.6655 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.4180 -0.9510 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0055 -0.2365 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0055 -1.6655 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.2430 -0.1260 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.5285 0.2865 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.9575 0.2865 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9034 -2.9639 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.4539 -3.6558 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.6301 -3.6125 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.1807 -4.3043 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.3569 -4.2610 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.2935 3.0214 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.4205 3.3236 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.5955 1.8945 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.7225 2.1966 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -6.0080 2.6091 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -8.1514 2.1966 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -9.9929 4.7822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -10.8179 4.7822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -9.5804 5.4966 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -9.5804 4.0677 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -9.1679 6.2111 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -9.5804 6.9256 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -8.3429 6.2111 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -10.2948 5.9091 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -10.2948 6.7341 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -11.0093 5.4966 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9178 4.8686 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.3303 5.5831 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0928 4.8686 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -3.3303 4.1541 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.2678 4.8686 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8553 5.5831 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8553 4.1541 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0928 5.6936 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.3783 6.1061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.8073 6.1061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.0710 -0.7738 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 -5.7010 0.6065 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 -4.6907 -0.4039 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 0.2468 2.8555 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6961 2.1635 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.5199 2.2066 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.9692 1.5147 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.7930 1.5578 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 6 1 1 0 0 0 0 6 7 1 0 0 0 0 2 8 1 6 0 0 0 1 9 1 1 0 0 0 5 10 1 0 0 0 0 5 11 1 1 0 0 0 10 12 1 6 0 0 0 10 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 1 1 0 0 0 15 16 2 0 0 0 0 16 17 2 0 0 0 0 17 18 1 0 0 0 0 18 19 1 1 0 0 0 18 20 1 0 0 0 0 12 21 1 0 0 0 0 21 22 1 0 0 0 0 21 23 2 0 0 0 0 24 25 2 0 0 0 0 25 26 1 0 0 0 0 26 27 2 0 0 0 0 27 28 1 0 0 0 0 22 24 1 0 0 0 0 22 28 2 0 0 0 0 27 29 1 0 0 0 0 17 30 1 0 0 0 0 20 31 1 0 0 0 0 15 32 1 6 0 0 0 33 34 1 0 0 0 0 34 35 1 0 0 0 0 35 36 1 0 0 0 0 36 37 1 0 0 0 0 37 38 1 0 0 0 0 38 33 1 0 0 0 0 38 39 1 0 0 0 0 34 40 1 6 0 0 0 33 41 1 1 0 0 0 37 42 1 0 0 0 0 37 43 1 1 0 0 0 42 44 1 1 0 0 0 42 45 1 0 0 0 0 45 46 1 0 0 0 0 46 47 1 1 0 0 0 47 48 2 0 0 0 0 48 49 2 0 0 0 0 49 50 1 0 0 0 0 50 51 1 1 0 0 0 50 52 1 0 0 0 0 44 53 1 0 0 0 0 53 54 1 0 0 0 0 53 55 2 0 0 0 0 56 57 2 0 0 0 0 57 58 1 0 0 0 0 58 59 2 0 0 0 0 59 60 1 0 0 0 0 54 56 1 0 0 0 0 54 60 2 0 0 0 0 59 61 1 0 0 0 0 49 62 1 0 0 0 0 52 63 1 0 0 0 0 47 64 1 6 0 0 0 68 65 1 0 0 0 0 65 66 1 0 0 0 0 65 67 1 0 0 0 0 67 8 1 0 0 0 0 67 69 1 0 0 0 0 69 70 1 0 0 0 0 69 71 1 0 0 0 0 67 72 1 0 0 0 0 72 73 1 0 0 0 0 72 74 1 0 0 0 0 79 75 1 0 0 0 0 79 76 1 0 0 0 0 79 77 1 0 0 0 0 79 78 1 0 0 0 0 78 7 1 0 0 0 0 7 80 2 0 0 0 0 81 29 1 0 0 0 0 29 82 1 0 0 0 0 29 83 1 0 0 0 0 87 84 1 0 0 0 0 84 85 1 0 0 0 0 84 86 1 0 0 0 0 86 19 1 0 0 0 0 86 88 1 0 0 0 0 88 89 1 0 0 0 0 88 90 1 0 0 0 0 86 91 1 0 0 0 0 91 92 1 0 0 0 0 91 93 1 0 0 0 0 31 94 1 0 0 0 0 94 95 1 0 0 0 0 95 96 1 0 0 0 0 96 97 1 0 0 0 0 97 98 1 0 0 0 0 103 99 1 0 0 0 0 103100 1 0 0 0 0 103101 1 0 0 0 0 103102 1 0 0 0 0 102 39 1 0 0 0 0 39104 2 0 0 0 0 108105 1 0 0 0 0 105106 1 0 0 0 0 105107 1 0 0 0 0 107 40 1 0 0 0 0 107109 1 0 0 0 0 109110 1 0 0 0 0 109111 1 0 0 0 0 107112 1 0 0 0 0 112113 1 0 0 0 0 112114 1 0 0 0 0 118115 1 0 0 0 0 115116 1 0 0 0 0 115117 1 0 0 0 0 117 51 1 0 0 0 0 117119 1 0 0 0 0 119120 1 0 0 0 0 119121 1 0 0 0 0 117122 1 0 0 0 0 122123 1 0 0 0 0 122124 1 0 0 0 0 125 61 1 0 0 0 0 61126 1 0 0 0 0 61127 1 0 0 0 0 63128 1 0 0 0 0 128129 1 0 0 0 0 129130 1 0 0 0 0 130131 1 0 0 0 0 131132 1 0 0 0 0 M STY 8 1 SUP 2 SUP 3 SUP 4 SUP 5 SUP 6 SUP 7 SUP 8 SUP M STY 2 9 SUP 10 SUP M SAL 1 11 8 65 66 67 68 69 70 71 72 73 74 M SBL 1 1 8 M SMT 1 OTIPS M SAP 1 1 8 2 1 M SAL 2 7 7 75 76 77 78 79 80 M SBL 2 1 7 M SMT 2 Boc M SAP 2 1 7 6 1 M SAL 3 4 29 81 82 83 M SBL 3 1 30 M SMT 3 CF3 M SAP 3 1 29 27 1 M SAL 4 11 19 84 85 86 87 88 89 90 91 92 93 M SBL 4 1 19 M SMT 4 OTIPS M SAP 4 1 19 18 1 M SAL 5 6 31 94 95 96 97 98 M SBL 5 1 32 M SMT 5 Hex M SAP 5 1 31 20 1 M SAL 6 7 39 99 100 101 102 103 104 M SBL 6 1 40 M SMT 6 Boc M SAP 6 1 39 38 1 M SAL 7 11 40 105 106 107 108 109 110 111 112 113 114 M SBL 7 1 41 M SMT 7 OTIPS M SAP 7 1 40 34 1 M SAL 8 11 51 115 116 117 118 119 120 121 122 123 124 M SBL 8 1 52 M SMT 8 OTIPS M SAP 8 1 51 50 1 M SAL 9 4 61 125 126 127 M SBL 9 1 63 M SMT 9 CF3 M SAP 9 1 61 59 1 M SAL 10 6 63 128 129 130 131 132 M SBL 10 1 65 M SMT 10 Hex M SAP 10 1 63 52 1 M END > UALIB-222 > (1S,4R,7S)-1-[(2R,5R,6S)-1-(t-Butyloxycarbonyl)-6-methyl-5-(triisopropylsiloxy)piperidin-2-yl]-7-(triisopropyliloxy)-4,5-tetradecadien-1-yl 3-trifluoromethylbenzoate and (1R,4R,7S)-1-[(2R,5R,6S)-1-(t-Butyloxycarbonyl)-6-methyl-5-(triisopropylsiloxy)piperidin-2-yl]-7-(triisopropyliloxy)-4,5-tetradecadien-1-yl 3-trifluoromethylbenzoate > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H]C(CC[C@@H](OC(=O)C1=CC(=CC=C1)C(F)(F)F)[C@@]1([H])CC[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N1C(=O)OC(C)(C)C)=[C@@]=C([H])[C@H](CCCCCCC)O[Si](C(C)C)(C(C)C)C(C)C.[H]C(CC[C@H](OC(=O)C1=CC(=CC=C1)C(F)(F)F)[C@@]1([H])CC[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N1C(=O)OC(C)(C)C)=[C@@]=C([H])[C@H](CCCCCCC)O[Si](C(C)C)(C(C)C)C(C)C > InChI=1S/2C51H88F3NO6Si2/c2*1-18-19-20-21-23-29-44(60-62(35(2)3,36(4)5)37(6)7)30-24-22-25-31-47(58-48(56)42-27-26-28-43(34-42)51(52,53)54)45-32-33-46(41(14)55(45)49(57)59-50(15,16)17)61-63(38(8)9,39(10)11)40(12)13/h2*22,26-28,30,34-41,44-47H,18-21,23,25,29,31-33H2,1-17H3/t24?,41-,44-,45+,46+,47+;24?,41-,44-,45+,46+,47-/m00/s1 $$$$ Mrv1927 02072015252D 59 60 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.8860 0.3169 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -0.8615 1.2511 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.1940 0.7662 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4190 0.2141 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1541 0.5887 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1973 1.4126 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 1.8686 0.1762 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 2.5831 -0.2363 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.7546 -1.0433 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 3.3677 0.0186 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 4.0596 -0.4307 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8860 -0.5081 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.4010 -1.1756 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4228 -1.1324 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.9531 -1.7887 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7600 -1.6172 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3121 -2.2303 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0572 -3.0149 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.2502 -3.1864 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6981 -2.5733 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6981 -3.7995 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.8298 -0.1350 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.4109 0.8425 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1460 -4.4126 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 -1.5050 -3.9711 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 -0.4432 -3.0149 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 2.6303 1.7096 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.2558 2.4447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.4541 1.6664 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 2.1808 1.0177 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.2780 1.6231 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.7274 2.3149 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.6525 0.8879 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.4974 2.4902 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.2325 2.8647 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8056 2.9397 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.6000 0.1607 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.2411 -0.3584 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.0113 -0.0627 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.6526 -0.5818 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.4227 -0.2861 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 5 9 1 0 0 0 0 5 10 1 1 0 0 0 9 11 1 0 0 0 0 11 12 1 0 0 0 0 12 13 1 1 0 0 0 13 14 1 6 0 0 0 13 15 2 0 0 0 0 15 16 2 0 0 0 0 16 17 1 0 0 0 0 16 18 1 0 0 0 0 18 19 1 0 0 0 0 9 20 1 6 0 0 0 20 21 1 0 0 0 0 21 22 2 0 0 0 0 21 23 1 0 0 0 0 24 25 2 0 0 0 0 25 26 1 0 0 0 0 26 27 2 0 0 0 0 27 28 1 0 0 0 0 23 24 1 0 0 0 0 23 28 2 0 0 0 0 27 29 1 0 0 0 0 19 30 1 0 0 0 0 18 31 1 1 0 0 0 35 32 1 0 0 0 0 32 33 1 0 0 0 0 32 34 1 0 0 0 0 34 8 1 0 0 0 0 34 36 1 0 0 0 0 36 37 1 0 0 0 0 36 38 1 0 0 0 0 34 39 1 0 0 0 0 39 40 1 0 0 0 0 39 41 1 0 0 0 0 42 29 1 0 0 0 0 29 43 1 0 0 0 0 29 44 1 0 0 0 0 48 45 1 0 0 0 0 45 46 1 0 0 0 0 45 47 1 0 0 0 0 47 31 1 0 0 0 0 47 49 1 0 0 0 0 49 50 1 0 0 0 0 49 51 1 0 0 0 0 47 52 1 0 0 0 0 52 53 1 0 0 0 0 52 54 1 0 0 0 0 30 55 1 0 0 0 0 55 56 1 0 0 0 0 56 57 1 0 0 0 0 57 58 1 0 0 0 0 58 59 1 0 0 0 0 M STY 4 1 SUP 2 SUP 3 SUP 4 SUP M SAL 1 11 8 32 33 34 35 36 37 38 39 40 41 M SBL 1 1 8 M SMT 1 OTIPS M SAP 1 1 8 2 1 M SAL 2 4 29 42 43 44 M SBL 2 1 30 M SMT 2 CF3 M SAP 2 1 29 27 1 M SAL 3 11 31 45 46 47 48 49 50 51 52 53 54 M SBL 3 1 32 M SMT 3 OTIPS M SAP 3 1 31 18 1 M SAL 4 6 30 55 56 57 58 59 M SBL 4 1 31 M SMT 4 Hex M SAP 4 1 30 19 1 M END > UALIB-223 > (1S,4R,7S)-1-[(2R,5R,6S)-6-Methyl-5-(triisopropylsiloxy)piperidine-2-yl]-7-(triisopropylsiloxy)-4,5-tetradecadien-1-yl 3-trifluoromethylbenzoate > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H]C(CC[C@H](OC(=O)C1=CC(=CC=C1)C(F)(F)F)[C@@]1([H])CC[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N1)=[C@@]=C([H])[C@H](CCCCCCC)O[Si](C(C)C)(C(C)C)C(C)C > InChI=1S/C46H80F3NO4Si2/c1-15-16-17-18-20-26-41(53-55(32(2)3,33(4)5)34(6)7)27-21-19-22-28-44(52-45(51)39-24-23-25-40(31-39)46(47,48)49)42-29-30-43(38(14)50-42)54-56(35(8)9,36(10)11)37(12)13/h19,23-25,27,31-38,41-44,50H,15-18,20,22,26,28-30H2,1-14H3/t21?,38-,41-,42+,43+,44-/m0/s1 $$$$ Mrv1927 02072015252D 59 60 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.8860 0.3169 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -0.8615 1.2511 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.1940 0.7662 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4190 0.2141 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1541 0.5887 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1973 1.4126 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 1.8686 0.1762 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 2.5831 -0.2363 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.7546 -1.0433 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 3.3677 0.0186 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 4.0596 -0.4307 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8860 -0.5081 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.4010 -1.1756 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4228 -1.1324 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.9531 -1.7887 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7600 -1.6172 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3121 -2.2303 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0572 -3.0149 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.2502 -3.1864 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6981 -2.5733 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6981 -3.7995 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.8298 -0.1350 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.4109 0.8425 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1460 -4.4126 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 -1.5050 -3.9711 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 -0.4432 -3.0149 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 2.6303 1.7096 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.2558 2.4447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.4541 1.6664 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 2.1808 1.0177 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.2780 1.6231 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.7274 2.3149 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.6525 0.8879 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.4974 2.4902 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.2325 2.8647 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8056 2.9397 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.6000 0.1607 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.2411 -0.3584 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.0113 -0.0627 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.6526 -0.5818 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.4227 -0.2861 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 5 9 1 0 0 0 0 5 10 1 1 0 0 0 9 11 1 0 0 0 0 11 12 1 0 0 0 0 12 13 1 1 0 0 0 13 14 1 6 0 0 0 13 15 2 0 0 0 0 15 16 2 0 0 0 0 16 17 1 0 0 0 0 16 18 1 0 0 0 0 18 19 1 0 0 0 0 9 20 1 1 0 0 0 20 21 1 0 0 0 0 21 22 2 0 0 0 0 21 23 1 0 0 0 0 24 25 2 0 0 0 0 25 26 1 0 0 0 0 26 27 2 0 0 0 0 27 28 1 0 0 0 0 23 24 1 0 0 0 0 23 28 2 0 0 0 0 27 29 1 0 0 0 0 19 30 1 0 0 0 0 18 31 1 1 0 0 0 35 32 1 0 0 0 0 32 33 1 0 0 0 0 32 34 1 0 0 0 0 34 8 1 0 0 0 0 34 36 1 0 0 0 0 36 37 1 0 0 0 0 36 38 1 0 0 0 0 34 39 1 0 0 0 0 39 40 1 0 0 0 0 39 41 1 0 0 0 0 42 29 1 0 0 0 0 29 43 1 0 0 0 0 29 44 1 0 0 0 0 48 45 1 0 0 0 0 45 46 1 0 0 0 0 45 47 1 0 0 0 0 47 31 1 0 0 0 0 47 49 1 0 0 0 0 49 50 1 0 0 0 0 49 51 1 0 0 0 0 47 52 1 0 0 0 0 52 53 1 0 0 0 0 52 54 1 0 0 0 0 30 55 1 0 0 0 0 55 56 1 0 0 0 0 56 57 1 0 0 0 0 57 58 1 0 0 0 0 58 59 1 0 0 0 0 M STY 4 1 SUP 2 SUP 3 SUP 4 SUP M SAL 1 11 8 32 33 34 35 36 37 38 39 40 41 M SBL 1 1 8 M SMT 1 OTIPS M SAP 1 1 8 2 1 M SAL 2 4 29 42 43 44 M SBL 2 1 30 M SMT 2 CF3 M SAP 2 1 29 27 1 M SAL 3 11 31 45 46 47 48 49 50 51 52 53 54 M SBL 3 1 32 M SMT 3 OTIPS M SAP 3 1 31 18 1 M SAL 4 6 30 55 56 57 58 59 M SBL 4 1 31 M SMT 4 Hex M SAP 4 1 30 19 1 M END > UALIB-224 > (1R,4R,7S)-1-[(2R,5R,6S)-6-Methyl-5-(triisopropylsiloxy)piperidine-2-yl]-7-(triisopropylsiloxy)-4,5-tetradecadien-1-yl 3-trifluoromethylbenzoate > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H]C(CC[C@@H](OC(=O)C1=CC(=CC=C1)C(F)(F)F)[C@@]1([H])CC[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N1)=[C@@]=C([H])[C@H](CCCCCCC)O[Si](C(C)C)(C(C)C)C(C)C > InChI=1S/C46H80F3NO4Si2/c1-15-16-17-18-20-26-41(53-55(32(2)3,33(4)5)34(6)7)27-21-19-22-28-44(52-45(51)39-24-23-25-40(31-39)46(47,48)49)42-29-30-43(38(14)50-42)54-56(35(8)9,36(10)11)37(12)13/h19,23-25,27,31-38,41-44,50H,15-18,20,22,26,28-30H2,1-14H3/t21?,38-,41-,42+,43+,44+/m0/s1 $$$$ Mrv1927 02072015252D 57 59 0 0 1 0 999 V2000 -3.1205 4.3386 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.5074 4.8906 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7228 4.6357 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5512 3.8287 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.1643 3.2767 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -2.9490 3.5316 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.9928 2.4697 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.2082 2.2148 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.5951 2.7668 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7666 3.5738 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.6059 1.9177 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.5621 2.9796 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9051 4.5935 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.4344 1.1107 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0475 0.5587 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.8759 -0.2483 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.4890 -0.8003 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.8321 0.8136 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.1535 4.1258 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.6311 3.8709 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.8026 3.0639 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.2442 4.4229 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0288 4.1680 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.6419 4.7200 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.4704 5.5270 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.6858 5.7819 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.0727 5.2299 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.1019 4.5206 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 3.3338 4.2707 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.4744 5.1032 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6461 5.9102 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6897 4.8484 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -6.0874 4.5511 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.9446 4.0637 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3925 3.4506 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7515 3.8921 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.4349 5.6330 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6279 5.8046 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.9870 6.2461 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.4013 1.3235 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.5729 2.1305 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6167 1.0685 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -6.0144 0.7714 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.8717 0.2839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3196 -0.3292 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6786 0.1124 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3618 1.8532 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.5548 2.0247 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.9138 2.4663 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.1021 -1.3523 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9307 -2.1593 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.5439 -2.7113 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3724 -3.5182 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.9856 -4.0703 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.3770 5.0945 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 4.0257 3.8213 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 2.5987 3.8961 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 6 1 1 0 0 0 0 5 7 1 0 0 0 0 7 8 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 10 4 1 0 0 0 0 7 11 1 1 0 0 0 6 12 1 1 0 0 0 1 13 1 6 0 0 0 11 14 2 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 15 18 1 6 0 0 0 10 19 1 1 0 0 0 19 20 1 0 0 0 0 20 21 2 0 0 0 0 20 22 1 0 0 0 0 23 24 2 0 0 0 0 24 25 1 0 0 0 0 25 26 2 0 0 0 0 26 27 1 0 0 0 0 22 23 1 0 0 0 0 22 27 2 0 0 0 0 4 28 1 1 0 0 0 24 29 1 0 0 0 0 33 30 1 0 0 0 0 30 31 1 0 0 0 0 30 32 1 0 0 0 0 32 13 1 0 0 0 0 32 34 1 0 0 0 0 34 35 1 0 0 0 0 34 36 1 0 0 0 0 32 37 1 0 0 0 0 37 38 1 0 0 0 0 37 39 1 0 0 0 0 43 40 1 0 0 0 0 40 41 1 0 0 0 0 40 42 1 0 0 0 0 42 18 1 0 0 0 0 42 44 1 0 0 0 0 44 45 1 0 0 0 0 44 46 1 0 0 0 0 42 47 1 0 0 0 0 47 48 1 0 0 0 0 47 49 1 0 0 0 0 17 50 1 0 0 0 0 50 51 1 0 0 0 0 51 52 1 0 0 0 0 52 53 1 0 0 0 0 53 54 1 0 0 0 0 55 29 1 0 0 0 0 29 56 1 0 0 0 0 29 57 1 0 0 0 0 M STY 4 1 SUP 2 SUP 3 SUP 4 SUP M SAL 1 11 13 30 31 32 33 34 35 36 37 38 39 M SBL 1 1 14 M SMT 1 OTIPS M SAP 1 1 13 1 1 M SAL 2 11 18 40 41 42 43 44 45 46 47 48 49 M SBL 2 1 19 M SMT 2 OTIPS M SAP 2 1 18 15 1 M SAL 3 6 17 50 51 52 53 54 M SBL 3 1 18 M SMT 3 Hex M SAP 3 1 17 16 1 M SAL 4 4 29 55 56 57 M SBL 4 1 31 M SMT 4 CF3 M SAP 4 1 29 24 1 M END > UALIB-225 > (1S,4S,6S,7R,9aR)-Octahydro-6-methyl-4-[(1E,3S)-3-(triisopropylsiloxy)-1-decenyl)-7-(triisopropylsiloxy)-4H-quinolizin-1-yl 3-trifluoromethylbenzoate > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@]12CC[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N1[C@@H](CC[C@@H]2OC(=O)C1=CC=CC(=C1)C(F)(F)F)\C=C\[C@H](CCCCCCC)O[Si](C(C)C)(C(C)C)C(C)C > InChI=1S/C46H80F3NO4Si2/c1-15-16-17-18-19-23-41(53-55(31(2)3,32(4)5)33(6)7)26-24-40-25-28-44(52-45(51)38-21-20-22-39(30-38)46(47,48)49)42-27-29-43(37(14)50(40)42)54-56(34(8)9,35(10)11)36(12)13/h20-22,24,26,30-37,40-44H,15-19,23,25,27-29H2,1-14H3/b26-24+/t37-,40+,41-,42+,43+,44-/m0/s1 $$$$ Mrv1927 02072015252D 57 59 0 0 1 0 999 V2000 -3.1205 4.3386 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.5074 4.8906 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7228 4.6357 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5512 3.8287 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.1643 3.2767 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -2.9490 3.5316 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.9928 2.4697 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.2082 2.2148 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.5951 2.7668 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7666 3.5738 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.6059 1.9177 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.5621 2.9796 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9051 4.5935 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.4344 1.1107 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0475 0.5587 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.8759 -0.2483 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.4890 -0.8003 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.8321 0.8136 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.1535 4.1258 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.6311 3.8709 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.8026 3.0639 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.2442 4.4229 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0288 4.1680 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.6419 4.7200 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.4704 5.5270 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.6858 5.7819 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.0727 5.2299 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.1019 4.5206 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 3.3338 4.2707 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.4744 5.1032 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6461 5.9102 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6897 4.8484 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -6.0874 4.5511 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.9446 4.0637 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3925 3.4506 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7515 3.8921 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.4349 5.6330 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6279 5.8046 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.9870 6.2461 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.4013 1.3235 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.5729 2.1305 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6167 1.0685 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -6.0144 0.7714 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.8717 0.2839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3196 -0.3292 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6786 0.1124 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3618 1.8532 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.5548 2.0247 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.9138 2.4663 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.1021 -1.3523 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9307 -2.1593 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.5439 -2.7113 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3724 -3.5182 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.9856 -4.0703 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.3770 5.0945 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 4.0257 3.8213 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 2.5987 3.8961 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 6 1 1 0 0 0 0 5 7 1 0 0 0 0 7 8 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 10 4 1 0 0 0 0 7 11 1 1 0 0 0 6 12 1 1 0 0 0 1 13 1 6 0 0 0 11 14 2 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 15 18 1 6 0 0 0 10 19 1 6 0 0 0 19 20 1 0 0 0 0 20 21 2 0 0 0 0 20 22 1 0 0 0 0 23 24 2 0 0 0 0 24 25 1 0 0 0 0 25 26 2 0 0 0 0 26 27 1 0 0 0 0 22 23 1 0 0 0 0 22 27 2 0 0 0 0 4 28 1 1 0 0 0 24 29 1 0 0 0 0 33 30 1 0 0 0 0 30 31 1 0 0 0 0 30 32 1 0 0 0 0 32 13 1 0 0 0 0 32 34 1 0 0 0 0 34 35 1 0 0 0 0 34 36 1 0 0 0 0 32 37 1 0 0 0 0 37 38 1 0 0 0 0 37 39 1 0 0 0 0 43 40 1 0 0 0 0 40 41 1 0 0 0 0 40 42 1 0 0 0 0 42 18 1 0 0 0 0 42 44 1 0 0 0 0 44 45 1 0 0 0 0 44 46 1 0 0 0 0 42 47 1 0 0 0 0 47 48 1 0 0 0 0 47 49 1 0 0 0 0 17 50 1 0 0 0 0 50 51 1 0 0 0 0 51 52 1 0 0 0 0 52 53 1 0 0 0 0 53 54 1 0 0 0 0 55 29 1 0 0 0 0 29 56 1 0 0 0 0 29 57 1 0 0 0 0 M STY 4 1 SUP 2 SUP 3 SUP 4 SUP M SAL 1 11 13 30 31 32 33 34 35 36 37 38 39 M SBL 1 1 14 M SMT 1 OTIPS M SAP 1 1 13 1 1 M SAL 2 11 18 40 41 42 43 44 45 46 47 48 49 M SBL 2 1 19 M SMT 2 OTIPS M SAP 2 1 18 15 1 M SAL 3 6 17 50 51 52 53 54 M SBL 3 1 18 M SMT 3 Hex M SAP 3 1 17 16 1 M SAL 4 4 29 55 56 57 M SBL 4 1 31 M SMT 4 CF3 M SAP 4 1 29 24 1 M END > UALIB-226 > (1R,4S,6S,7R,9aR)-Octahydro-6-methyl-4-[(1E,3S)-3-(triisopropylsiloxy)-1-decenyl)-7-(triisopropylsiloxy)-4H-quinolizin-1-yl 3-trifluoromethylbenzoate > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@]12CC[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N1[C@@H](CC[C@H]2OC(=O)C1=CC=CC(=C1)C(F)(F)F)\C=C\[C@H](CCCCCCC)O[Si](C(C)C)(C(C)C)C(C)C > InChI=1S/C46H80F3NO4Si2/c1-15-16-17-18-19-23-41(53-55(31(2)3,32(4)5)33(6)7)26-24-40-25-28-44(52-45(51)38-21-20-22-39(30-38)46(47,48)49)42-27-29-43(37(14)50(40)42)54-56(34(8)9,35(10)11)36(12)13/h20-22,24,26,30-37,40-44H,15-19,23,25,27-29H2,1-14H3/b26-24+/t37-,40+,41-,42+,43+,44+/m0/s1 $$$$ Mrv1927 02072015252D 45 46 0 0 1 0 999 V2000 -3.1205 4.3386 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.5074 4.8906 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7228 4.6357 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5512 3.8287 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.1643 3.2767 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -2.9490 3.5316 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.9928 2.4697 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.2082 2.2148 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.5951 2.7668 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7666 3.5738 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.6059 1.9177 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.5621 2.9796 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9051 4.5935 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.4344 1.1107 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0475 0.5587 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.8759 -0.2483 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.4890 -0.8003 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.8321 0.8136 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.1535 4.1258 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.1019 4.5206 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -5.4744 5.1032 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6461 5.9102 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6897 4.8484 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -6.0874 4.5511 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.9446 4.0637 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3925 3.4506 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7515 3.8921 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.4349 5.6330 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6279 5.8046 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.9870 6.2461 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.4013 1.3235 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.5729 2.1305 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6167 1.0685 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -6.0144 0.7714 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.8717 0.2839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3196 -0.3292 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6786 0.1124 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3618 1.8532 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.5548 2.0247 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.9138 2.4663 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.1021 -1.3523 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9307 -2.1593 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.5439 -2.7113 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3724 -3.5182 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.9856 -4.0703 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 6 1 1 0 0 0 0 5 7 1 0 0 0 0 7 8 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 10 4 1 0 0 0 0 7 11 1 1 0 0 0 6 12 1 1 0 0 0 1 13 1 6 0 0 0 11 14 2 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 15 18 1 6 0 0 0 10 19 1 1 0 0 0 4 20 1 1 0 0 0 24 21 1 0 0 0 0 21 22 1 0 0 0 0 21 23 1 0 0 0 0 23 13 1 0 0 0 0 23 25 1 0 0 0 0 25 26 1 0 0 0 0 25 27 1 0 0 0 0 23 28 1 0 0 0 0 28 29 1 0 0 0 0 28 30 1 0 0 0 0 34 31 1 0 0 0 0 31 32 1 0 0 0 0 31 33 1 0 0 0 0 33 18 1 0 0 0 0 33 35 1 0 0 0 0 35 36 1 0 0 0 0 35 37 1 0 0 0 0 33 38 1 0 0 0 0 38 39 1 0 0 0 0 38 40 1 0 0 0 0 17 41 1 0 0 0 0 41 42 1 0 0 0 0 42 43 1 0 0 0 0 43 44 1 0 0 0 0 44 45 1 0 0 0 0 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 11 13 21 22 23 24 25 26 27 28 29 30 M SBL 1 1 14 M SMT 1 OTIPS M SAP 1 1 13 1 1 M SAL 2 11 18 31 32 33 34 35 36 37 38 39 40 M SBL 2 1 19 M SMT 2 OTIPS M SAP 2 1 18 15 1 M SAL 3 6 17 41 42 43 44 45 M SBL 3 1 18 M SMT 3 Hex M SAP 3 1 17 16 1 M END > UALIB-227 > (1S,4S,6S,7R,9aR)-Octahydro-6-methyl-4-[(1E,3S)-3-(triisopropylsiloxy)-1-decenyl)-7-(triisopropylsiloxy)-4H-quinolizin-1-ol > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@]12CC[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N1[C@@H](CC[C@@H]2O)\C=C\[C@H](CCCCCCC)O[Si](C(C)C)(C(C)C)C(C)C > InChI=1S/C38H77NO3Si2/c1-15-16-17-18-19-20-35(41-43(27(2)3,28(4)5)29(6)7)23-21-34-22-25-37(40)36-24-26-38(33(14)39(34)36)42-44(30(8)9,31(10)11)32(12)13/h21,23,27-38,40H,15-20,22,24-26H2,1-14H3/b23-21+/t33-,34+,35-,36+,37-,38+/m0/s1 $$$$ Mrv1927 02072015252D 45 46 0 0 1 0 999 V2000 -3.1205 4.3386 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.5074 4.8906 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7228 4.6357 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5512 3.8287 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.1643 3.2767 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -2.9490 3.5316 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.9928 2.4697 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.2082 2.2148 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.5951 2.7668 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7666 3.5738 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.6059 1.9177 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.5621 2.9796 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9051 4.5935 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.4344 1.1107 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0475 0.5587 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.8759 -0.2483 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.4890 -0.8003 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.8321 0.8136 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.1535 4.1258 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.1019 4.5206 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -5.4744 5.1032 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6461 5.9102 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6897 4.8484 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -6.0874 4.5511 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.9446 4.0637 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3925 3.4506 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7515 3.8921 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.4349 5.6330 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6279 5.8046 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.9870 6.2461 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.4013 1.3235 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.5729 2.1305 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6167 1.0685 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -6.0144 0.7714 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.8717 0.2839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3196 -0.3292 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6786 0.1124 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3618 1.8532 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.5548 2.0247 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.9138 2.4663 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.1021 -1.3523 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9307 -2.1593 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.5439 -2.7113 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3724 -3.5182 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.9856 -4.0703 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 6 1 1 0 0 0 0 5 7 1 0 0 0 0 7 8 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 10 4 1 0 0 0 0 7 11 1 1 0 0 0 6 12 1 1 0 0 0 1 13 1 6 0 0 0 11 14 2 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 15 18 1 6 0 0 0 10 19 1 6 0 0 0 4 20 1 1 0 0 0 24 21 1 0 0 0 0 21 22 1 0 0 0 0 21 23 1 0 0 0 0 23 13 1 0 0 0 0 23 25 1 0 0 0 0 25 26 1 0 0 0 0 25 27 1 0 0 0 0 23 28 1 0 0 0 0 28 29 1 0 0 0 0 28 30 1 0 0 0 0 34 31 1 0 0 0 0 31 32 1 0 0 0 0 31 33 1 0 0 0 0 33 18 1 0 0 0 0 33 35 1 0 0 0 0 35 36 1 0 0 0 0 35 37 1 0 0 0 0 33 38 1 0 0 0 0 38 39 1 0 0 0 0 38 40 1 0 0 0 0 17 41 1 0 0 0 0 41 42 1 0 0 0 0 42 43 1 0 0 0 0 43 44 1 0 0 0 0 44 45 1 0 0 0 0 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 11 13 21 22 23 24 25 26 27 28 29 30 M SBL 1 1 14 M SMT 1 OTIPS M SAP 1 1 13 1 1 M SAL 2 11 18 31 32 33 34 35 36 37 38 39 40 M SBL 2 1 19 M SMT 2 OTIPS M SAP 2 1 18 15 1 M SAL 3 6 17 41 42 43 44 45 M SBL 3 1 18 M SMT 3 Hex M SAP 3 1 17 16 1 M END > UALIB-228 > (1R,4S,6S,7R,9aR)-Octahydro-6-methyl-4-[(1E,3S)-3-(triisopropylsiloxy)-1-decenyl)-7-(triisopropylsiloxy)-4H-quinolizin-1-ol > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@]12CC[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N1[C@@H](CC[C@H]2O)\C=C\[C@H](CCCCCCC)O[Si](C(C)C)(C(C)C)C(C)C > InChI=1S/C38H77NO3Si2/c1-15-16-17-18-19-20-35(41-43(27(2)3,28(4)5)29(6)7)23-21-34-22-25-37(40)36-24-26-38(33(14)39(34)36)42-44(30(8)9,31(10)11)32(12)13/h21,23,27-38,40H,15-20,22,24-26H2,1-14H3/b23-21+/t33-,34+,35-,36+,37+,38+/m0/s1 $$$$ Mrv1927 02072015252D 60 62 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2679 -0.4357 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.6004 -0.9207 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8859 -0.5082 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8428 0.3157 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9598 -0.8851 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -1.7101 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6272 -2.1950 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -3.6272 -3.0200 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -3.5049 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2453 -3.0924 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6619 -3.6758 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0488 -3.1237 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3814 -3.6087 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.3537 -3.2341 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8615 1.2511 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.1509 0.7650 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.6730 0.8082 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.8445 1.6152 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7592 -0.0123 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4969 0.7650 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3623 -1.8204 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.0161 2.4222 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 1.4576 1.0632 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 0.0599 1.3603 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 0.0056 0.3232 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 1.4267 0.4725 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 0.8454 -0.8329 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 1.9462 1.4569 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.7701 1.4138 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.1446 0.6785 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.6953 -0.0132 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.8714 0.0300 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.4719 -2.1809 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.2958 -2.2240 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0974 -1.4458 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -5.0227 -2.8728 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.7227 -0.7108 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.1719 -0.0188 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.8988 -0.6677 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.8323 -1.0712 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.8754 -0.2473 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.5243 -1.5205 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 4 9 1 0 0 0 0 9 10 1 0 0 0 0 10 11 1 0 0 0 0 11 12 1 0 0 0 0 12 5 1 0 0 0 0 9 13 1 1 0 0 0 13 14 2 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 17 18 1 0 0 0 0 18 19 1 0 0 0 0 19 20 1 0 0 0 0 20 21 1 0 0 0 0 21 22 1 0 0 0 0 5 23 1 1 0 0 0 12 24 1 1 0 0 0 24 25 1 0 0 0 0 25 26 1 0 0 0 0 25 27 1 0 0 0 0 25 28 1 0 0 0 0 15 29 1 6 0 0 0 33 30 1 0 0 0 0 30 31 1 0 0 0 0 30 32 1 0 0 0 0 32 8 1 0 0 0 0 32 34 1 0 0 0 0 34 35 1 0 0 0 0 34 36 1 0 0 0 0 32 37 1 0 0 0 0 37 38 1 0 0 0 0 37 39 1 0 0 0 0 40 26 1 0 0 0 0 26 41 1 0 0 0 0 26 42 1 0 0 0 0 43 27 1 0 0 0 0 27 44 1 0 0 0 0 27 45 1 0 0 0 0 28 46 2 0 0 0 0 46 47 1 0 0 0 0 47 48 2 0 0 0 0 48 49 1 0 0 0 0 49 50 2 0 0 0 0 28 50 1 0 0 0 0 54 51 1 0 0 0 0 51 52 1 0 0 0 0 51 53 1 0 0 0 0 53 29 1 0 0 0 0 53 55 1 0 0 0 0 55 56 1 0 0 0 0 55 57 1 0 0 0 0 53 58 1 0 0 0 0 58 59 1 0 0 0 0 58 60 1 0 0 0 0 M STY 5 1 SUP 2 SUP 3 SUP 4 SUP 5 SUP M SAL 1 11 8 30 31 32 33 34 35 36 37 38 39 M SBL 1 1 8 M SMT 1 OTIPS M SAP 1 1 8 2 1 M SAL 2 4 26 40 41 42 M SBL 2 1 27 M SMT 2 CF3 M SAP 2 1 26 25 1 M SAL 3 4 27 43 44 45 M SBL 3 1 28 M SMT 3 CF3 M SAP 3 1 27 25 1 M SAL 4 6 28 46 47 48 49 50 M SBL 4 1 29 M SMT 4 Ph M SAP 4 1 28 25 1 M SAL 5 11 29 51 52 53 54 55 56 57 58 59 60 M SBL 5 1 30 M SMT 5 OTIPS M SAP 5 1 29 15 1 M END > UALIB-229 > (1R,4S,6S,7R,9aS)-Octahydro-1-(1,1,1,3,3,3-hexafluoro-2-phenyl-2-propoxy)-6-methyl-4-[(1E,3S)-3-(triisopropylsiloxy)-1-decenyl]-7-(triisopropylsiloxy)-4H-quinolizine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@]12CC[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N1[C@@H](CC[C@@H]2OC(C1=CC=CC=C1)(C(F)(F)F)C(F)(F)F)\C=C\[C@H](CCCCCCC)O[Si](C(C)C)(C(C)C)C(C)C > InChI=1S/C47H81F6NO3Si2/c1-15-16-17-18-22-25-41(56-58(32(2)3,33(4)5)34(6)7)28-26-40-27-30-44(55-45(46(48,49)50,47(51,52)53)39-23-20-19-21-24-39)42-29-31-43(38(14)54(40)42)57-59(35(8)9,36(10)11)37(12)13/h19-21,23-24,26,28,32-38,40-44H,15-18,22,25,27,29-31H2,1-14H3/b28-26+/t38-,40+,41-,42+,43+,44-/m0/s1 $$$$ Mrv1927 02072015252D 60 62 0 0 1 0 999 V2000 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2679 -0.4357 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9598 -0.8851 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -1.7101 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6272 -2.1950 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -3.6272 -3.0200 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -3.5049 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2453 -3.0924 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6619 -3.6758 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0488 -3.1237 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3814 -3.6087 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.3537 -3.2341 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3623 -1.8204 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.4974 2.2942 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6735 2.2511 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.2242 1.5592 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5142 -0.7713 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.9621 -0.1582 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7329 0.7155 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.4003 1.6023 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.3966 1.8159 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7711 1.0808 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2035 1.9874 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.2675 2.6307 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.4719 -2.1809 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.2958 -2.2240 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0974 -1.4458 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -5.0227 -2.8728 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.7227 -0.7108 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.1719 -0.0188 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.8988 -0.6677 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.8323 -1.0712 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.8754 -0.2473 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.5243 -1.5205 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2205 1.7727 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 1.1456 0.3457 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 -0.0528 1.1240 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 0.1384 3.4455 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 1.0377 2.3351 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 -0.3737 2.1115 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 1.4585 2.7720 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.2654 2.9435 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8175 2.3304 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.5625 1.5458 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.7556 1.3743 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 2 5 1 1 0 0 0 1 6 1 6 0 0 0 3 7 1 0 0 0 0 7 8 1 1 0 0 0 8 9 2 0 0 0 0 9 10 1 0 0 0 0 10 11 1 0 0 0 0 11 12 1 0 0 0 0 12 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 10 18 1 6 0 0 0 1 19 1 0 0 0 0 19 20 1 0 0 0 0 20 21 1 0 0 0 0 21 4 1 0 0 0 0 7 22 1 0 0 0 0 22 23 1 0 0 0 0 23 4 1 0 0 0 0 4 24 1 6 0 0 0 21 25 1 6 0 0 0 25 26 1 0 0 0 0 26 27 1 0 0 0 0 26 28 1 0 0 0 0 26 29 1 0 0 0 0 33 30 1 0 0 0 0 30 31 1 0 0 0 0 30 32 1 0 0 0 0 32 6 1 0 0 0 0 32 34 1 0 0 0 0 34 35 1 0 0 0 0 34 36 1 0 0 0 0 32 37 1 0 0 0 0 37 38 1 0 0 0 0 37 39 1 0 0 0 0 43 40 1 0 0 0 0 40 41 1 0 0 0 0 40 42 1 0 0 0 0 42 18 1 0 0 0 0 42 44 1 0 0 0 0 44 45 1 0 0 0 0 44 46 1 0 0 0 0 42 47 1 0 0 0 0 47 48 1 0 0 0 0 47 49 1 0 0 0 0 50 27 1 0 0 0 0 27 51 1 0 0 0 0 27 52 1 0 0 0 0 53 29 1 0 0 0 0 29 54 1 0 0 0 0 29 55 1 0 0 0 0 28 56 2 0 0 0 0 56 57 1 0 0 0 0 57 58 2 0 0 0 0 58 59 1 0 0 0 0 59 60 2 0 0 0 0 28 60 1 0 0 0 0 M STY 5 1 SUP 2 SUP 3 SUP 4 SUP 5 SUP M SAL 1 11 6 30 31 32 33 34 35 36 37 38 39 M SBL 1 1 5 M SMT 1 OTIPS M SAP 1 1 6 1 1 M SAL 2 11 18 40 41 42 43 44 45 46 47 48 49 M SBL 2 1 17 M SMT 2 OTIPS M SAP 2 1 18 10 1 M SAL 3 4 27 50 51 52 M SBL 3 1 28 M SMT 3 CF3 M SAP 3 1 27 26 1 M SAL 4 4 29 53 54 55 M SBL 4 1 30 M SMT 4 CF3 M SAP 4 1 29 26 1 M SAL 5 6 28 56 57 58 59 60 M SBL 5 1 29 M SMT 5 Ph M SAP 5 1 28 26 1 M END > UALIB-230 > (2S,3R,6S,7S,10S)-6-(1,1,1,3,3,3-hexafluoro-2-phenyl-2-propoxy)-2-Methyl-3-(triisopropylsiloxy)-10-[(1E,3S)-3-triisopropylsiloxy)-1-decenyl]-1-azabicyclo[5.3.0]decane > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@]12CC[C@@H](\C=C\[C@H](CCCCCCC)O[Si](C(C)C)(C(C)C)C(C)C)N1[C@@H](C)[C@@H](CC[C@@H]2OC(C1=CC=CC=C1)(C(F)(F)F)C(F)(F)F)O[Si](C(C)C)(C(C)C)C(C)C > InChI=1S/C47H81F6NO3Si2/c1-15-16-17-18-22-25-41(56-58(32(2)3,33(4)5)34(6)7)28-26-40-27-29-42-44(55-45(46(48,49)50,47(51,52)53)39-23-20-19-21-24-39)31-30-43(38(14)54(40)42)57-59(35(8)9,36(10)11)37(12)13/h19-21,23-24,26,28,32-38,40-44H,15-18,22,25,27,29-31H2,1-14H3/b28-26+/t38-,40+,41-,42+,43+,44-/m0/s1 $$$$ Mrv1927 02072015252D 34 35 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2679 -0.4357 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.6004 -0.9207 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8859 -0.5082 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8428 0.3157 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -0.8851 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -1.7101 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6272 -2.1950 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -3.6272 -3.0200 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -3.5049 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2453 -3.0924 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6619 -3.6758 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0488 -3.1237 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3814 -3.6087 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.3537 -3.2341 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8615 1.2511 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -4.3623 -1.8204 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -5.4719 -2.1809 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.2958 -2.2240 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0974 -1.4458 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -5.0227 -2.8728 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.7227 -0.7108 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.1719 -0.0188 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.8988 -0.6677 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.8323 -1.0712 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.8754 -0.2473 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.5243 -1.5205 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 4 9 1 0 0 0 0 9 10 1 0 0 0 0 10 11 1 0 0 0 0 11 12 1 0 0 0 0 12 5 1 0 0 0 0 9 13 1 1 0 0 0 13 14 2 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 17 18 1 0 0 0 0 18 19 1 0 0 0 0 19 20 1 0 0 0 0 20 21 1 0 0 0 0 21 22 1 0 0 0 0 5 23 1 1 0 0 0 15 24 1 6 0 0 0 28 25 1 0 0 0 0 25 26 1 0 0 0 0 25 27 1 0 0 0 0 27 24 1 0 0 0 0 27 29 1 0 0 0 0 29 30 1 0 0 0 0 29 31 1 0 0 0 0 27 32 1 0 0 0 0 32 33 1 0 0 0 0 32 34 1 0 0 0 0 M STY 1 1 SUP M SAL 1 11 24 25 26 27 28 29 30 31 32 33 34 M SBL 1 1 25 M SMT 1 OTIPS M SAP 1 1 24 15 1 M END > UALIB-231 > (4S,6S,7R,9aR)-Octahydro-6-methyl-4-[(1E,3S)-3-(triisopropylsiloxy)-1-decenyl]-4H-quinolizin-7-ol > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@@]12CCC[C@@H](\C=C\[C@H](CCCCCCC)O[Si](C(C)C)(C(C)C)C(C)C)N1[C@@H](C)[C@H](O)CC2 > InChI=1S/C29H57NO2Si/c1-9-10-11-12-13-17-28(32-33(22(2)3,23(4)5)24(6)7)20-18-26-15-14-16-27-19-21-29(31)25(8)30(26)27/h18,20,22-29,31H,9-17,19,21H2,1-8H3/b20-18+/t25-,26-,27-,28-,29+/m0/s1 $$$$ Mrv1927 02072015252D 44 45 0 0 1 0 999 V2000 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2679 -0.4357 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9598 -0.8851 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -1.7101 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6272 -2.1950 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -3.6272 -3.0200 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -3.5049 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2453 -3.0924 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6619 -3.6758 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0488 -3.1237 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3814 -3.6087 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.3537 -3.2341 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3623 -1.8204 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.4974 2.2942 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6735 2.2511 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.2242 1.5592 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5142 -0.7713 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.9621 -0.1582 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7329 0.7155 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.4719 -2.1809 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.2958 -2.2240 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0974 -1.4458 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -5.0227 -2.8728 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.7227 -0.7108 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.1719 -0.0188 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.8988 -0.6677 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.8323 -1.0712 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.8754 -0.2473 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.5243 -1.5205 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 2 5 1 1 0 0 0 1 6 1 6 0 0 0 3 7 1 0 0 0 0 7 8 1 1 0 0 0 8 9 2 0 0 0 0 9 10 1 0 0 0 0 10 11 1 0 0 0 0 11 12 1 0 0 0 0 12 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 10 18 1 6 0 0 0 1 19 1 0 0 0 0 19 20 1 0 0 0 0 20 21 1 0 0 0 0 21 4 1 0 0 0 0 7 22 1 0 0 0 0 22 23 1 0 0 0 0 23 4 1 0 0 0 0 4 24 1 6 0 0 0 28 25 1 0 0 0 0 25 26 1 0 0 0 0 25 27 1 0 0 0 0 27 6 1 0 0 0 0 27 29 1 0 0 0 0 29 30 1 0 0 0 0 29 31 1 0 0 0 0 27 32 1 0 0 0 0 32 33 1 0 0 0 0 32 34 1 0 0 0 0 38 35 1 0 0 0 0 35 36 1 0 0 0 0 35 37 1 0 0 0 0 37 18 1 0 0 0 0 37 39 1 0 0 0 0 39 40 1 0 0 0 0 39 41 1 0 0 0 0 37 42 1 0 0 0 0 42 43 1 0 0 0 0 42 44 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 11 6 25 26 27 28 29 30 31 32 33 34 M SBL 1 1 5 M SMT 1 OTIPS M SAP 1 1 6 1 1 M SAL 2 11 18 35 36 37 38 39 40 41 42 43 44 M SBL 2 1 17 M SMT 2 OTIPS M SAP 2 1 18 10 1 M END > UALIB-232 > (2S,3R,7S,10S)-2-Methyl-3-(triisopropyl)-10-[(1E,3S)-3-triisopropylsiloxy)-1-decenyl]-1-azabicyclo[5.3.0]decane > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@]12CC[C@@H](\C=C\[C@H](CCCCCCC)O[Si](C(C)C)(C(C)C)C(C)C)N1[C@@H](C)[C@@H](CCC2)O[Si](C(C)C)(C(C)C)C(C)C > InChI=1S/C38H77NO2Si2/c1-15-16-17-18-19-22-37(40-42(28(2)3,29(4)5)30(6)7)27-26-36-25-24-35-21-20-23-38(34(14)39(35)36)41-43(31(8)9,32(10)11)33(12)13/h26-38H,15-25H2,1-14H3/b27-26+/t34-,35-,36-,37-,38+/m0/s1 $$$$ Mrv1927 02072015252D 56 58 0 0 1 0 999 V2000 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2679 -0.4357 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9598 -0.8851 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -1.7101 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6272 -2.1950 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -3.6272 -3.0200 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -3.5049 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2453 -3.0924 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6619 -3.6758 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0488 -3.1237 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3814 -3.6087 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.3537 -3.2341 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3623 -1.8204 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.4974 2.2942 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6735 2.2511 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.2242 1.5592 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5142 -0.7713 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.9621 -0.1582 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7329 0.7155 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.4396 1.8141 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.2749 2.2266 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.3181 3.0505 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.0451 1.9309 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1742 1.1161 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.9444 0.8204 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.5855 1.3396 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.4565 2.1545 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.6862 2.4501 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.3000 0.9271 0.0000 N 0 3 0 0 0 0 0 0 0 0 0 0 -4.8155 1.8335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6393 1.8767 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.4409 1.0985 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9168 3.2174 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2913 3.9524 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0929 3.1742 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0580 2.9748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0149 3.7986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7931 2.6002 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.4719 -2.1809 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.2958 -2.2240 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0974 -1.4458 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -5.0227 -2.8728 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.7227 -0.7108 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.1719 -0.0188 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.8988 -0.6677 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.8323 -1.0712 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.8754 -0.2473 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.5243 -1.5205 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.0145 1.3396 0.0000 O 0 5 0 0 0 0 0 0 0 0 0 0 3.3000 0.1021 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 2 5 1 1 0 0 0 1 6 1 6 0 0 0 3 7 1 0 0 0 0 7 8 1 1 0 0 0 8 9 2 0 0 0 0 9 10 1 0 0 0 0 10 11 1 0 0 0 0 11 12 1 0 0 0 0 12 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 10 18 1 6 0 0 0 1 19 1 0 0 0 0 19 20 1 0 0 0 0 20 21 1 0 0 0 0 21 4 1 0 0 0 0 7 22 1 0 0 0 0 22 23 1 0 0 0 0 23 4 1 0 0 0 0 4 24 1 6 0 0 0 21 25 1 6 0 0 0 25 26 1 0 0 0 0 26 27 2 0 0 0 0 26 28 1 0 0 0 0 29 30 2 0 0 0 0 30 31 1 0 0 0 0 31 32 2 0 0 0 0 32 33 1 0 0 0 0 28 29 1 0 0 0 0 28 33 2 0 0 0 0 31 34 1 0 0 0 0 38 35 1 0 0 0 0 35 36 1 0 0 0 0 35 37 1 0 0 0 0 37 6 1 0 0 0 0 37 39 1 0 0 0 0 39 40 1 0 0 0 0 39 41 1 0 0 0 0 37 42 1 0 0 0 0 42 43 1 0 0 0 0 42 44 1 0 0 0 0 48 45 1 0 0 0 0 45 46 1 0 0 0 0 45 47 1 0 0 0 0 47 18 1 0 0 0 0 47 49 1 0 0 0 0 49 50 1 0 0 0 0 49 51 1 0 0 0 0 47 52 1 0 0 0 0 52 53 1 0 0 0 0 52 54 1 0 0 0 0 34 55 1 0 0 0 0 34 56 2 0 0 0 0 M CHG 2 34 1 55 -1 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 11 6 35 36 37 38 39 40 41 42 43 44 M SBL 1 1 5 M SMT 1 OTIPS M SAP 1 1 6 1 1 M SAL 2 11 18 45 46 47 48 49 50 51 52 53 54 M SBL 2 1 17 M SMT 2 OTIPS M SAP 2 1 18 10 1 M SAL 3 3 34 55 56 M SBL 3 1 36 M SMT 3 NO2 M SAP 3 1 34 31 1 M END > UALIB-233 > (2S,3R,6S,7S,10S)-2-Methyl-3-(triisopropylsiloxy)-10-[(1E,3S)-3-triisopropylsiloxy)-1-decenyl]-1-azabicyclo[6.3.0]dec-9-yl 4 nitrobenzoate > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@]12CC[C@@H](\C=C\[C@H](CCCCCCC)O[Si](C(C)C)(C(C)C)C(C)C)N1[C@@H](C)[C@@H](CC[C@@H]2OC(=O)C1=CC=C(C=C1)[N+]([O-])=O)O[Si](C(C)C)(C(C)C)C(C)C > InChI=1S/C45H80N2O6Si2/c1-15-16-17-18-19-20-41(52-54(31(2)3,32(4)5)33(6)7)27-25-39-26-28-42-44(51-45(48)38-21-23-40(24-22-38)47(49)50)30-29-43(37(14)46(39)42)53-55(34(8)9,35(10)11)36(12)13/h21-25,27,31-37,39,41-44H,15-20,26,28-30H2,1-14H3/b27-25+/t37-,39+,41-,42+,43+,44-/m0/s1 $$$$ Mrv1927 02072015252D 35 36 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2679 -0.4357 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.6004 -0.9207 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8859 -0.5082 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8428 0.3157 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.9598 -0.8851 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -1.7101 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6272 -2.1950 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -3.6272 -3.0200 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -3.5049 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2453 -3.0924 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6619 -3.6758 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0488 -3.1237 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3814 -3.6087 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.3537 -3.2341 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8615 1.2511 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -4.3623 -1.8204 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.0279 0.4448 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -5.4719 -2.1809 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.2958 -2.2240 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0974 -1.4458 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -5.0227 -2.8728 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.7227 -0.7108 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.1719 -0.0188 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.8988 -0.6677 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.8323 -1.0712 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.8754 -0.2473 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.5243 -1.5205 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 4 9 1 0 0 0 0 9 10 1 0 0 0 0 10 11 1 0 0 0 0 11 12 1 0 0 0 0 12 5 1 0 0 0 0 9 13 1 1 0 0 0 13 14 2 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 17 18 1 0 0 0 0 18 19 1 0 0 0 0 19 20 1 0 0 0 0 20 21 1 0 0 0 0 21 22 1 0 0 0 0 5 23 1 1 0 0 0 15 24 1 6 0 0 0 12 25 1 6 0 0 0 29 26 1 0 0 0 0 26 27 1 0 0 0 0 26 28 1 0 0 0 0 28 24 1 0 0 0 0 28 30 1 0 0 0 0 30 31 1 0 0 0 0 30 32 1 0 0 0 0 28 33 1 0 0 0 0 33 34 1 0 0 0 0 33 35 1 0 0 0 0 M STY 1 1 SUP M SAL 1 11 24 26 27 28 29 30 31 32 33 34 35 M SBL 1 1 25 M SMT 1 OTIPS M SAP 1 1 24 15 1 M END > UALIB-234 > alpha-alcohol of (1S,4S,6S,7R,9aR)-Octahydro-6-methyl-4-[(1E,3S)-3-(triisopropylsiloxy)-1-decenyl)-7-(triisopropylsiloxy)-4H-quinolizin-1-ol > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@]12CC[C@@H](O)[C@H](C)N1[C@@H](CC[C@H]2O)\C=C\[C@H](CCCCCCC)O[Si](C(C)C)(C(C)C)C(C)C > InChI=1S/C29H57NO3Si/c1-9-10-11-12-13-14-26(33-34(21(2)3,22(4)5)23(6)7)17-15-25-16-19-29(32)27-18-20-28(31)24(8)30(25)27/h15,17,21-29,31-32H,9-14,16,18-20H2,1-8H3/b17-15+/t24-,25+,26-,27+,28+,29+/m0/s1 $$$$ Mrv1927 02072015252D 37 38 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2679 -0.4357 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.6004 -0.9207 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8859 -0.5082 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8428 0.3157 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -0.8851 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -1.7101 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6272 -2.1950 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -3.6272 -3.0200 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -3.5049 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2453 -3.0924 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6619 -3.6758 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0488 -3.1237 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3814 -3.6087 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.3537 -3.2341 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8615 1.2511 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -4.3623 -1.8204 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -5.4719 -2.1809 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.2958 -2.2240 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.0974 -1.4458 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -5.0227 -2.8728 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.7227 -0.7108 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.1719 -0.0188 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.8988 -0.6677 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.8323 -1.0712 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.8754 -0.2473 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.5243 -1.5205 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3230 3.3493 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.1012 2.1509 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 4 9 1 0 0 0 0 9 10 1 0 0 0 0 10 11 1 0 0 0 0 11 12 1 0 0 0 0 12 5 1 0 0 0 0 9 13 1 1 0 0 0 13 14 2 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 17 18 1 0 0 0 0 18 19 1 0 0 0 0 19 20 1 0 0 0 0 20 21 1 0 0 0 0 21 22 1 0 0 0 0 5 23 1 1 0 0 0 15 24 1 6 0 0 0 28 25 1 0 0 0 0 25 26 1 0 0 0 0 25 27 1 0 0 0 0 27 24 1 0 0 0 0 27 29 1 0 0 0 0 29 30 1 0 0 0 0 29 31 1 0 0 0 0 27 32 1 0 0 0 0 32 33 1 0 0 0 0 32 34 1 0 0 0 0 36 35 1 0 0 0 0 35 8 1 0 0 0 0 35 37 2 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 11 24 25 26 27 28 29 30 31 32 33 34 M SBL 1 1 25 M SMT 1 OTIPS M SAP 1 1 24 15 1 M SAL 2 4 8 35 36 37 M SBL 2 1 8 M SMT 2 OAc M SAP 2 1 8 2 1 M END > UALIB-235 > (4S,6S,7R,9aR)-Octahydro-6-methyl-4-[(1E,3S)-3-(triisopropylsiloxy)-1-decenyl]-4H-quinolizin-7-yl Acetate > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@@]12CCC[C@@H](\C=C\[C@H](CCCCCCC)O[Si](C(C)C)(C(C)C)C(C)C)N1[C@@H](C)[C@@H](CC2)OC(C)=O > InChI=1S/C31H59NO3Si/c1-10-11-12-13-14-18-30(35-36(23(2)3,24(4)5)25(6)7)21-19-28-16-15-17-29-20-22-31(34-27(9)33)26(8)32(28)29/h19,21,23-26,28-31H,10-18,20,22H2,1-9H3/b21-19+/t26-,28-,29-,30-,31+/m0/s1 $$$$ Mrv1927 02072015252D 27 28 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2679 -0.4357 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.6004 -0.9207 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8859 -0.5082 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8428 0.3157 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -0.8851 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -1.7101 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6272 -2.1950 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -3.6272 -3.0200 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -3.5049 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2453 -3.0924 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6619 -3.6758 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0488 -3.1237 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3814 -3.6087 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.3537 -3.2341 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8615 1.2511 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -4.3623 -1.8204 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3230 3.3493 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.1012 2.1509 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 4 9 1 0 0 0 0 9 10 1 0 0 0 0 10 11 1 0 0 0 0 11 12 1 0 0 0 0 12 5 1 0 0 0 0 9 13 1 1 0 0 0 13 14 2 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 17 18 1 0 0 0 0 18 19 1 0 0 0 0 19 20 1 0 0 0 0 20 21 1 0 0 0 0 21 22 1 0 0 0 0 5 23 1 1 0 0 0 15 24 1 6 0 0 0 26 25 1 0 0 0 0 25 8 1 0 0 0 0 25 27 2 0 0 0 0 M STY 1 1 SUP M SAL 1 4 8 25 26 27 M SBL 1 1 8 M SMT 1 OAc M SAP 1 1 8 2 1 M END > UALIB-236 > (4S,6S,7R,9aR)-Octahydro-6-methyl-4-[(1E,3S)-3-hydroxy-1-decenyl]-4H-quinolizin-7-yl Acetate > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@@]12CCC[C@@H](\C=C\[C@@H](O)CCCCCCC)N1[C@@H](C)[C@@H](CC2)OC(C)=O > InChI=1S/C22H39NO3/c1-4-5-6-7-8-12-21(25)15-13-19-10-9-11-20-14-16-22(26-18(3)24)17(2)23(19)20/h13,15,17,19-22,25H,4-12,14,16H2,1-3H3/b15-13+/t17-,19-,20-,21-,22+/m0/s1 $$$$ Mrv1927 02072015252D 32 33 0 0 1 0 999 V2000 -2.2679 2.0214 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6089 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 0.7839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2679 0.3714 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.7839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 1.6089 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3110 -0.4525 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8615 0.3346 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1264 0.7091 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.5655 0.2598 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6087 -0.5641 0.0000 Se 0 0 0 0 0 0 0 0 0 0 0 0 1.3357 0.5555 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3789 1.3793 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1326 1.7149 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.7580 2.4500 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.4499 2.8993 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.8979 3.5124 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6087 -1.3891 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1058 -1.8016 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1058 -2.6266 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6087 -3.0391 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3231 -2.6266 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3231 -1.8016 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0376 -1.3891 0.0000 N 0 3 0 0 0 0 0 0 0 0 0 0 -0.1490 -0.1525 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.2587 0.2079 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.5094 -1.2621 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6191 -0.9017 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.8841 -0.5270 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0461 -0.8271 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 2.0376 -0.5641 0.0000 O 0 5 0 0 0 0 0 0 0 0 0 0 2.7521 -1.8016 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 4 7 1 0 0 0 0 5 8 1 0 0 0 0 8 9 2 0 0 0 0 9 10 1 0 0 0 0 10 11 1 0 0 0 0 10 12 1 0 0 0 0 12 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 11 18 1 0 0 0 0 19 20 2 0 0 0 0 20 21 1 0 0 0 0 21 22 2 0 0 0 0 22 23 1 0 0 0 0 18 19 1 0 0 0 0 18 23 2 0 0 0 0 23 24 1 0 0 0 0 29 25 1 0 0 0 0 29 26 1 0 0 0 0 29 27 1 0 0 0 0 29 28 1 0 0 0 0 28 7 1 0 0 0 0 7 30 2 0 0 0 0 24 31 1 0 0 0 0 24 32 2 0 0 0 0 M CHG 2 24 1 31 -1 M STY 2 1 SUP 2 SUP M SAL 1 7 7 25 26 27 28 29 30 M SBL 1 1 7 M SMT 1 Boc M SAP 1 1 7 4 1 M SAL 2 3 24 31 32 M SBL 2 1 25 M SMT 2 NO2 M SAP 2 1 24 23 1 M END > UALIB-237 > N-(t-Butyloxycarbonyl)-2-[(1E)-3-(2-nitrophenyl)seleno-1-nonenyl]piperidine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CCCCCCC([Se]C1=C(C=CC=C1)[N+]([O-])=O)\C=C\C1CCCCN1C(=O)OC(C)(C)C > InChI=1S/C25H38N2O4Se/c1-5-6-7-8-14-21(32-23-16-10-9-15-22(23)27(29)30)18-17-20-13-11-12-19-26(20)24(28)31-25(2,3)4/h9-10,15-18,20-21H,5-8,11-14,19H2,1-4H3/b18-17+ $$$$ Mrv1927 02072015252D 23 23 0 0 1 0 999 V2000 -2.2679 2.0214 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6089 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 0.7839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2679 0.3714 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.7839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 1.6089 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3110 -0.4525 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8615 0.3346 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1264 0.7091 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.5655 0.2598 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6087 -0.5641 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.3357 0.5555 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3789 1.3793 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1326 1.7149 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.7580 2.4500 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.4499 2.8993 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.8979 3.5124 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1490 -0.1525 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.2587 0.2079 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.5094 -1.2621 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6191 -0.9017 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.8841 -0.5270 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0461 -0.8271 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 4 7 1 0 0 0 0 5 8 1 0 0 0 0 8 9 2 0 0 0 0 9 10 1 0 0 0 0 10 11 1 0 0 0 0 10 12 1 0 0 0 0 12 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 22 18 1 0 0 0 0 22 19 1 0 0 0 0 22 20 1 0 0 0 0 22 21 1 0 0 0 0 21 7 1 0 0 0 0 7 23 2 0 0 0 0 M STY 1 1 SUP M SAL 1 7 7 18 19 20 21 22 23 M SBL 1 1 7 M SMT 1 Boc M SAP 1 1 7 4 1 M END > UALIB-238 > N-(t-Butyloxycarbonyl)-2-[(2E)-1-hydroxy-2-nonenyl]piperidine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CCCCCCC(O)\C=C\C1CCCCN1C(=O)OC(C)(C)C > InChI=1S/C19H35NO3/c1-5-6-7-8-12-17(21)14-13-16-11-9-10-15-20(16)18(22)23-19(2,3)4/h13-14,16-17,21H,5-12,15H2,1-4H3/b14-13+ $$$$ Mrv1927 02072015252D 29 31 0 0 1 0 999 V2000 -2.2679 2.0214 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6089 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 0.7839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2679 0.3714 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.7839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 1.6089 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3110 -0.4525 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8615 0.3346 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1264 0.7091 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.5655 0.2598 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6087 -0.5641 0.0000 S 0 0 0 0 0 0 0 0 0 0 0 0 1.3357 0.5555 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3789 1.3793 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1326 1.7149 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.7580 2.4500 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.4499 2.8993 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.8979 3.5124 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6087 -1.3891 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1058 -1.8016 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1058 -2.6266 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6087 -3.0391 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3231 -2.6266 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3231 -1.8016 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7052 -2.5494 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.4403 -2.9241 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.1322 -2.4748 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0891 -1.6510 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3541 -1.2763 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6621 -1.7256 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 4 7 1 0 0 0 0 5 8 1 0 0 0 0 8 9 2 0 0 0 0 9 10 1 0 0 0 0 10 11 1 0 0 0 0 10 12 1 0 0 0 0 12 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 11 18 1 0 0 0 0 19 20 2 0 0 0 0 20 21 1 0 0 0 0 21 22 2 0 0 0 0 22 23 1 0 0 0 0 18 19 1 0 0 0 0 18 23 2 0 0 0 0 29 24 2 0 0 0 0 24 25 1 0 0 0 0 25 26 2 0 0 0 0 26 27 1 0 0 0 0 27 28 2 0 0 0 0 29 28 1 0 0 0 0 28 7 1 0 0 0 0 M STY 1 1 SUP M SAL 1 7 7 24 25 26 27 28 29 M SBL 1 1 7 M SMT 1 Bn M SAP 1 1 7 4 1 M END > UALIB-239 > N-Benzyl-2-[(1E)-3-phenylthio-1-nonenyl]piperidine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CCCCCCC(SC1=CC=CC=C1)\C=C\C1CCCCN1CC1=CC=CC=C1 > InChI=1S/C27H37NS/c1-2-3-4-9-19-27(29-26-17-10-6-11-18-26)21-20-25-16-12-13-22-28(25)23-24-14-7-5-8-15-24/h5-8,10-11,14-15,17-18,20-21,25,27H,2-4,9,12-13,16,19,22-23H2,1H3/b21-20+ $$$$ Mrv1927 02072015252D 44 46 0 0 1 0 999 V2000 -2.2679 2.0214 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6089 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 0.7839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2679 0.3714 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.7839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 1.6089 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3110 -0.4525 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8615 0.3346 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1264 0.7091 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.5655 0.2598 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2800 0.6723 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2800 1.4973 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.9211 2.0165 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4718 2.7084 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0849 3.2604 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.7493 4.0141 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.5882 -0.2053 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.8737 -0.6178 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.8737 -1.4428 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.5882 -1.8553 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 5.3026 -1.4428 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.3026 -0.6178 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.5450 -2.6792 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.9945 -1.8921 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.7296 -1.5176 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.4215 -1.9669 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.1360 -1.5544 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.8505 -1.9669 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.5149 -2.7206 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.0669 -3.3337 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.3525 -3.7462 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.0669 -4.1587 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.8244 -2.0254 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.5163 -1.5761 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.4731 -0.7522 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7380 -0.3777 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0461 -0.8270 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0893 -1.6509 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.0317 -4.2521 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.3398 -3.8028 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.3829 -2.9789 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.1180 -2.6044 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.8099 -3.0537 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.7667 -3.8776 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 4 7 1 0 0 0 0 5 8 1 0 0 0 0 8 9 2 0 0 0 0 9 10 1 0 0 0 0 10 11 2 0 0 0 0 11 12 1 0 0 0 0 12 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 17 18 1 0 0 0 0 18 19 1 0 0 0 0 19 20 1 0 0 0 0 20 21 1 0 0 0 0 21 22 1 0 0 0 0 17 22 1 0 0 0 0 20 23 1 0 0 0 0 21 24 1 0 0 0 0 24 25 2 0 0 0 0 25 26 1 0 0 0 0 26 27 2 0 0 0 0 27 28 1 0 0 0 0 28 29 1 0 0 0 0 29 30 1 0 0 0 0 30 31 1 0 0 0 0 31 32 1 0 0 0 0 38 33 2 0 0 0 0 33 34 1 0 0 0 0 34 35 2 0 0 0 0 35 36 1 0 0 0 0 36 37 2 0 0 0 0 38 37 1 0 0 0 0 37 7 1 0 0 0 0 44 39 2 0 0 0 0 39 40 1 0 0 0 0 40 41 2 0 0 0 0 41 42 1 0 0 0 0 42 43 2 0 0 0 0 44 43 1 0 0 0 0 43 23 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 7 7 33 34 35 36 37 38 M SBL 1 1 7 M SMT 1 Bn M SAP 1 1 7 4 1 M SDS EXP 1 1 M SAL 2 7 23 39 40 41 42 43 44 M SBL 2 1 23 M SMT 2 Bn M SAP 2 1 23 20 1 M SDS EXP 1 2 M END > UALIB-240 > N-Benzyl-2-[(1E,2E)-1,3-nonanedienyl]piperidine and N-Benzyl-2-[(1E,2Z)-1,3-nonanedienyl]piperidine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CCCCC\C=C\C=C\C1CCCCN1CC1=CC=CC=C1.CCCCC\C=C/C=C/C1CCCCN1CC1=CC=CC=C1 > InChI=1S/2C21H31N/c2*1-2-3-4-5-6-7-11-16-21-17-12-13-18-22(21)19-20-14-9-8-10-15-20/h2*6-11,14-16,21H,2-5,12-13,17-19H2,1H3/b7-6+,16-11+;7-6-,16-11+ $$$$ Mrv1927 02072015252D 33 35 0 0 1 0 999 V2000 -2.2679 2.0393 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9823 1.6268 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.9823 0.8018 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.2679 0.3893 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.5534 0.8018 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.5534 1.6268 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7525 0.5061 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6742 2.0761 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.2679 -0.4357 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.6004 -0.9207 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8859 -0.5082 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8428 0.3157 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -0.8851 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -1.7101 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.6272 -2.1950 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -3.6272 -3.0200 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9598 -3.5049 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.2453 -3.0924 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6619 -3.6758 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0488 -3.1237 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3814 -3.6087 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.3537 -3.2341 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.8615 1.2511 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -4.3623 -1.8204 0.0000 S 0 0 0 0 0 0 0 0 0 0 0 0 -4.9249 -1.2171 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7288 -1.4027 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.2914 -0.7993 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.0502 -0.0103 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.2464 0.1752 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6837 -0.4281 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3661 2.5254 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3230 3.3493 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.1012 2.1509 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 3 7 1 1 0 0 0 2 8 1 6 0 0 0 4 9 1 0 0 0 0 9 10 1 0 0 0 0 10 11 1 0 0 0 0 11 12 1 0 0 0 0 12 5 1 0 0 0 0 9 13 1 1 0 0 0 13 14 2 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 17 18 1 0 0 0 0 18 19 1 0 0 0 0 19 20 1 0 0 0 0 20 21 1 0 0 0 0 21 22 1 0 0 0 0 5 23 1 1 0 0 0 15 24 1 1 0 0 0 24 25 1 0 0 0 0 25 26 2 0 0 0 0 26 27 1 0 0 0 0 27 28 2 0 0 0 0 28 29 1 0 0 0 0 29 30 2 0 0 0 0 25 30 1 0 0 0 0 32 31 1 0 0 0 0 31 8 1 0 0 0 0 31 33 2 0 0 0 0 M STY 1 1 SUP M SAL 1 4 8 31 32 33 M SBL 1 1 8 M SMT 1 OAc M SAP 1 1 8 2 1 M END > UALIB-241 > (4S,6S,7R,9aR)-Octahydro-6-methyl-4-[(1E,3R)-3-phenylthio-1-decenyl]-4H-quinolizin-7-yl acetate > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@@]12CCC[C@@H](\C=C\[C@@H](CCCCCCC)SC3=CC=CC=C3)N1[C@@H](C)[C@@H](CC2)OC(C)=O > InChI=1S/C28H43NO2S/c1-4-5-6-7-9-17-27(32-26-15-10-8-11-16-26)20-18-24-13-12-14-25-19-21-28(31-23(3)30)22(2)29(24)25/h8,10-11,15-16,18,20,22,24-25,27-28H,4-7,9,12-14,17,19,21H2,1-3H3/b20-18+/t22-,24-,25-,27+,28+/m0/s1 $$$$ Mrv1927 02072015252D 24 25 0 0 0 0 999 V2000 -1.8080 1.5839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5225 1.1714 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5225 0.3464 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.8080 -0.0661 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.0936 0.3464 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0936 1.1714 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7649 -0.8900 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.4524 -0.1728 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.4568 -1.3392 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.0298 -1.2646 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.3379 -0.8154 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.3972 -1.1899 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.0891 -0.7407 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.8242 -1.1153 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.8673 -1.9392 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1753 -2.3884 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4403 -2.0138 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.1887 -0.6920 0.0000 S 0 0 0 0 0 0 0 0 0 0 0 0 -0.3303 -1.3331 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.7079 -0.0506 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.8301 -1.2109 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4712 -1.7301 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 0.3109 -1.8521 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 1.3491 -0.5698 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 2 0 0 0 0 1 6 1 0 0 0 0 4 7 1 0 0 0 0 5 8 1 0 0 0 0 9 7 2 0 0 0 0 7 10 1 0 0 0 0 10 11 1 0 0 0 0 11 12 1 0 0 0 0 12 13 2 0 0 0 0 13 14 1 0 0 0 0 14 15 2 0 0 0 0 15 16 1 0 0 0 0 16 17 2 0 0 0 0 12 17 1 0 0 0 0 8 18 1 0 0 0 0 18 19 2 0 0 0 0 18 20 2 0 0 0 0 18 21 1 0 0 0 0 21 22 1 0 0 0 0 21 23 1 0 0 0 0 21 24 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 10 7 9 10 11 12 13 14 15 16 17 M SBL 1 1 7 M SMT 1 Cbz M SAP 1 1 7 4 1 M SAL 2 8 8 18 19 20 21 22 23 24 M SBL 2 1 8 M SMT 2 OTf M SAP 2 1 8 5 1 M END > UALIB-242 > Trifluoromethanesulfonic acid N-(Benzyloxycarbonyl)-1,2,3,4-tetrahydropyridin-6-yl ester > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > FC(F)(F)S(=O)(=O)OC1=CCCCN1C(=O)OCC1=CC=CC=C1 > InChI=1S/C14H14F3NO5S/c15-14(16,17)24(20,21)23-12-8-4-5-9-18(12)13(19)22-10-11-6-2-1-3-7-11/h1-3,6-8H,4-5,9-10H2 $$$$ Mrv1927 02072015252D 36 37 0 0 1 0 999 V2000 -1.8080 1.5839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5225 1.1714 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5225 0.3464 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.8080 -0.0661 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.0936 0.3464 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0936 1.1714 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7649 -0.8900 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.4524 -0.1728 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.1356 -0.2056 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.8275 0.2437 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.4568 -1.3392 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.0298 -1.2646 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.3379 -0.8154 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.3972 -1.1899 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.0891 -0.7407 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.8242 -1.1153 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.8673 -1.9392 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1753 -2.3884 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4403 -2.0138 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.1887 -0.6920 0.0000 S 0 0 0 0 0 0 0 0 0 0 0 0 -0.3303 -1.3331 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.7079 -0.0506 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.8301 -1.2109 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4712 -1.7301 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 0.3109 -1.8521 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 1.3491 -0.5698 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 -4.9687 0.0011 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7926 0.0443 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.5194 0.6930 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.5942 -0.7339 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.0701 1.3849 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.4446 2.1200 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.2462 1.3418 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.2113 1.1424 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.1681 1.9662 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.9464 0.7678 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 2 0 0 0 0 1 6 1 0 0 0 0 4 7 1 0 0 0 0 5 8 1 0 0 0 0 3 9 1 0 0 0 0 9 10 1 0 0 0 0 11 7 2 0 0 0 0 7 12 1 0 0 0 0 12 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 2 0 0 0 0 15 16 1 0 0 0 0 16 17 2 0 0 0 0 17 18 1 0 0 0 0 18 19 2 0 0 0 0 14 19 1 0 0 0 0 8 20 1 0 0 0 0 20 21 2 0 0 0 0 20 22 2 0 0 0 0 20 23 1 0 0 0 0 23 24 1 0 0 0 0 23 25 1 0 0 0 0 23 26 1 0 0 0 0 30 27 1 0 0 0 0 27 28 1 0 0 0 0 27 29 1 0 0 0 0 29 10 1 0 0 0 0 29 31 1 0 0 0 0 31 32 1 0 0 0 0 31 33 1 0 0 0 0 29 34 1 0 0 0 0 34 35 1 0 0 0 0 34 36 1 0 0 0 0 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 10 7 11 12 13 14 15 16 17 18 19 M SBL 1 1 7 M SMT 1 Cbz M SAP 1 1 7 4 1 M SAL 2 8 8 20 21 22 23 24 25 26 M SBL 2 1 8 M SMT 2 OTf M SAP 2 1 8 5 1 M SAL 3 11 10 27 28 29 30 31 32 33 34 35 36 M SBL 3 1 10 M SMT 3 OTIPS M SAP 3 1 10 9 1 M END > UALIB-243 > Trifluoromethanesulfonic acid N-(Benzyloxycarbonyl)-2-(triisopropylsiloxymethyl)-1,2,3,4-tetrahydropyridin-6-yl ester > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CC(C)[Si](OCC1CCC=C(OS(=O)(=O)C(F)(F)F)N1C(=O)OCC1=CC=CC=C1)(C(C)C)C(C)C > InChI=1S/C24H36F3NO6SSi/c1-17(2)36(18(3)4,19(5)6)33-16-21-13-10-14-22(34-35(30,31)24(25,26)27)28(21)23(29)32-15-20-11-8-7-9-12-20/h7-9,11-12,14,17-19,21H,10,13,15-16H2,1-6H3 $$$$ Mrv1927 02072015252D 27 28 0 0 1 0 999 V2000 -1.8080 1.5839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5225 1.1714 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5225 0.3464 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.8080 -0.0661 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.0936 0.3464 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0936 1.1714 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7649 -0.8900 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.4524 -0.1728 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.1356 -0.2056 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7487 0.3464 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.5189 0.0508 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.4568 -1.3392 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.0298 -1.2646 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.3379 -0.8154 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.3972 -1.1899 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.0891 -0.7407 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.8242 -1.1153 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.8673 -1.9392 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1753 -2.3884 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4403 -2.0138 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.1887 -0.6920 0.0000 S 0 0 0 0 0 0 0 0 0 0 0 0 -0.3303 -1.3331 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.7079 -0.0506 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.8301 -1.2109 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4712 -1.7301 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 0.3109 -1.8521 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 1.3491 -0.5698 0.0000 F 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 2 0 0 0 0 1 6 1 0 0 0 0 4 7 1 0 0 0 0 5 8 1 0 0 0 0 3 9 1 0 0 0 0 9 10 1 0 0 0 0 10 11 2 0 0 0 0 12 7 2 0 0 0 0 7 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 2 0 0 0 0 16 17 1 0 0 0 0 17 18 2 0 0 0 0 18 19 1 0 0 0 0 19 20 2 0 0 0 0 15 20 1 0 0 0 0 8 21 1 0 0 0 0 21 22 2 0 0 0 0 21 23 2 0 0 0 0 21 24 1 0 0 0 0 24 25 1 0 0 0 0 24 26 1 0 0 0 0 24 27 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 10 7 12 13 14 15 16 17 18 19 20 M SBL 1 1 7 M SMT 1 Cbz M SAP 1 1 7 4 1 M SAL 2 8 8 21 22 23 24 25 26 27 M SBL 2 1 8 M SMT 2 OTf M SAP 2 1 8 5 1 M END > UALIB-244 > Trifluoromethanesulfonic acid N-(Benzyloxycarbonyl)-2-(propenyl)-1,2,3,4-tetrahydropyridin-6-yl ester > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > FC(F)(F)S(=O)(=O)OC1=CCCC(CC=C)N1C(=O)OCC1=CC=CC=C1 > InChI=1S/C17H18F3NO5S/c1-2-7-14-10-6-11-15(26-27(23,24)17(18,19)20)21(14)16(22)25-12-13-8-4-3-5-9-13/h2-5,8-9,11,14H,1,6-7,10,12H2 $$$$ Mrv1927 02072015252D 30 31 0 0 1 0 999 V2000 -1.8080 1.5839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5225 1.1714 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.5225 0.3464 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.8080 -0.0661 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.0936 0.3464 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0936 1.1714 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7649 -0.8900 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.4524 -0.1728 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.2620 0.2397 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.2370 -0.0661 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.2370 1.5839 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.4568 -1.3392 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.0298 -1.2646 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.3379 -0.8154 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.3972 -1.1899 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.0891 -0.7407 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.8242 -1.1153 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.8673 -1.9392 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1753 -2.3884 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4403 -2.0138 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3639 1.2818 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.1889 1.2817 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9514 1.9964 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -3.9512 0.5675 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.5392 2.7109 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9517 3.4254 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.7142 2.7109 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6659 2.4087 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6661 3.2337 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.3804 1.9962 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 2 0 0 0 0 1 6 1 0 0 0 0 4 7 1 0 0 0 0 5 8 1 0 0 0 0 8 9 2 0 0 0 0 3 10 1 1 0 0 0 2 11 1 6 0 0 0 12 7 2 0 0 0 0 7 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 2 0 0 0 0 16 17 1 0 0 0 0 17 18 2 0 0 0 0 18 19 1 0 0 0 0 19 20 2 0 0 0 0 15 20 1 0 0 0 0 24 21 1 0 0 0 0 21 22 1 0 0 0 0 21 23 1 0 0 0 0 23 11 1 0 0 0 0 23 25 1 0 0 0 0 25 26 1 0 0 0 0 25 27 1 0 0 0 0 23 28 1 0 0 0 0 28 29 1 0 0 0 0 28 30 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 10 7 12 13 14 15 16 17 18 19 20 M SBL 1 1 7 M SMT 1 Cbz M SAP 1 1 7 4 1 M SAL 2 11 11 21 22 23 24 25 26 27 28 29 30 M SBL 2 1 11 M SMT 2 OTIPS M SAP 2 1 11 2 1 M END > UALIB-245 > (2S,3R)-N-(Benzyloxycarbonyl)-6-vinyl-2-methyl-3-(triisopropylsiloxy)-1,2,3,4-tetrahydropyridine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CC(C)[Si](O[C@@H]1CC=C(C=C)N([C@H]1C)C(=O)OCC1=CC=CC=C1)(C(C)C)C(C)C > InChI=1S/C25H39NO3Si/c1-9-23-15-16-24(29-30(18(2)3,19(4)5)20(6)7)21(8)26(23)25(27)28-17-22-13-11-10-12-14-22/h9-15,18-21,24H,1,16-17H2,2-8H3/t21-,24+/m0/s1 $$$$ Mrv1927 02072015252D 18 19 0 0 0 0 999 V2000 -1.8080 1.5839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5225 1.1714 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5225 0.3464 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.8080 -0.0661 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.0936 0.3464 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0936 1.1714 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7649 -0.8900 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.4524 -0.1728 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.2620 0.2397 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.4568 -1.3392 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.0298 -1.2646 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.3379 -0.8154 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.3972 -1.1899 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.0891 -0.7407 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.8242 -1.1153 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.8673 -1.9392 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1753 -2.3884 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4403 -2.0138 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 2 0 0 0 0 1 6 1 0 0 0 0 4 7 1 0 0 0 0 5 8 1 0 0 0 0 8 9 2 0 0 0 0 10 7 2 0 0 0 0 7 11 1 0 0 0 0 11 12 1 0 0 0 0 12 13 1 0 0 0 0 13 14 2 0 0 0 0 14 15 1 0 0 0 0 15 16 2 0 0 0 0 16 17 1 0 0 0 0 17 18 2 0 0 0 0 13 18 1 0 0 0 0 M STY 1 1 SUP M SAL 1 10 7 10 11 12 13 14 15 16 17 18 M SBL 1 1 7 M SMT 1 Cbz M SAP 1 1 7 4 1 M END > UALIB-246 > N-(Benzyloxycarbonyl)-6-vinyl-1,2,3,4-tetrahydropyridine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > C=CC1=CCCCN1C(=O)OCC1=CC=CC=C1 > InChI=1S/C15H17NO2/c1-2-14-10-6-7-11-16(14)15(17)18-12-13-8-4-3-5-9-13/h2-5,8-10H,1,6-7,11-12H2 $$$$ Mrv1927 02072015252D 30 31 0 0 1 0 999 V2000 -1.8080 1.5839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5225 1.1714 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5225 0.3464 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.8080 -0.0661 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.0936 0.3464 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0936 1.1714 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7649 -0.8900 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.4524 -0.1728 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.2620 0.2397 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.2144 -0.1029 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7664 0.5102 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.4568 -1.3392 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.0298 -1.2646 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.3379 -0.8154 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.3972 -1.1899 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.0891 -0.7407 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.8242 -1.1153 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.8673 -1.9392 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1753 -2.3884 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4403 -2.0138 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.9316 0.5713 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.7162 0.8264 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.3184 1.1233 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.7601 -0.2356 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.7053 1.6753 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.8767 2.4823 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.9207 1.4203 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.8704 1.7365 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6154 2.5211 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6774 1.5650 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 2 0 0 0 0 1 6 1 0 0 0 0 4 7 1 0 0 0 0 5 8 1 0 0 0 0 8 9 2 0 0 0 0 3 10 1 0 0 0 0 10 11 1 0 0 0 0 12 7 2 0 0 0 0 7 13 1 0 0 0 0 13 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 2 0 0 0 0 16 17 1 0 0 0 0 17 18 2 0 0 0 0 18 19 1 0 0 0 0 19 20 2 0 0 0 0 15 20 1 0 0 0 0 24 21 1 0 0 0 0 21 22 1 0 0 0 0 21 23 1 0 0 0 0 23 11 1 0 0 0 0 23 25 1 0 0 0 0 25 26 1 0 0 0 0 25 27 1 0 0 0 0 23 28 1 0 0 0 0 28 29 1 0 0 0 0 28 30 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 10 7 12 13 14 15 16 17 18 19 20 M SBL 1 1 7 M SMT 1 Cbz M SAP 1 1 7 4 1 M SAL 2 11 11 21 22 23 24 25 26 27 28 29 30 M SBL 2 1 11 M SMT 2 OTIPS M SAP 2 1 11 10 1 M END > UALIB-247 > N-(Benzyloxycarbonyl)-6-vinyl-2-(triisopropylsiloxymethyl)-1,2,3,4-tetrahydropyridine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CC(C)[Si](OCC1CCC=C(C=C)N1C(=O)OCC1=CC=CC=C1)(C(C)C)C(C)C > InChI=1S/C25H39NO3Si/c1-8-23-15-12-16-24(18-29-30(19(2)3,20(4)5)21(6)7)26(23)25(27)28-17-22-13-10-9-11-14-22/h8-11,13-15,19-21,24H,1,12,16-18H2,2-7H3 $$$$ Mrv1927 02072015252D 21 22 0 0 1 0 999 V2000 -1.8080 1.5839 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5225 1.1714 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5225 0.3464 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.8080 -0.0661 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.0936 0.3464 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0936 1.1714 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7649 -0.8900 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.4524 -0.1728 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.2620 0.2397 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.2144 -0.1029 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.8556 0.4163 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6092 0.0807 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.4568 -1.3392 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.0298 -1.2646 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.3379 -0.8154 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.3972 -1.1899 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.0891 -0.7407 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.8242 -1.1153 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.8673 -1.9392 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1753 -2.3884 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4403 -2.0138 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 2 0 0 0 0 1 6 1 0 0 0 0 4 7 1 0 0 0 0 5 8 1 0 0 0 0 8 9 2 0 0 0 0 3 10 1 0 0 0 0 10 11 1 0 0 0 0 11 12 2 0 0 0 0 13 7 2 0 0 0 0 7 14 1 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 2 0 0 0 0 17 18 1 0 0 0 0 18 19 2 0 0 0 0 19 20 1 0 0 0 0 20 21 2 0 0 0 0 16 21 1 0 0 0 0 M STY 1 1 SUP M SAL 1 10 7 13 14 15 16 17 18 19 20 21 M SBL 1 1 7 M SMT 1 Cbz M SAP 1 1 7 4 1 M END > UALIB-248 > N-(Benzyloxycarbonyl)-6-vinyl-2-(2-propenyl)-1,2,3,4-tetrahydropyridine > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > C=CCC1CCC=C(C=C)N1C(=O)OCC1=CC=CC=C1 > InChI=1S/C18H21NO2/c1-3-9-17-13-8-12-16(4-2)19(17)18(20)21-14-15-10-6-5-7-11-15/h3-7,10-12,17H,1-2,8-9,13-14H2 $$$$ Mrv1927 02072015252D 32 36 0 0 1 0 999 V2000 -1.4063 1.0929 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.1207 0.6804 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.1207 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4063 -0.5572 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 0.6804 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 0.0227 -0.5572 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 0.6803 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 1.0928 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4925 1.9134 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.6399 1.3215 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3043 2.0752 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -0.7350 1.5042 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.7168 2.7897 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0800 2.6278 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.4604 1.4077 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.5418 2.7897 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9543 3.5041 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.5418 4.2186 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.7168 4.2186 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3043 3.5041 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.4516 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -3.0322 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 2 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 7 8 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 5 7 1 0 0 0 0 6 10 1 0 0 0 0 7 11 1 0 0 0 0 1 12 1 6 0 0 0 2 13 1 6 0 0 0 13 14 1 0 0 0 0 14 12 1 0 0 0 0 6 15 1 1 0 0 0 14 16 1 0 0 0 0 12 17 2 0 0 0 0 13 18 2 0 0 0 0 16 19 2 0 0 0 0 19 20 1 0 0 0 0 20 21 2 0 0 0 0 21 22 1 0 0 0 0 22 23 2 0 0 0 0 16 23 1 0 0 0 0 24 11 2 0 0 0 0 11 25 1 0 0 0 0 25 26 1 0 0 0 0 26 27 1 0 0 0 0 27 28 2 0 0 0 0 28 29 1 0 0 0 0 29 30 2 0 0 0 0 30 31 1 0 0 0 0 31 32 2 0 0 0 0 27 32 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 6 16 19 20 21 22 23 M SBL 1 1 18 M SMT 1 Ph M SAP 1 1 16 14 1 M SAL 2 10 11 24 25 26 27 28 29 30 31 32 M SBL 2 1 12 M SMT 2 Cbz M SAP 2 1 11 7 1 M END > UALIB-249 > Cycloadduct 179 > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@@]12CCCN(C(=O)OCC3=CC=CC=C3)C1=CC[C@H]1[C@@H]2C(=O)N(C1=O)C1=CC=CC=C1 > InChI=1S/C25H24N2O4/c28-23-20-13-14-21-19(22(20)24(29)27(23)18-10-5-2-6-11-18)12-7-15-26(21)25(30)31-16-17-8-3-1-4-9-17/h1-6,8-11,14,19-20,22H,7,12-13,15-16H2/t19-,20+,22-/m1/s1 $$$$ Mrv1927 02072015252D 31 35 0 0 1 0 999 V2000 -1.4063 1.0929 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.1207 0.6804 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.1207 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4063 -0.5572 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 0.6804 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 -0.5572 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 0.6803 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 1.0928 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4925 1.9134 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.6399 1.3215 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3043 2.0752 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -2.7168 2.7897 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0800 2.6278 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.4604 1.4077 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.5418 2.7897 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9543 3.5041 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.5418 4.2186 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.7168 4.2186 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3043 3.5041 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.4516 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -3.0322 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 2 0 0 0 0 1 6 1 0 0 0 0 7 8 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 5 7 1 0 0 0 0 6 10 1 0 0 0 0 7 11 1 0 0 0 0 1 12 1 0 0 0 0 2 13 1 0 0 0 0 13 14 1 0 0 0 0 14 12 1 0 0 0 0 14 15 1 0 0 0 0 12 16 2 0 0 0 0 13 17 2 0 0 0 0 15 18 2 0 0 0 0 18 19 1 0 0 0 0 19 20 2 0 0 0 0 20 21 1 0 0 0 0 21 22 2 0 0 0 0 15 22 1 0 0 0 0 23 11 2 0 0 0 0 11 24 1 0 0 0 0 24 25 1 0 0 0 0 25 26 1 0 0 0 0 26 27 2 0 0 0 0 27 28 1 0 0 0 0 28 29 2 0 0 0 0 29 30 1 0 0 0 0 30 31 2 0 0 0 0 26 31 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 6 15 18 19 20 21 22 M SBL 1 1 17 M SMT 1 Ph M SAP 1 1 15 14 1 M SAL 2 10 11 23 24 25 26 27 28 29 30 31 M SBL 2 1 12 M SMT 2 Cbz M SAP 2 1 11 7 1 M END > UALIB-250 > Cycloadduct 180 > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > O=C(OCC1=CC=CC=C1)N1CCCC2=C1CCC1C2C(=O)N(C1=O)C1=CC=CC=C1 > InChI=1S/C25H24N2O4/c28-23-20-13-14-21-19(22(20)24(29)27(23)18-10-5-2-6-11-18)12-7-15-26(21)25(30)31-16-17-8-3-1-4-9-17/h1-6,8-11,20,22H,7,12-16H2 $$$$ Mrv1927 02072015252D 29 31 0 0 1 0 999 V2000 -1.4063 1.0929 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.1207 0.6804 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.1207 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4063 -0.5572 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 0.6804 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 0.0227 -0.5572 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 0.6803 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 1.0928 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6055 1.5008 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.3631 1.9167 0.0000 N 0 3 0 0 0 0 0 0 0 0 0 0 -2.7882 1.1653 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.5026 0.7528 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.1701 1.2377 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.8112 0.7185 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.3304 1.3597 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.4516 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -3.0322 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0550 2.3661 0.0000 O 0 5 0 0 0 0 0 0 0 0 0 0 -0.6280 2.2913 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 2 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 7 8 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 5 7 1 0 0 0 0 6 10 1 0 0 0 0 7 11 1 0 0 0 0 6 12 1 1 0 0 0 1 13 1 1 0 0 0 2 14 1 6 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 17 18 1 0 0 0 0 19 11 2 0 0 0 0 11 20 1 0 0 0 0 20 21 1 0 0 0 0 21 22 1 0 0 0 0 22 23 2 0 0 0 0 23 24 1 0 0 0 0 24 25 2 0 0 0 0 25 26 1 0 0 0 0 26 27 2 0 0 0 0 22 27 1 0 0 0 0 13 28 1 0 0 0 0 13 29 2 0 0 0 0 M CHG 2 13 1 28 -1 M STY 2 1 SUP 2 SUP M SAL 1 10 11 19 20 21 22 23 24 25 26 27 M SBL 1 1 12 M SMT 1 Cbz M SAP 1 1 11 7 1 M SAL 2 3 13 28 29 M SBL 2 1 14 M SMT 2 NO2 M SAP 2 1 13 1 1 M END > UALIB-251 > Cycloadduct 181a > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@@]12CCCN(C(=O)OCC3=CC=CC=C3)C1=CC[C@H](CCCCC)[C@H]2[N+]([O-])=O > InChI=1S/C22H30N2O4/c1-2-3-5-11-18-13-14-20-19(21(18)24(26)27)12-8-15-23(20)22(25)28-16-17-9-6-4-7-10-17/h4,6-7,9-10,14,18-19,21H,2-3,5,8,11-13,15-16H2,1H3/t18-,19+,21+/m0/s1 $$$$ Mrv1927 02072015252D 29 31 0 0 1 0 999 V2000 -1.4063 1.0929 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.1207 0.6804 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.1207 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4063 -0.5572 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 0.6804 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 0.0227 -0.5572 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 0.6803 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 1.0928 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6055 1.5008 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.3631 1.9167 0.0000 N 0 3 0 0 0 0 0 0 0 0 0 0 -2.7882 1.1653 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.5026 0.7528 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.1701 1.2377 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.8112 0.7185 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.3304 1.3597 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.4516 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -3.0322 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0550 2.3661 0.0000 O 0 5 0 0 0 0 0 0 0 0 0 0 -0.6280 2.2913 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 2 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 7 8 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 5 7 1 0 0 0 0 6 10 1 0 0 0 0 7 11 1 0 0 0 0 6 12 1 1 0 0 0 1 13 1 6 0 0 0 2 14 1 1 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 17 18 1 0 0 0 0 19 11 2 0 0 0 0 11 20 1 0 0 0 0 20 21 1 0 0 0 0 21 22 1 0 0 0 0 22 23 2 0 0 0 0 23 24 1 0 0 0 0 24 25 2 0 0 0 0 25 26 1 0 0 0 0 26 27 2 0 0 0 0 22 27 1 0 0 0 0 13 28 1 0 0 0 0 13 29 2 0 0 0 0 M CHG 2 13 1 28 -1 M STY 2 1 SUP 2 SUP M SAL 1 10 11 19 20 21 22 23 24 25 26 27 M SBL 1 1 12 M SMT 1 Cbz M SAP 1 1 11 7 1 M SAL 2 3 13 28 29 M SBL 2 1 14 M SMT 2 NO2 M SAP 2 1 13 1 1 M END > UALIB-252 > Cycloadduct 181b > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@@]12CCCN(C(=O)OCC3=CC=CC=C3)C1=CC[C@@H](CCCCC)[C@@H]2[N+]([O-])=O > InChI=1S/C22H30N2O4/c1-2-3-5-11-18-13-14-20-19(21(18)24(26)27)12-8-15-23(20)22(25)28-16-17-9-6-4-7-10-17/h4,6-7,9-10,14,18-19,21H,2-3,5,8,11-13,15-16H2,1H3/t18-,19-,21+/m1/s1 $$$$ Mrv1927 02072015252D 38 40 0 0 1 0 999 V2000 -1.4063 1.0929 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.1207 0.6804 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.1207 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4063 -0.5572 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 0.6804 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 0.0227 -0.5572 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -0.1447 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 0.7372 0.6803 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 0.0227 1.0928 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6055 1.5008 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.3631 1.9167 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4291 1.1296 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.3783 -0.6639 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.4516 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -3.0322 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.7901 1.9915 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0550 2.3661 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.4820 2.4409 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6280 2.2913 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.6718 2.2709 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0464 3.0058 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1210 1.5789 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 0.8479 2.2278 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.5703 0.8870 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.3942 0.9300 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1957 0.1519 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8130 2.0282 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5481 1.6536 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.7699 2.8521 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 2 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 7 8 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 5 7 1 0 0 0 0 6 10 1 0 0 0 0 7 11 1 0 0 0 0 6 12 1 6 0 0 0 1 13 1 6 0 0 0 9 14 1 1 0 0 0 8 15 1 6 0 0 0 16 11 2 0 0 0 0 11 17 1 0 0 0 0 17 18 1 0 0 0 0 18 19 1 0 0 0 0 19 20 2 0 0 0 0 20 21 1 0 0 0 0 21 22 2 0 0 0 0 22 23 1 0 0 0 0 23 24 2 0 0 0 0 19 24 1 0 0 0 0 27 25 1 0 0 0 0 25 26 1 0 0 0 0 26 13 1 0 0 0 0 13 28 2 0 0 0 0 32 29 1 0 0 0 0 29 30 1 0 0 0 0 29 31 1 0 0 0 0 31 14 1 0 0 0 0 31 33 1 0 0 0 0 33 34 1 0 0 0 0 33 35 1 0 0 0 0 31 36 1 0 0 0 0 36 37 1 0 0 0 0 36 38 1 0 0 0 0 M STY 4 1 SUP 2 SUP 3 SUP 4 SUP M SAL 1 10 11 16 17 18 19 20 21 22 23 24 M SBL 1 1 12 M SMT 1 Cbz M SAP 1 1 11 7 1 M SAL 2 5 13 25 26 27 28 M SBL 2 1 14 M SMT 2 CO2Et M SAP 2 1 13 1 1 M SAL 3 1 15 M SBL 3 1 16 M SMT 3 Me M SAP 3 1 15 8 1 M SDS EXP 1 3 M SAL 4 11 14 29 30 31 32 33 34 35 36 37 38 M SBL 4 1 15 M SMT 4 OTIPS M SAP 4 1 14 9 1 M END > UALIB-253 > Cycloadduct 188a > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@]12C[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N(C(=O)OCC3=CC=CC=C3)C1=CCC[C@@H]2C(=O)OCC > InChI=1S/C30H47NO5Si/c1-9-34-29(32)25-16-13-17-27-26(25)18-28(36-37(20(2)3,21(4)5)22(6)7)23(8)31(27)30(33)35-19-24-14-11-10-12-15-24/h10-12,14-15,17,20-23,25-26,28H,9,13,16,18-19H2,1-8H3/t23-,25-,26+,28+/m0/s1 $$$$ Mrv1927 02072015252D 38 40 0 0 1 0 999 V2000 -1.4063 1.0929 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.1207 0.6804 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.1207 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4063 -0.5572 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 0.6804 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 0.0227 -0.5572 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -0.1447 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 0.7372 0.6803 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 0.0227 1.0928 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6055 1.5008 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.3631 1.9167 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4291 1.1296 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.3783 -0.6639 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.4516 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -3.0322 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.7901 1.9915 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0550 2.3661 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.4820 2.4409 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6280 2.2913 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.6718 2.2709 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0464 3.0058 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1210 1.5789 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 0.8479 2.2278 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.5703 0.8870 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.3942 0.9300 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1957 0.1519 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8130 2.0282 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5481 1.6536 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.7699 2.8521 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 2 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 7 8 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 5 7 1 0 0 0 0 6 10 1 0 0 0 0 7 11 1 0 0 0 0 6 12 1 6 0 0 0 1 13 1 1 0 0 0 9 14 1 1 0 0 0 8 15 1 6 0 0 0 16 11 2 0 0 0 0 11 17 1 0 0 0 0 17 18 1 0 0 0 0 18 19 1 0 0 0 0 19 20 2 0 0 0 0 20 21 1 0 0 0 0 21 22 2 0 0 0 0 22 23 1 0 0 0 0 23 24 2 0 0 0 0 19 24 1 0 0 0 0 27 25 1 0 0 0 0 25 26 1 0 0 0 0 26 13 1 0 0 0 0 13 28 2 0 0 0 0 32 29 1 0 0 0 0 29 30 1 0 0 0 0 29 31 1 0 0 0 0 31 14 1 0 0 0 0 31 33 1 0 0 0 0 33 34 1 0 0 0 0 33 35 1 0 0 0 0 31 36 1 0 0 0 0 36 37 1 0 0 0 0 36 38 1 0 0 0 0 M STY 4 1 SUP 2 SUP 3 SUP 4 SUP M SAL 1 10 11 16 17 18 19 20 21 22 23 24 M SBL 1 1 12 M SMT 1 Cbz M SAP 1 1 11 7 1 M SAL 2 5 13 25 26 27 28 M SBL 2 1 14 M SMT 2 CO2Et M SAP 2 1 13 1 1 M SAL 3 1 15 M SBL 3 1 16 M SMT 3 Me M SAP 3 1 15 8 1 M SDS EXP 1 3 M SAL 4 11 14 29 30 31 32 33 34 35 36 37 38 M SBL 4 1 15 M SMT 4 OTIPS M SAP 4 1 14 9 1 M END > UALIB-254 > Cycloadduct 188b > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@]12C[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N(C(=O)OCC3=CC=CC=C3)C1=CCC[C@H]2C(=O)OCC > InChI=1S/C30H47NO5Si/c1-9-34-29(32)25-16-13-17-27-26(25)18-28(36-37(20(2)3,21(4)5)22(6)7)23(8)31(27)30(33)35-19-24-14-11-10-12-15-24/h10-12,14-15,17,20-23,25-26,28H,9,13,16,18-19H2,1-8H3/t23-,25+,26+,28+/m0/s1 $$$$ Mrv1927 02072015252D 38 40 0 0 1 0 999 V2000 -1.4063 1.0929 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.1207 0.6804 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.1207 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4063 -0.5572 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 0.6804 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 0.0227 -0.5572 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -0.1447 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 0.7372 0.6803 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 1.0928 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6055 1.5008 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.3631 1.9167 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3783 -0.6639 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0928 -0.2514 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.4516 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -3.0322 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.7901 1.9915 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0550 2.3661 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.4820 2.4409 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6280 2.2913 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 2.3948 0.8756 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8073 1.5901 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8073 0.1611 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 1.5698 0.8756 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.2198 -0.5533 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.0448 -0.5533 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8073 -1.2678 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5217 0.5736 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.2362 0.1611 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5217 1.3986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 2 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 7 8 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 5 7 1 0 0 0 0 6 10 1 0 0 0 0 7 11 1 0 0 0 0 6 12 1 1 0 0 0 1 13 1 1 0 0 0 8 14 1 1 0 0 0 14 15 1 0 0 0 0 16 11 2 0 0 0 0 11 17 1 0 0 0 0 17 18 1 0 0 0 0 18 19 1 0 0 0 0 19 20 2 0 0 0 0 20 21 1 0 0 0 0 21 22 2 0 0 0 0 22 23 1 0 0 0 0 23 24 2 0 0 0 0 19 24 1 0 0 0 0 27 25 1 0 0 0 0 25 26 1 0 0 0 0 26 13 1 0 0 0 0 13 28 2 0 0 0 0 32 29 1 0 0 0 0 29 30 1 0 0 0 0 29 31 1 0 0 0 0 31 15 1 0 0 0 0 31 33 1 0 0 0 0 33 34 1 0 0 0 0 33 35 1 0 0 0 0 31 36 1 0 0 0 0 36 37 1 0 0 0 0 36 38 1 0 0 0 0 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 10 11 16 17 18 19 20 21 22 23 24 M SBL 1 1 12 M SMT 1 Cbz M SAP 1 1 11 7 1 M SAL 2 5 13 25 26 27 28 M SBL 2 1 14 M SMT 2 CO2Et M SAP 2 1 13 1 1 M SAL 3 11 15 29 30 31 32 33 34 35 36 37 38 M SBL 3 1 16 M SMT 3 OTIPS M SAP 3 1 15 14 1 M END > UALIB-255 > Cycloadduct 184a > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@@]12CC[C@@H](CO[Si](C(C)C)(C(C)C)C(C)C)N(C(=O)OCC3=CC=CC=C3)C1=CCC[C@H]2C(=O)OCC > InChI=1S/C30H47NO5Si/c1-8-34-29(32)27-15-12-16-28-26(27)18-17-25(20-36-37(21(2)3,22(4)5)23(6)7)31(28)30(33)35-19-24-13-10-9-11-14-24/h9-11,13-14,16,21-23,25-27H,8,12,15,17-20H2,1-7H3/t25-,26-,27+/m0/s1 $$$$ Mrv1927 02072015252D 38 40 0 0 1 0 999 V2000 -1.4063 1.0929 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.1207 0.6804 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.1207 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4063 -0.5572 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 0.6804 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 0.0227 -0.5572 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -0.1447 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 0.7372 0.6803 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 1.0928 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6055 1.5008 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.3631 1.9167 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3783 -0.6639 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0928 -0.2514 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.4516 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -3.0322 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.7901 1.9915 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0550 2.3661 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.4820 2.4409 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6280 2.2913 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 2.3948 0.8756 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8073 1.5901 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8073 0.1611 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 1.5698 0.8756 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.2198 -0.5533 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.0448 -0.5533 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8073 -1.2678 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5217 0.5736 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.2362 0.1611 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5217 1.3986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 2 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 7 8 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 5 7 1 0 0 0 0 6 10 1 0 0 0 0 7 11 1 0 0 0 0 6 12 1 1 0 0 0 1 13 1 6 0 0 0 8 14 1 1 0 0 0 14 15 1 0 0 0 0 16 11 2 0 0 0 0 11 17 1 0 0 0 0 17 18 1 0 0 0 0 18 19 1 0 0 0 0 19 20 2 0 0 0 0 20 21 1 0 0 0 0 21 22 2 0 0 0 0 22 23 1 0 0 0 0 23 24 2 0 0 0 0 19 24 1 0 0 0 0 27 25 1 0 0 0 0 25 26 1 0 0 0 0 26 13 1 0 0 0 0 13 28 2 0 0 0 0 32 29 1 0 0 0 0 29 30 1 0 0 0 0 29 31 1 0 0 0 0 31 15 1 0 0 0 0 31 33 1 0 0 0 0 33 34 1 0 0 0 0 33 35 1 0 0 0 0 31 36 1 0 0 0 0 36 37 1 0 0 0 0 36 38 1 0 0 0 0 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 10 11 16 17 18 19 20 21 22 23 24 M SBL 1 1 12 M SMT 1 Cbz M SAP 1 1 11 7 1 M SAL 2 5 13 25 26 27 28 M SBL 2 1 14 M SMT 2 CO2Et M SAP 2 1 13 1 1 M SAL 3 11 15 29 30 31 32 33 34 35 36 37 38 M SBL 3 1 16 M SMT 3 OTIPS M SAP 3 1 15 14 1 M END > UALIB-256 > Cycloadduct 184b > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@@]12CC[C@@H](CO[Si](C(C)C)(C(C)C)C(C)C)N(C(=O)OCC3=CC=CC=C3)C1=CCC[C@@H]2C(=O)OCC > InChI=1S/C30H47NO5Si/c1-8-34-29(32)27-15-12-16-28-26(27)18-17-25(20-36-37(21(2)3,22(4)5)23(6)7)31(28)30(33)35-19-24-13-10-9-11-14-24/h9-11,13-14,16,21-23,25-27H,8,12,15,17-20H2,1-7H3/t25-,26-,27-/m0/s1 $$$$ Mrv1927 02072015252D 41 43 0 0 1 0 999 V2000 -1.4063 1.0929 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.1207 0.6804 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.1207 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4063 -0.5572 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 0.6804 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 0.0227 -0.5572 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -0.1447 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 0.7372 0.6803 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 1.0928 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6055 1.5008 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.3631 1.9167 0.0000 N 0 3 0 0 0 0 0 0 0 0 0 0 1.3783 -0.6639 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0928 -0.2514 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -2.7619 1.1996 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.4538 0.7502 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.1212 1.2352 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.7623 0.7160 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.1369 1.4510 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.4516 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -3.0322 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.3948 0.8756 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8073 1.5901 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8073 0.1611 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 1.5698 0.8756 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.2198 -0.5533 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.0448 -0.5533 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8073 -1.2678 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5217 0.5736 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.2362 0.1611 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5217 1.3986 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0550 2.3661 0.0000 O 0 5 0 0 0 0 0 0 0 0 0 0 -0.6280 2.2913 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 2 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 7 8 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 5 7 1 0 0 0 0 6 10 1 0 0 0 0 7 11 1 0 0 0 0 6 12 1 1 0 0 0 1 13 1 1 0 0 0 8 14 1 1 0 0 0 14 15 1 0 0 0 0 2 16 1 6 0 0 0 16 17 1 0 0 0 0 17 18 1 0 0 0 0 18 19 1 0 0 0 0 19 20 1 0 0 0 0 21 11 2 0 0 0 0 11 22 1 0 0 0 0 22 23 1 0 0 0 0 23 24 1 0 0 0 0 24 25 2 0 0 0 0 25 26 1 0 0 0 0 26 27 2 0 0 0 0 27 28 1 0 0 0 0 28 29 2 0 0 0 0 24 29 1 0 0 0 0 33 30 1 0 0 0 0 30 31 1 0 0 0 0 30 32 1 0 0 0 0 32 15 1 0 0 0 0 32 34 1 0 0 0 0 34 35 1 0 0 0 0 34 36 1 0 0 0 0 32 37 1 0 0 0 0 37 38 1 0 0 0 0 37 39 1 0 0 0 0 13 40 1 0 0 0 0 13 41 2 0 0 0 0 M CHG 2 13 1 40 -1 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 10 11 21 22 23 24 25 26 27 28 29 M SBL 1 1 12 M SMT 1 Cbz M SAP 1 1 11 7 1 M SAL 2 11 15 30 31 32 33 34 35 36 37 38 39 M SBL 2 1 16 M SMT 2 OTIPS M SAP 2 1 15 14 1 M SAL 3 3 13 40 41 M SBL 3 1 14 M SMT 3 NO2 M SAP 3 1 13 1 1 M END > UALIB-257 > Cycloadduct 185a > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@@]12CC[C@@H](CO[Si](C(C)C)(C(C)C)C(C)C)N(C(=O)OCC3=CC=CC=C3)C1=CC[C@H](CCCCC)[C@H]2[N+]([O-])=O > InChI=1S/C32H52N2O5Si/c1-8-9-11-16-27-17-20-30-29(31(27)34(36)37)19-18-28(22-39-40(23(2)3,24(4)5)25(6)7)33(30)32(35)38-21-26-14-12-10-13-15-26/h10,12-15,20,23-25,27-29,31H,8-9,11,16-19,21-22H2,1-7H3/t27-,28-,29+,31+/m0/s1 $$$$ Mrv1927 02072015252D 29 31 0 0 1 0 999 V2000 -1.4063 1.0929 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.1207 0.6804 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.1207 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4063 -0.5572 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 0.6804 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 0.0227 -0.5572 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -0.1447 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 0.7372 0.6803 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 1.0928 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6055 1.5008 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.3631 1.9167 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3783 -0.6639 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0702 -0.2146 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8053 -0.5891 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.4516 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -3.0322 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.7901 1.9915 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0550 2.3661 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.4820 2.4409 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6280 2.2913 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 2 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 7 8 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 5 7 1 0 0 0 0 6 10 1 0 0 0 0 7 11 1 0 0 0 0 6 12 1 1 0 0 0 1 13 1 1 0 0 0 8 14 1 1 0 0 0 14 15 1 0 0 0 0 15 16 2 0 0 0 0 17 11 2 0 0 0 0 11 18 1 0 0 0 0 18 19 1 0 0 0 0 19 20 1 0 0 0 0 20 21 2 0 0 0 0 21 22 1 0 0 0 0 22 23 2 0 0 0 0 23 24 1 0 0 0 0 24 25 2 0 0 0 0 20 25 1 0 0 0 0 28 26 1 0 0 0 0 26 27 1 0 0 0 0 27 13 1 0 0 0 0 13 29 2 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 10 11 17 18 19 20 21 22 23 24 25 M SBL 1 1 12 M SMT 1 Cbz M SAP 1 1 11 7 1 M SAL 2 5 13 26 27 28 29 M SBL 2 1 14 M SMT 2 CO2Et M SAP 2 1 13 1 1 M END > UALIB-258 > Cycloadduct 186a > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@@]12CC[C@@H](CC=C)N(C(=O)OCC3=CC=CC=C3)C1=CCC[C@H]2C(=O)OCC > InChI=1S/C23H29NO4/c1-3-9-18-14-15-19-20(22(25)27-4-2)12-8-13-21(19)24(18)23(26)28-16-17-10-6-5-7-11-17/h3,5-7,10-11,13,18-20H,1,4,8-9,12,14-16H2,2H3/t18-,19+,20-/m1/s1 $$$$ Mrv1927 02072015252D 29 31 0 0 1 0 999 V2000 -1.4063 1.0929 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.1207 0.6804 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.1207 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4063 -0.5572 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 0.6804 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 0.0227 -0.5572 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -0.1447 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 0.7372 0.6803 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 1.0928 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6055 1.5008 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.3631 1.9167 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.3783 -0.6639 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0702 -0.2146 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8053 -0.5891 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.4516 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -3.0322 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.7901 1.9915 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0550 2.3661 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.4820 2.4409 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6280 2.2913 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 2 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 7 8 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 5 7 1 0 0 0 0 6 10 1 0 0 0 0 7 11 1 0 0 0 0 6 12 1 1 0 0 0 1 13 1 6 0 0 0 8 14 1 1 0 0 0 14 15 1 0 0 0 0 15 16 2 0 0 0 0 17 11 2 0 0 0 0 11 18 1 0 0 0 0 18 19 1 0 0 0 0 19 20 1 0 0 0 0 20 21 2 0 0 0 0 21 22 1 0 0 0 0 22 23 2 0 0 0 0 23 24 1 0 0 0 0 24 25 2 0 0 0 0 20 25 1 0 0 0 0 28 26 1 0 0 0 0 26 27 1 0 0 0 0 27 13 1 0 0 0 0 13 29 2 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 10 11 17 18 19 20 21 22 23 24 25 M SBL 1 1 12 M SMT 1 Cbz M SAP 1 1 11 7 1 M SAL 2 5 13 26 27 28 29 M SBL 2 1 14 M SMT 2 CO2Et M SAP 2 1 13 1 1 M END > UALIB-259 > Cycloadduct 186b > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@@]12CC[C@@H](CC=C)N(C(=O)OCC3=CC=CC=C3)C1=CCC[C@@H]2C(=O)OCC > InChI=1S/C23H29NO4/c1-3-9-18-14-15-19-20(22(25)27-4-2)12-8-13-21(19)24(18)23(26)28-16-17-10-6-5-7-11-17/h3,5-7,10-11,13,18-20H,1,4,8-9,12,14-16H2,2H3/t18-,19+,20+/m1/s1 $$$$ Mrv1927 02072015252D 32 34 0 0 1 0 999 V2000 -1.4063 1.0929 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.1207 0.6804 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.1207 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4063 -0.5572 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 0.6804 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 0.0227 -0.5572 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -0.1447 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 0.7372 0.6803 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 1.0928 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6055 1.5008 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.3631 1.9167 0.0000 N 0 3 0 0 0 0 0 0 0 0 0 0 1.3783 -0.6639 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.7619 1.1996 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.4538 0.7502 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.1212 1.2352 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.7623 0.7160 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.1369 1.4510 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0195 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.7114 -0.5940 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.4516 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -3.0322 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0550 2.3661 0.0000 O 0 5 0 0 0 0 0 0 0 0 0 0 -0.6280 2.2913 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 2 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 7 8 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 5 7 1 0 0 0 0 6 10 1 0 0 0 0 7 11 1 0 0 0 0 6 12 1 1 0 0 0 1 13 1 1 0 0 0 8 14 1 1 0 0 0 2 15 1 6 0 0 0 15 16 1 0 0 0 0 16 17 1 0 0 0 0 17 18 1 0 0 0 0 18 19 1 0 0 0 0 14 20 1 0 0 0 0 20 21 2 0 0 0 0 22 11 2 0 0 0 0 11 23 1 0 0 0 0 23 24 1 0 0 0 0 24 25 1 0 0 0 0 25 26 2 0 0 0 0 26 27 1 0 0 0 0 27 28 2 0 0 0 0 28 29 1 0 0 0 0 29 30 2 0 0 0 0 25 30 1 0 0 0 0 13 31 1 0 0 0 0 13 32 2 0 0 0 0 M CHG 2 13 1 31 -1 M STY 2 1 SUP 2 SUP M SAL 1 10 11 22 23 24 25 26 27 28 29 30 M SBL 1 1 12 M SMT 1 Cbz M SAP 1 1 11 7 1 M SAL 2 3 13 31 32 M SBL 2 1 14 M SMT 2 NO2 M SAP 2 1 13 1 1 M END > UALIB-260 > Cycloadduct 187a > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@@]12CC[C@@H](CC=C)N(C(=O)OCC3=CC=CC=C3)C1=CC[C@H](CCCCC)[C@H]2[N+]([O-])=O > InChI=1S/C25H34N2O4/c1-3-5-7-13-20-14-17-23-22(24(20)27(29)30)16-15-21(10-4-2)26(23)25(28)31-18-19-11-8-6-9-12-19/h4,6,8-9,11-12,17,20-22,24H,2-3,5,7,10,13-16,18H2,1H3/t20-,21+,22+,24+/m0/s1 $$$$ Mrv1927 02072015252D 44 48 0 0 1 0 999 V2000 -1.4063 1.0929 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.1207 0.6804 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.1207 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4063 -0.5572 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 0.6804 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 0.0227 -0.5572 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -0.1447 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 0.7372 0.6803 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 0.0227 1.0928 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4925 1.9134 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.6399 1.3215 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3043 2.0752 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -2.7168 2.7897 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0800 2.6278 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.4604 1.4077 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.4909 1.0159 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.4046 -0.6296 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 1.5054 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.5418 2.7897 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9543 3.5041 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.5418 4.2186 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.7168 4.2186 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3043 3.5041 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.4516 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -3.0322 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.9088 2.1051 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.3937 2.7727 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.2445 1.3514 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 1.0883 2.1913 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.5801 0.5980 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.4006 0.5117 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0954 -0.0697 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.9982 1.6872 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.6656 1.2023 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.0842 2.5077 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 2 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 7 8 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 5 7 1 0 0 0 0 6 10 1 0 0 0 0 7 11 1 0 0 0 0 1 12 1 1 0 0 0 2 13 1 1 0 0 0 13 14 1 0 0 0 0 14 12 1 0 0 0 0 14 15 1 0 0 0 0 12 16 2 0 0 0 0 13 17 2 0 0 0 0 9 18 1 1 0 0 0 8 19 1 6 0 0 0 6 20 1 6 0 0 0 15 21 2 0 0 0 0 21 22 1 0 0 0 0 22 23 2 0 0 0 0 23 24 1 0 0 0 0 24 25 2 0 0 0 0 15 25 1 0 0 0 0 26 11 2 0 0 0 0 11 27 1 0 0 0 0 27 28 1 0 0 0 0 28 29 1 0 0 0 0 29 30 2 0 0 0 0 30 31 1 0 0 0 0 31 32 2 0 0 0 0 32 33 1 0 0 0 0 33 34 2 0 0 0 0 29 34 1 0 0 0 0 38 35 1 0 0 0 0 35 36 1 0 0 0 0 35 37 1 0 0 0 0 37 18 1 0 0 0 0 37 39 1 0 0 0 0 39 40 1 0 0 0 0 39 41 1 0 0 0 0 37 42 1 0 0 0 0 42 43 1 0 0 0 0 42 44 1 0 0 0 0 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 6 15 21 22 23 24 25 M SBL 1 1 17 M SMT 1 Ph M SAP 1 1 15 14 1 M SAL 2 10 11 26 27 28 29 30 31 32 33 34 M SBL 2 1 12 M SMT 2 Cbz M SAP 2 1 11 7 1 M SAL 3 11 18 35 36 37 38 39 40 41 42 43 44 M SBL 3 1 20 M SMT 3 OTIPS M SAP 3 1 18 9 1 M END > UALIB-261 > Cycloadduct 189a > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@]12C[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N(C(=O)OCC3=CC=CC=C3)C1=CC[C@@H]1[C@H]2C(=O)N(C1=O)C1=CC=CC=C1 > InChI=1S/C35H46N2O5Si/c1-22(2)43(23(3)4,24(5)6)42-31-20-29-30(36(25(31)7)35(40)41-21-26-14-10-8-11-15-26)19-18-28-32(29)34(39)37(33(28)38)27-16-12-9-13-17-27/h8-17,19,22-25,28-29,31-32H,18,20-21H2,1-7H3/t25-,28+,29-,31+,32+/m0/s1 $$$$ Mrv1927 02072015252D 44 48 0 0 1 0 999 V2000 -1.4063 1.0929 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.1207 0.6804 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.1207 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4063 -0.5572 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 0.6804 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 0.0227 -0.5572 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -0.1447 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 0.7372 0.6803 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 0.0227 1.0928 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4925 1.9134 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.6399 1.3215 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3043 2.0752 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -2.7168 2.7897 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0800 2.6278 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.4604 1.4077 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.4909 1.0159 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.4046 -0.6296 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 1.5054 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.5418 2.7897 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9543 3.5041 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.5418 4.2186 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.7168 4.2186 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3043 3.5041 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.4516 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -3.0322 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.9088 2.1051 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.3937 2.7727 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.2445 1.3514 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 1.0883 2.1913 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.5801 0.5980 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.4006 0.5117 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0954 -0.0697 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.9982 1.6872 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.6656 1.2023 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.0842 2.5077 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 2 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 7 8 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 5 7 1 0 0 0 0 6 10 1 0 0 0 0 7 11 1 0 0 0 0 1 12 1 6 0 0 0 2 13 1 6 0 0 0 13 14 1 0 0 0 0 14 12 1 0 0 0 0 14 15 1 0 0 0 0 12 16 2 0 0 0 0 13 17 2 0 0 0 0 9 18 1 1 0 0 0 8 19 1 6 0 0 0 6 20 1 1 0 0 0 15 21 2 0 0 0 0 21 22 1 0 0 0 0 22 23 2 0 0 0 0 23 24 1 0 0 0 0 24 25 2 0 0 0 0 15 25 1 0 0 0 0 26 11 2 0 0 0 0 11 27 1 0 0 0 0 27 28 1 0 0 0 0 28 29 1 0 0 0 0 29 30 2 0 0 0 0 30 31 1 0 0 0 0 31 32 2 0 0 0 0 32 33 1 0 0 0 0 33 34 2 0 0 0 0 29 34 1 0 0 0 0 38 35 1 0 0 0 0 35 36 1 0 0 0 0 35 37 1 0 0 0 0 37 18 1 0 0 0 0 37 39 1 0 0 0 0 39 40 1 0 0 0 0 39 41 1 0 0 0 0 37 42 1 0 0 0 0 42 43 1 0 0 0 0 42 44 1 0 0 0 0 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 6 15 21 22 23 24 25 M SBL 1 1 17 M SMT 1 Ph M SAP 1 1 15 14 1 M SAL 2 10 11 26 27 28 29 30 31 32 33 34 M SBL 2 1 12 M SMT 2 Cbz M SAP 2 1 11 7 1 M SAL 3 11 18 35 36 37 38 39 40 41 42 43 44 M SBL 3 1 20 M SMT 3 OTIPS M SAP 3 1 18 9 1 M END > UALIB-262 > Cycloadduct 189b > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > [H][C@@]12C[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N(C(=O)OCC3=CC=CC=C3)C1=CC[C@H]1[C@@H]2C(=O)N(C1=O)C1=CC=CC=C1 > InChI=1S/C35H46N2O5Si/c1-22(2)43(23(3)4,24(5)6)42-31-20-29-30(36(25(31)7)35(40)41-21-26-14-10-8-11-15-26)19-18-28-32(29)34(39)37(33(28)38)27-16-12-9-13-17-27/h8-17,19,22-25,28-29,31-32H,18,20-21H2,1-7H3/t25-,28-,29+,31+,32-/m0/s1 $$$$ Mrv1927 02072015252D 43 47 0 0 1 0 999 V2000 -1.4063 1.0929 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.1207 0.6804 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.1207 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4063 -0.5572 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -0.1447 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 0.6804 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 -0.5572 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -0.1447 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 0.7372 0.6803 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 0.0227 1.0928 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0227 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.4925 1.9134 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.6399 1.3215 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3043 2.0752 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -2.7168 2.7897 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0800 2.6278 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.4604 1.4077 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.4909 1.0159 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.4046 -0.6296 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.5418 2.7897 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9543 3.5041 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.5418 4.2186 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.7168 4.2186 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3043 3.5041 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6918 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.7372 -1.7947 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.4516 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -1.3822 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -1.7947 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5951 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8806 -3.0322 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1661 -2.6197 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.9088 2.1051 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.3937 2.7727 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.2445 1.3514 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 1.0883 2.1913 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.5801 0.5980 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.4006 0.5117 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0954 -0.0697 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.9982 1.6872 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.6656 1.2023 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.0842 2.5077 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 2 0 0 0 0 1 6 1 0 0 0 0 7 8 1 0 0 0 0 8 9 1 0 0 0 0 9 10 1 0 0 0 0 5 7 1 0 0 0 0 6 10 1 0 0 0 0 7 11 1 0 0 0 0 1 12 1 6 0 0 0 2 13 1 6 0 0 0 13 14 1 0 0 0 0 14 12 1 0 0 0 0 14 15 1 0 0 0 0 12 16 2 0 0 0 0 13 17 2 0 0 0 0 9 18 1 1 0 0 0 8 19 1 6 0 0 0 15 20 2 0 0 0 0 20 21 1 0 0 0 0 21 22 2 0 0 0 0 22 23 1 0 0 0 0 23 24 2 0 0 0 0 15 24 1 0 0 0 0 25 11 2 0 0 0 0 11 26 1 0 0 0 0 26 27 1 0 0 0 0 27 28 1 0 0 0 0 28 29 2 0 0 0 0 29 30 1 0 0 0 0 30 31 2 0 0 0 0 31 32 1 0 0 0 0 32 33 2 0 0 0 0 28 33 1 0 0 0 0 37 34 1 0 0 0 0 34 35 1 0 0 0 0 34 36 1 0 0 0 0 36 18 1 0 0 0 0 36 38 1 0 0 0 0 38 39 1 0 0 0 0 38 40 1 0 0 0 0 36 41 1 0 0 0 0 41 42 1 0 0 0 0 41 43 1 0 0 0 0 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 6 15 20 21 22 23 24 M SBL 1 1 17 M SMT 1 Ph M SAP 1 1 15 14 1 M SAL 2 10 11 25 26 27 28 29 30 31 32 33 M SBL 2 1 12 M SMT 2 Cbz M SAP 2 1 11 7 1 M SAL 3 11 18 34 35 36 37 38 39 40 41 42 43 M SBL 3 1 20 M SMT 3 OTIPS M SAP 3 1 18 9 1 M END > UALIB-263 > Cycloadduct 190 > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CC(C)[Si](O[C@@H]1CC2=C(CC[C@H]3[C@@H]2C(=O)N(C3=O)C2=CC=CC=C2)N([C@H]1C)C(=O)OCC1=CC=CC=C1)(C(C)C)C(C)C > InChI=1S/C35H46N2O5Si/c1-22(2)43(23(3)4,24(5)6)42-31-20-29-30(36(25(31)7)35(40)41-21-26-14-10-8-11-15-26)19-18-28-32(29)34(39)37(33(28)38)27-16-12-9-13-17-27/h8-17,22-25,28,31-32H,18-21H2,1-7H3/t25-,28-,31+,32-/m0/s1 $$$$ Mrv1927 02072015252D 60 64 0 0 1 0 999 V2000 -4.2411 0.9589 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -4.9555 0.5464 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -4.9555 -0.2786 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -4.2411 -0.6911 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.5266 -0.2786 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.5266 0.5464 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.8121 0.9589 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.3272 1.6264 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.7438 1.0430 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.1447 0.4740 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.9902 1.3786 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.2757 2.6161 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.9902 2.2036 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.2757 0.9661 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 0.4388 1.3786 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 0.4388 2.2036 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 1.1532 0.9661 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.4747 1.1876 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.6700 -0.6911 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.1924 2.5391 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.1979 1.7828 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.2325 0.1422 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.4628 2.1574 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.8898 2.2321 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -5.6249 1.8578 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.3168 2.3071 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -7.0519 1.9328 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -7.7438 2.3821 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -7.7004 3.2060 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.9653 3.5805 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.2734 3.1310 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.9244 -0.3071 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.5025 -0.2323 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.1945 0.2172 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.9295 -0.1574 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.6214 0.2920 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.3565 -0.0826 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.3997 -0.9064 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.7080 -1.3558 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.9727 -0.9812 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.6107 3.6284 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0957 4.2956 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.9461 2.8747 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 0.7903 3.7146 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.2817 2.1208 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.1021 2.0346 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.7965 1.4536 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.6998 3.2101 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.3672 2.7251 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.7862 4.0305 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.9720 -1.8181 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.3845 -2.5325 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.3845 -1.1036 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -5.1470 -1.8181 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.7970 -0.3891 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -7.6220 -0.3891 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.3845 0.3254 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -7.0989 -1.5161 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -7.8134 -1.1036 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -7.0989 -2.3411 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 2 0 0 0 0 1 6 1 0 0 0 0 6 7 1 0 0 0 0 7 8 1 0 0 0 0 8 9 1 0 0 0 0 7 10 1 0 0 0 0 10 9 1 0 0 0 0 9 11 1 0 0 0 0 12 13 1 0 0 0 0 14 15 1 0 0 0 0 15 16 1 0 0 0 0 12 16 1 0 0 0 0 13 11 2 0 0 0 0 11 14 1 0 0 0 0 15 17 1 6 0 0 0 2 18 1 6 0 0 0 3 19 1 1 0 0 0 16 20 1 1 0 0 0 1 21 1 0 0 0 0 14 22 1 0 0 0 0 23 21 2 0 0 0 0 21 24 1 0 0 0 0 24 25 1 0 0 0 0 25 26 1 0 0 0 0 26 27 2 0 0 0 0 27 28 1 0 0 0 0 28 29 2 0 0 0 0 29 30 1 0 0 0 0 30 31 2 0 0 0 0 26 31 1 0 0 0 0 32 22 2 0 0 0 0 22 33 1 0 0 0 0 33 34 1 0 0 0 0 34 35 1 0 0 0 0 35 36 2 0 0 0 0 36 37 1 0 0 0 0 37 38 2 0 0 0 0 38 39 1 0 0 0 0 39 40 2 0 0 0 0 35 40 1 0 0 0 0 44 41 1 0 0 0 0 41 42 1 0 0 0 0 41 43 1 0 0 0 0 43 20 1 0 0 0 0 43 45 1 0 0 0 0 45 46 1 0 0 0 0 45 47 1 0 0 0 0 43 48 1 0 0 0 0 48 49 1 0 0 0 0 48 50 1 0 0 0 0 54 51 1 0 0 0 0 51 52 1 0 0 0 0 51 53 1 0 0 0 0 53 19 1 0 0 0 0 53 55 1 0 0 0 0 55 56 1 0 0 0 0 55 57 1 0 0 0 0 53 58 1 0 0 0 0 58 59 1 0 0 0 0 58 60 1 0 0 0 0 M STY 4 1 SUP 2 SUP 3 SUP 4 SUP M SAL 1 10 21 23 24 25 26 27 28 29 30 31 M SBL 1 1 23 M SMT 1 Cbz M SAP 1 1 21 1 1 M SAL 2 10 22 32 33 34 35 36 37 38 39 40 M SBL 2 1 24 M SMT 2 Cbz M SAP 2 1 22 14 1 M SAL 3 11 20 41 42 43 44 45 46 47 48 49 50 M SBL 3 1 22 M SMT 3 OTIPS M SAP 3 1 20 16 1 M SAL 4 11 19 51 52 53 54 55 56 57 58 59 60 M SBL 4 1 21 M SMT 4 OTIPS M SAP 4 1 19 3 1 M END > UALIB-264 > Dimer 196 > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CC(C)[Si](O[C@@H]1CC=C(C2CC(C2)C2=CC[C@@H](O[Si](C(C)C)(C(C)C)C(C)C)[C@H](C)N2C(=O)OCC2=CC=CC=C2)N([C@H]1C)C(=O)OCC1=CC=CC=C1)(C(C)C)C(C)C > InChI=1S/C50H78N2O6Si2/c1-33(2)59(34(3)4,35(5)6)57-47-27-25-45(51(39(47)13)49(53)55-31-41-21-17-15-18-22-41)43-29-44(30-43)46-26-28-48(58-60(36(7)8,37(9)10)38(11)12)40(14)52(46)50(54)56-32-42-23-19-16-20-24-42/h15-26,33-40,43-44,47-48H,27-32H2,1-14H3/t39-,40-,43?,44?,47+,48+/m0/s1 $$$$ Mrv1927 02072015252D 23 22 0 0 1 0 999 V2000 -3.9732 0.8705 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.2587 1.2830 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5913 0.7981 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -2.5913 -0.0269 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.9502 1.3173 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.3090 0.7981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.5553 1.1337 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.2685 1.0905 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7179 1.7824 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0260 2.2317 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4098 1.3331 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1672 2.4743 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6431 0.3554 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.2752 -0.2564 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6877 -0.9709 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6877 0.4580 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -3.4502 -0.2564 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.1002 1.1725 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.9252 1.1725 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6877 1.8870 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.4022 0.0455 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.1166 0.4580 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.4022 -0.7795 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 6 0 0 0 3 5 1 0 0 0 0 5 6 1 0 0 0 0 6 7 1 0 0 0 0 7 8 1 0 0 0 0 12 9 1 0 0 0 0 9 10 1 0 0 0 0 9 11 1 0 0 0 0 9 8 1 0 0 0 0 8 13 2 0 0 0 0 17 14 1 0 0 0 0 14 15 1 0 0 0 0 14 16 1 0 0 0 0 16 1 1 0 0 0 0 16 18 1 0 0 0 0 18 19 1 0 0 0 0 18 20 1 0 0 0 0 16 21 1 0 0 0 0 21 22 1 0 0 0 0 21 23 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 6 8 9 10 11 12 13 M SBL 1 1 7 M SMT 1 Piv M SAP 1 1 8 7 1 M SAL 2 11 1 14 15 16 17 18 19 20 21 22 23 M SBL 2 1 1 M SMT 2 OTIPS M SAP 2 1 1 2 1 M END > UALIB-265 > (3S)-4-Triisopropylsiloxy-3-hydroxybutyl 2,2-dimethylpropionate > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CC(C)[Si](OC[C@@H](O)CCOC(=O)C(C)(C)C)(C(C)C)C(C)C > InChI=1S/C18H38O4Si/c1-13(2)23(14(3)4,15(5)6)22-12-16(19)10-11-21-17(20)18(7,8)9/h13-16,19H,10-12H2,1-9H3/t16-/m0/s1 $$$$ Mrv1927 02072015252D 25 24 0 0 1 0 999 V2000 -3.9732 0.8705 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.2587 1.2830 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5913 0.7981 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.5913 -0.0269 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.9502 1.3173 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.3090 0.7981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.5553 1.1337 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 0.2685 1.0905 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7179 1.7824 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0260 2.2317 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.4098 1.3331 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1672 2.4743 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6431 0.3554 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.2752 -0.2564 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6877 -0.9709 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6877 0.4580 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -3.4502 -0.2564 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.1002 1.1725 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.9252 1.1725 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6877 1.8870 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.4022 0.0455 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.1166 0.4580 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.4022 -0.7795 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5913 -0.8519 0.0000 N 0 3 0 0 0 0 0 0 0 0 0 0 -2.5913 -1.6769 0.0000 N 0 5 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 1 0 0 0 3 5 1 0 0 0 0 5 6 1 0 0 0 0 6 7 1 0 0 0 0 7 8 1 0 0 0 0 12 9 1 0 0 0 0 9 10 1 0 0 0 0 9 11 1 0 0 0 0 9 8 1 0 0 0 0 8 13 2 0 0 0 0 17 14 1 0 0 0 0 14 15 1 0 0 0 0 14 16 1 0 0 0 0 16 1 1 0 0 0 0 16 18 1 0 0 0 0 18 19 1 0 0 0 0 18 20 1 0 0 0 0 16 21 1 0 0 0 0 21 22 1 0 0 0 0 21 23 1 0 0 0 0 4 24 2 0 0 0 0 24 25 2 0 0 0 0 M CHG 2 24 1 25 -1 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 6 8 9 10 11 12 13 M SBL 1 1 7 M SMT 1 Piv M SAP 1 1 8 7 1 M SAL 2 11 1 14 15 16 17 18 19 20 21 22 23 M SBL 2 1 1 M SMT 2 OTIPS M SAP 2 1 1 2 1 M SAL 3 3 4 24 25 M SBL 3 1 3 M SMT 3 N3 M SAP 3 1 4 3 1 M END > UALIB-266 > (3R)-4-Triisopropylsiloxy-3-azidobutyl 2,2-dimethylpropionate > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CC(C)[Si](OC[C@@H](CCOC(=O)C(C)(C)C)N=[N+]=[N-])(C(C)C)C(C)C > InChI=1S/C18H37N3O3Si/c1-13(2)25(14(3)4,15(5)6)24-12-16(20-21-19)10-11-23-17(22)18(7,8)9/h13-16H,10-12H2,1-9H3/t16-/m1/s1 $$$$ Mrv1927 02072015252D 27 27 0 0 1 0 999 V2000 -3.9732 0.8705 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.2587 1.2830 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5913 0.7981 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.5913 -0.0269 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.9502 1.3173 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.3090 0.7981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.5553 1.1337 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.8067 -0.2818 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2752 -0.2564 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6877 -0.9709 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6877 0.4580 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -3.4502 -0.2564 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.1002 1.1725 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.9252 1.1725 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6877 1.8870 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.4022 0.0455 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.1166 0.4580 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.4022 -0.7795 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6351 -1.0888 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.1936 0.2702 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.3652 1.0772 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7521 1.6293 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.9237 2.4363 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3107 2.9883 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4740 2.7335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6455 1.9265 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0325 1.3744 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 1 0 0 0 3 5 1 0 0 0 0 5 6 1 0 0 0 0 6 7 1 0 0 0 0 4 8 1 0 0 0 0 12 9 1 0 0 0 0 9 10 1 0 0 0 0 9 11 1 0 0 0 0 11 1 1 0 0 0 0 11 13 1 0 0 0 0 13 14 1 0 0 0 0 13 15 1 0 0 0 0 11 16 1 0 0 0 0 16 17 1 0 0 0 0 16 18 1 0 0 0 0 19 8 2 0 0 0 0 8 20 1 0 0 0 0 20 21 1 0 0 0 0 21 22 1 0 0 0 0 22 23 2 0 0 0 0 23 24 1 0 0 0 0 24 25 2 0 0 0 0 25 26 1 0 0 0 0 26 27 2 0 0 0 0 22 27 1 0 0 0 0 M STY 2 1 SUP 2 SUP M SAL 1 11 1 9 10 11 12 13 14 15 16 17 18 M SBL 1 1 1 M SMT 1 OTIPS M SAP 1 1 1 2 1 M SAL 2 10 8 19 20 21 22 23 24 25 26 27 M SBL 2 1 7 M SMT 2 Cbz M SAP 2 1 8 4 1 M END > UALIB-267 > (3R)-3-(N-Benzyloxycarbonylamino)-4-triisopropylsiloxy-1-butanol > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CC(C)[Si](OC[C@@H](CCO)NC(=O)OCC1=CC=CC=C1)(C(C)C)C(C)C > InChI=1S/C21H37NO4Si/c1-16(2)27(17(3)4,18(5)6)26-15-20(12-13-23)22-21(24)25-14-19-10-8-7-9-11-19/h7-11,16-18,20,23H,12-15H2,1-6H3,(H,22,24)/t20-/m1/s1 $$$$ Mrv1927 02072015252D 32 32 0 0 1 0 999 V2000 -3.9732 0.8705 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.2587 1.2830 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5913 0.7981 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 -2.5913 -0.0269 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.9502 1.3173 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.3090 0.7981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.8067 -0.2818 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.6416 1.2830 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0259 0.7981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2752 -0.2564 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6877 -0.9709 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6877 0.4580 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -3.4502 -0.2564 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.1002 1.1725 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.9252 1.1725 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.6877 1.8870 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.4022 0.0455 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -6.1166 0.4580 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.4022 -0.7795 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.6351 -1.0888 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.1936 0.2702 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.3652 1.0772 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.7521 1.6293 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.9237 2.4363 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.3107 2.9883 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.4740 2.7335 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6455 1.9265 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0325 1.3744 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.8657 1.9543 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7795 1.1337 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1.6194 2.2898 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.0603 -0.0224 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 1 0 0 0 3 5 1 0 0 0 0 5 6 1 0 0 0 0 4 7 1 0 0 0 0 6 8 2 0 0 0 0 8 9 1 0 0 0 0 13 10 1 0 0 0 0 10 11 1 0 0 0 0 10 12 1 0 0 0 0 12 1 1 0 0 0 0 12 14 1 0 0 0 0 14 15 1 0 0 0 0 14 16 1 0 0 0 0 12 17 1 0 0 0 0 17 18 1 0 0 0 0 17 19 1 0 0 0 0 20 7 2 0 0 0 0 7 21 1 0 0 0 0 21 22 1 0 0 0 0 22 23 1 0 0 0 0 23 24 2 0 0 0 0 24 25 1 0 0 0 0 25 26 2 0 0 0 0 26 27 1 0 0 0 0 27 28 2 0 0 0 0 23 28 1 0 0 0 0 31 29 1 0 0 0 0 29 30 1 0 0 0 0 30 9 1 0 0 0 0 9 32 2 0 0 0 0 M STY 3 1 SUP 2 SUP 3 SUP M SAL 1 11 1 10 11 12 13 14 15 16 17 18 19 M SBL 1 1 1 M SMT 1 OTIPS M SAP 1 1 1 2 1 M SAL 2 10 7 20 21 22 23 24 25 26 27 28 M SBL 2 1 6 M SMT 2 Cbz M SAP 2 1 7 4 1 M SAL 3 5 9 29 30 31 32 M SBL 3 1 8 M SMT 3 CO2Et M SAP 3 1 9 8 1 M END > UALIB-268 > Ethyl (2E,5R)-5-(N-benzyoxycarbonylamino)-6-(triisopropylsiloxy-2-hexenoate > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CCOC(=O)\C=C\C[C@H](CO[Si](C(C)C)(C(C)C)C(C)C)NC(=O)OCC1=CC=CC=C1 > InChI=1S/C25H41NO5Si/c1-8-29-24(27)16-12-15-23(18-31-32(19(2)3,20(4)5)21(6)7)26-25(28)30-17-22-13-10-9-11-14-22/h9-14,16,19-21,23H,8,15,17-18H2,1-7H3,(H,26,28)/b16-12+/t23-/m1/s1 $$$$ Mrv1927 02072015252D 19 19 0 0 1 0 999 V2000 -1.7857 1.5616 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5002 1.1491 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.5002 0.3241 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 -1.7857 -0.0884 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.0712 0.3241 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.0712 1.1491 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.4038 -0.1608 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.1921 -0.1252 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.8332 0.3940 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 -4.9936 0.2722 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.8084 0.4014 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.4743 0.9132 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 -4.6981 -0.4981 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.9550 1.5543 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.2505 2.3246 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.1401 1.4251 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.1153 1.4325 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -4.9862 2.2474 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 -5.8856 1.1370 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 0 0 0 2 3 1 0 0 0 0 3 4 1 0 0 0 0 4 5 1 0 0 0 0 5 6 1 0 0 0 0 1 6 1 0 0 0 0 5 7 2 0 0 0 0 3 8 1 1 0 0 0 8 9 1 0 0 0 0 13 10 1 0 0 0 0 10 11 1 0 0 0 0 10 12 1 0 0 0 0 12 9 1 0 0 0 0 12 14 1 0 0 0 0 14 15 1 0 0 0 0 14 16 1 0 0 0 0 12 17 1 0 0 0 0 17 18 1 0 0 0 0 17 19 1 0 0 0 0 M STY 1 1 SUP M SAL 1 11 9 10 11 12 13 14 15 16 17 18 19 M SBL 1 1 9 M SMT 1 OTIPS M SAP 1 1 9 8 1 M END > UALIB-269 > (6R)-6-Triisopropylsiloxymethyl-2-piperidinone > Ha, J.D. Total Synthesis of Clavepictines A and B. Ph.D. Dissertation, The University of Alabama, 1999. > http://library.ua.edu/vwebv/holdingsInfo?bibId=1053962 > CC(C)[Si](OC[C@H]1CCCC(=O)N1)(C(C)C)C(C)C > InChI=1S/C15H31NO2Si/c1-11(2)19(12(3)4,13(5)6)18-10-14-8-7-9-15(17)16-14/h11-14H,7-10H2,1-6H3,(H,16,17)/t14-/m1/s1 $$$$